1839302
2025
1
surface-science-reports
50
creator
asc
23844
https://www-ipcms.u-strasbg.fr/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3Afalse%2C%22meta%22%3A%7B%22request_last%22%3A50%2C%22request_next%22%3A50%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22B2JAXSCM%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Aloui%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EE.%20Aloui%2C%20J.%20Beurton%2C%20C.%20Medemblik%2C%20L.%20Hugoni%2C%20I.%20Clarot%2C%20A.%20Boudier%2C%20Y.%20Arntz%2C%20M.%20De%20Giorgi%2C%20J.%20Combet%2C%20G.%20Fleith%2C%20E.%20Mathieu%2C%20N.%20Kharouf%2C%20L.%20Kocgozlu%2C%20B.%20Heinrich%2C%20D.%20Favier%2C%20M.%20Brender%2C%20F.%20Boulmedais%2C%20P.%20Schaaf%2C%20B.%20Frisch%2C%20P.%20Lavalle%2C%20Salt-Compact%20Albumin%20as%20a%20New%20Pure%20Protein-based%20Biomaterials%3A%20From%20Design%20to%20In%20Vivo%20Studies%2C%20Advanced%20Healthcare%20Materials%20%282025%29%202403385.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadhm.202403385%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadhm.202403385%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Salt-Compact%20Albumin%20as%20a%20New%20Pure%20Protein-based%20Biomaterials%3A%20From%20Design%20to%20In%20Vivo%20Studies%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Eya%22%2C%22lastName%22%3A%22Aloui%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jordan%22%2C%22lastName%22%3A%22Beurton%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Claire%22%2C%22lastName%22%3A%22Medemblik%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ludivine%22%2C%22lastName%22%3A%22Hugoni%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Igor%22%2C%22lastName%22%3A%22Clarot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ariane%22%2C%22lastName%22%3A%22Boudier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Youri%22%2C%22lastName%22%3A%22Arntz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marcella%22%2C%22lastName%22%3A%22De%20Giorgi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jerome%22%2C%22lastName%22%3A%22Combet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Fleith%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Eric%22%2C%22lastName%22%3A%22Mathieu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Naji%22%2C%22lastName%22%3A%22Kharouf%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Leyla%22%2C%22lastName%22%3A%22Kocgozlu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Damien%22%2C%22lastName%22%3A%22Favier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Michael%22%2C%22lastName%22%3A%22Brender%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fouzia%22%2C%22lastName%22%3A%22Boulmedais%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pierre%22%2C%22lastName%22%3A%22Schaaf%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Frisch%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%22%2C%22lastName%22%3A%22Lavalle%22%7D%5D%2C%22abstractNote%22%3A%22Current%20biodegradable%20materials%20are%20facing%20many%20challenges%20when%20used%20for%20the%20design%20of%20implantable%20devices%20because%20of%20shortcomings%20such%20as%20toxicity%20of%20crosslinking%20agents%20and%20degradation%20derivatives%2C%20limited%20cell%20adhesion%2C%20and%20limited%20immunological%20compatibility.%20Here%2C%20a%20class%20of%20materials%20built%20entirely%20of%20stable%20protein%20is%20designed%20using%20a%20simple%20protocol%20based%20on%20salt-assisted%20compaction%20of%20albumin%2C%20breaking%20with%20current%20crosslinking%20strategies.%20Salt-assisted%20compaction%20is%20based%20on%20the%20assembly%20of%20albumin%20in%20the%20presence%20of%20high%20concentrations%20of%20specific%20salts%20such%20as%20sodium%20bromide.%20This%20process%20leads%2C%20surprisingly%2C%20to%20water-insoluble%20handable%20materials%20with%20high%20preservation%20of%20their%20native%20protein%20structures%20and%20Young%27s%20modulus%20close%20to%20that%20of%20cartilage%20%280.86%20MPa%29.%20Furthermore%2C%20these%20materials%20are%20non-cytotoxic%2C%20non-inflammatory%2C%20and%20in%20vivo%20implantations%20%28using%20models%20of%20mice%20and%20rabbits%29%20demonstrate%20a%20very%20slow%20degradation%20rate%20of%20the%20material%20with%20excellent%20biocompatibility%20and%20absence%20of%20systemic%20inflammation%20and%20implant%20failure.%20Therefore%2C%20these%20materials%20constitute%20promising%20candidates%20for%20the%20design%20of%20biodegradable%20scaffolds%20and%20drug%20delivery%20systems%20as%20an%20alternative%20to%20conventional%20synthetic%20degradable%20polyester%20materials.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fadhm.202403385%22%2C%22ISSN%22%3A%222192-2640%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fadhm.202403385%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%5D%2C%22dateModified%22%3A%222025-02-13T13%3A07%3A21Z%22%7D%7D%2C%7B%22key%22%3A%22LXU89JQK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bacq-Labreuil%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EB.%20Bacq-Labreuil%2C%20C.%20Fawaz%2C%20Y.%20Okazaki%2C%20Y.%20Obata%2C%20H.%20Cercellier%2C%20P.%20Le%20Fevre%2C%20F.%20Bertran%2C%20D.%20Santos-Cottin%2C%20H.%20Yamamoto%2C%20I.%20Yamada%2C%20M.%20Azuma%2C%20K.%20Horiba%2C%20H.%20Kumigashira%2C%20M.%20d%26%23x2019%3BAstuto%2C%20S.%20Biermann%2C%20B.%20Lenz%2C%20Universal%20Waterfall%20Feature%20in%20Cuprate%20Superconductors%3A%20Evidence%20of%20a%20Momentum-Driven%20Crossover%2C%20Physical%20Review%20Letters%20134%20%282025%29%20016502.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevLett.134.016502%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevLett.134.016502%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Universal%20Waterfall%20Feature%20in%20Cuprate%20Superconductors%3A%20Evidence%20of%20a%20Momentum-Driven%20Crossover%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benjamin%22%2C%22lastName%22%3A%22Bacq-Labreuil%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C%22%2C%22lastName%22%3A%22Fawaz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y%22%2C%22lastName%22%3A%22Okazaki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y%22%2C%22lastName%22%3A%22Obata%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H%22%2C%22lastName%22%3A%22Cercellier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P%22%2C%22lastName%22%3A%22Le%20Fevre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F%22%2C%22lastName%22%3A%22Bertran%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D%22%2C%22lastName%22%3A%22Santos-Cottin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H%22%2C%22lastName%22%3A%22Yamamoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22I%22%2C%22lastName%22%3A%22Yamada%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M%22%2C%22lastName%22%3A%22Azuma%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K%22%2C%22lastName%22%3A%22Horiba%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H%22%2C%22lastName%22%3A%22Kumigashira%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M%22%2C%22lastName%22%3A%22d%27Astuto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S%22%2C%22lastName%22%3A%22Biermann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B%22%2C%22lastName%22%3A%22Lenz%22%7D%5D%2C%22abstractNote%22%3A%22We%20study%20two%20related%20universal%20anomalies%20of%20the%20spectral%20function%20of%20cuprates%2C%20so-called%20waterfall%20and%20high-energy%20kink%20features%2C%20by%20a%20combined%20cellular%20dynamical%20mean-field%20theory%20and%20angle-resolved%20photoemission%20study%20for%20the%20oxychloride%20NaxCa2-xCuO2Cl2%20%28Na-CCOC%29.%20Tracing%20their%20origin%20back%20to%20an%20interplay%20of%20spin-polaron%20and%20local-correlation%20effects%20both%20in%20undoped%20and%20hole-doped%20%28Na-%29CCOC%2C%20we%20establish%20them%20as%20a%20universal%20crossover%20between%20regions%20differing%20in%20the%20momentum%20dependence%20of%20the%20coupling%20and%20not%20necessarily%20in%20the%20related%20quasiparticles%27%20energies.%20The%20proposed%20scenario%20extends%20to%20doping%20levels%20coinciding%20with%20the%20cuprate%27s%20superconducting%20dome%20and%20motivates%20further%20investigations%20of%20the%20fate%20of%20spin%20polarons%20in%20the%20superconducting%20phase.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevLett.134.016502%22%2C%22ISSN%22%3A%220031-9007%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2FPhysRevLett.134.016502%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22IUWT6S8X%22%5D%2C%22dateModified%22%3A%222025-04-14T13%3A21%3A41Z%22%7D%7D%2C%7B%22key%22%3A%22UL8FH7XH%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bakri%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EB.%20Bakri%2C%20N.%20Crouseilles%2C%20P.-A.%20Hervieux%2C%20X.%20Hong%2C%20G.%20Manfredi%2C%20Ultrafast%20dynamics%20of%20a%20spin-polarized%20electron%20plasma%20with%20magnetic%20ions%2C%20Journal%20of%20Plasma%20Physics%2091%20%282025%29%20E9.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1017%5C%2FS0022377824001594%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1017%5C%2FS0022377824001594%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ultrafast%20dynamics%20of%20a%20spin-polarized%20electron%20plasma%20with%20magnetic%20ions%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B%22%2C%22lastName%22%3A%22Bakri%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N%22%2C%22lastName%22%3A%22Crouseilles%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paul-Antoine%22%2C%22lastName%22%3A%22Hervieux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22X%22%2C%22lastName%22%3A%22Hong%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Giovanni%22%2C%22lastName%22%3A%22Manfredi%22%7D%5D%2C%22abstractNote%22%3A%22We%20construct%20a%20mean-field%20model%20that%20describes%20the%20nonlinear%20dynamics%20of%20a%20spin-polarized%20electron%20gas%20interacting%20with%20fixed%2C%20positively%20charged%20ions%20possessing%20a%20magnetic%20moment%20that%20evolves%20in%20time.%20The%20mobile%20electrons%20are%20modelled%20by%20a%20four-component%20distribution%20function%20in%20the%20two-dimensional%20phase%20space%20%24%28x%2Cv%29%24%2C%20obeying%20a%20Vlasov-Poisson%20set%20of%20equations.%20The%20ions%20are%20modelled%20by%20a%20Landau-Lifshitz%20equation%20for%20their%20spin%20density%2C%20which%20contains%20ion-ion%20and%20electron-ion%20magnetic%20exchange%20terms.%20We%20perform%20a%20linear%20response%20study%20of%20the%20coupled%20Vlasov-Poisson-Landau-Lifshitz%20%28VPLL%29%20equations%20for%20the%20case%20of%20a%20Maxwell-Boltzmann%20equilibrium%2C%20focussing%20in%20particular%20on%20the%20spin%20dispersion%20relation.%20Conditions%20of%20stability%20or%20instability%20for%20the%20spin%20modes%20are%20identified%2C%20which%20depend%20essentially%20on%20the%20electron%20spin%20polarization%20rate%20%24%5C%5Ceta%24%20and%20the%20electron-ion%20magnetic%20coupling%20constant%20%24K%24.%20We%20also%20develop%20an%20Eulerian%20grid-based%20computational%20code%20for%20the%20fully%20nonlinear%20VPLL%20equations%2C%20based%20on%20the%20geometric%20Hamiltonian%20method%20first%20developed%20by%20Crouseilles%20et%20al.%20%28J.%20Plasma%20Phys.%2C%20vol.%2089%2C%20no.%202%2C%202023%2C%20p.%20905890215%29.%20This%20technique%20allows%20us%20to%20achieve%20great%20accuracy%20for%20the%20conserved%20quantities%2C%20such%20as%20the%20modulus%20of%20the%20ion%20spin%20vector%20and%20the%20total%20energy.%20Numerical%20tests%20in%20the%20linear%20regime%20are%20in%20accordance%20with%20the%20estimations%20of%20the%20linear%20response%20theory.%20For%20two-stream%20equilibria%2C%20we%20study%20the%20interplay%20of%20instabilities%20occurring%20in%20both%20the%20charge%20and%20the%20spin%20sectors.%20The%20set%20of%20parameters%20used%20in%20the%20simulations%2C%20with%20densities%20close%20to%20those%20of%20solids%20%28%24%7B%5C%5Capprox%20%7D10%3C%5E%3E%7B29%7D%5C%5C%20%7B%5C%5Crm%20m%7D%3C%5E%3E%7B-3%7D%24%29%20and%20temperatures%20of%20the%20order%20of%2010%20eV%2C%20may%20be%20relevant%20to%20the%20warm%20dense%20matter%20regime%20appearing%20in%20some%20inertial%20fusion%20experiments.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1017%5C%2FS0022377824001594%22%2C%22ISSN%22%3A%220022-3778%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1017%5C%2FS0022377824001594%22%2C%22collections%22%3A%5B%2288PVNMDA%22%2C%22CHW2VGSR%22%5D%2C%22dateModified%22%3A%222025-02-11T15%3A51%3A02Z%22%7D%7D%2C%7B%22key%22%3A%224VMJW99T%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bes%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20Bes%2C%20S.%20Lamont%2C%20A.%20Dufour-Lamartinie%2C%20J.-C.%20Mancer%2C%20L.%20Olanier%2C%20J.%20Robert%2C%20F.%20Vernerey%2C%20A.%20Kovalenko%2C%20%26%23x201C%3BMagnetic%20marshmallows%26%23x201D%3B%20for%20soft%20robotics%3A%20magneto-mechanical%20characterization%20and%20application%20in%20switchable%20adhesion%20structures%2C%20Soft%20Matter%20Early%20access%20%282025%29.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4sm01503g%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4sm01503g%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22%5C%22Magnetic%20marshmallows%5C%22%20for%20soft%20robotics%3A%20magneto-mechanical%20characterization%20and%20application%20in%20switchable%20adhesion%20structures%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maxime%22%2C%22lastName%22%3A%22Bes%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Samuel%22%2C%22lastName%22%3A%22Lamont%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Azadeh%22%2C%22lastName%22%3A%22Dufour-Lamartinie%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Claude%22%2C%22lastName%22%3A%22Mancer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ludovic%22%2C%22lastName%22%3A%22Olanier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jerome%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Franck%22%2C%22lastName%22%3A%22Vernerey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Artem%22%2C%22lastName%22%3A%22Kovalenko%22%7D%5D%2C%22abstractNote%22%3A%22Soft%20magnetic%20composites%20exhibit%20fast%20and%20programmable%20macroscopic%20deformations%20in%20magnetic%20fields%2C%20making%20them%20promising%20for%20applications%20in%20soft%20untethered%20robotics%20or%20in%20designing%20surfaces%20with%20switchable%20adhesion%20or%20wetting%20properties.%20However%2C%20due%20to%20the%20incompressible%20nature%20of%20soft%2C%20non-porous%20actuators%2C%20their%20compression%20or%20elongation%20leads%20to%20important%20shape%20change%20due%20to%20lateral%20expansion%20or%20compression%2C%20respectively.%20In%20practice%2C%20bending%20and%20folding%20remain%20preferred%20actuation%20modes.%20Here%2C%20we%20explore%20the%20potential%20of%20magnetic%20elastomer%20%5C%22marshmallows%5C%22%20as%20compressible%20actuators%20with%20low%20Poisson%27s%20ratio.%20Using%20a%20sacrificial%20salt%20pellet%20template%20method%2C%20we%20fabricate%20polydimethylsiloxane%20foams%20with%20open%20porosity%20filled%20with%20carbonyl%20iron%20particles.%20The%20obtained%20foams%20exhibit%20strong%20reversible%20compression%20under%20the%20influence%20of%20a%20magnetic%20field%20gradient.%20We%20reveal%20the%20significance%20of%20stress%20accumulation%20in%20the%20direction%20of%20the%20field%20gradient%20due%20to%20magnetic%20body%20forces%20and%20the%20key%20role%20of%20the%20foam%20thickness%20in%20magnetic%20strain.%20We%20propose%20a%20simple%20analytical%20model%20based%20on%20the%20action%20of%20a%20magnetic%20body%20force%20that%20explains%20these%20effects.%20Finally%2C%20we%20demonstrate%20the%20development%20of%20a%20novel%20switchable%20adhesion%20structure%2C%20in%20which%20the%20magnetic%20foam%20covered%20with%20a%20pressure-sensitive%20adhesive%20serves%20as%20a%20compressible%20actuator%20able%20to%20switch%20between%20adhesive%20and%20non-adhesive%20states.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd4sm01503g%22%2C%22ISSN%22%3A%221744-683X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd4sm01503g%22%2C%22collections%22%3A%5B%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T12%3A07%3A43Z%22%7D%7D%2C%7B%22key%22%3A%22YS6YIIZI%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bharwal%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.K.%20Bharwal%2C%20J.P.%20Briggs%2C%20C.%20Tamin%2C%20M.%20Hanauer%2C%20R.%20Vollondat%2C%20J.%20Bartringer%2C%20S.%20Roques%2C%20C.%20Chevalier%2C%20A.%20Dinia%2C%20R.T.%20Collins%2C%20A.%20Slaoui%2C%20T.%20Fix%2C%20Enhancing%20Morphological%20and%20Optoelectronic%20Properties%20of%20Silicon%20Clathrate%20Films%20through%20Thermal%20Press%20Annealing%20and%20SF6%20Treatment%2C%20ACS%20Applied%20Energy%20Materials%208%20%282025%29%201752%26%23x2013%3B1758.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsaem.4c02915%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsaem.4c02915%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Enhancing%20Morphological%20and%20Optoelectronic%20Properties%20of%20Silicon%20Clathrate%20Films%20through%20Thermal%20Press%20Annealing%20and%20SF6%20Treatment%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anil%20Kumar%22%2C%22lastName%22%3A%22Bharwal%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joseph%20P.%22%2C%22lastName%22%3A%22Briggs%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Charif%22%2C%22lastName%22%3A%22Tamin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maxime%22%2C%22lastName%22%3A%22Hanauer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Romain%22%2C%22lastName%22%3A%22Vollondat%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jeremy%22%2C%22lastName%22%3A%22Bartringer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Roques%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Celine%22%2C%22lastName%22%3A%22Chevalier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aziz%22%2C%22lastName%22%3A%22Dinia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Reuben%20T.%22%2C%22lastName%22%3A%22Collins%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Abdelilah%22%2C%22lastName%22%3A%22Slaoui%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Fix%22%7D%5D%2C%22abstractNote%22%3A%22Although%20silicon%20clathrates%20were%20discovered%20about%2060%20years%20ago%2C%20there%20has%20been%20little%20research%20on%20diverse%20applications%20of%20such%20materials%20beyond%20thermoelectrics.%20With%20a%20direct%20bandgap%20of%20about%201.7%20eV%20and%20given%20the%20advantages%20of%20the%20silicon%20element%20such%20as%20abundance%2C%20nontoxicity%20and%20stability%2C%20silicon%20clathrates%20hold%20potential%20for%20use%20in%20photovoltaics%20and%20optoelectronics.%20Additionally%2C%20due%20to%20their%20unique%20cage%20structure%20that%20can%20store%20and%20release%20sodium%20atoms%20with%20minimal%20lattice%20parameter%20changes%2C%20they%20are%20promising%20for%20battery%20applications.%20However%2C%20issues%20like%20nonhomogeneity%2C%20defects%2C%20and%20poor%20density%20in%20clathrate%20films%20have%20hindered%20such%20applications.%20We%20provide%20in%20this%20work%20substantial%20pathways%20to%20mitigate%20such%20issues%20with%20the%20use%20of%20SF6%20etching%20and%20thermal%20press%20annealing%2C%20enabling%20an%20improvement%20of%20the%20optoelectronic%20properties%2C%20by%20a%20factor%20of%207%20as%20observed%20by%20the%20surface%20photovoltage%20technique.%20The%20photovoltage%20response%20of%20above%20200%20mV%20at%200.2%20sun%20being%20above%20key%20photovoltaic%20thin%20film%20absorbers%20such%20as%20CIGS%20and%20rivaling%20III-V%20semiconductors%20such%20as%20GaAs.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facsaem.4c02915%22%2C%22ISSN%22%3A%222574-0962%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facsaem.4c02915%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222025-02-12T08%3A41%3A49Z%22%7D%7D%2C%7B%22key%22%3A%224V6WTMCP%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Blumer%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EP.%20Blumer%2C%20M.%20Charlton%2C%20M.%20Chung%2C%20P.%20Clade%2C%20P.%20Comini%2C%20P.%20Crivelli%2C%20O.%20Dalkarov%2C%20P.%20Debu%2C%20L.%20Dodd%2C%20A.%20Douillet%2C%20S.%20Guellati%2C%20P.-A.%20Hervieux%2C%20L.%20Hilico%2C%20A.%20Husson%2C%20P.%20Indelicato%2C%20G.%20Janka%2C%20S.%20Jonsell%2C%20J.P.%20Karr%2C%20B.H.%20Kim%2C%20E.S.%20Kim%2C%20S.K.%20Kim%2C%20Y.%20Ko%2C%20T.%20Kosinski%2C%20N.%20Kuroda%2C%20B.M.%20Latacz%2C%20B.%20Lee%2C%20H.%20Lee%2C%20J.%20Lee%2C%20A.M.M.%20Leite%2C%20K.%20Leveque%2C%20E.%20Lim%2C%20L.%20Liszkay%2C%20P.%20Lotrus%2C%20D.%20Lunney%2C%20G.%20Manfredi%2C%20B.%20Mansoulie%2C%20M.%20Matusiak%2C%20G.%20Mornacchi%2C%20V.%20Nesvizhevsky%2C%20F.%20Nez%2C%20S.%20Niang%2C%20R.%20Nishi%2C%20B.%20Ohayon%2C%20K.%20Park%2C%20N.%20Paul%2C%20P.%20Perez%2C%20S.%20Procureur%2C%20B.%20Radics%2C%20C.%20Regenfus%2C%20J.-M.%20Reymond%2C%20S.%20Reynaud%2C%20J.-Y.%20Rousse%2C%20O.%20Rousselle%2C%20A.%20Rubbia%2C%20J.%20Rzadkiewicz%2C%20Y.%20Sacquin%2C%20F.%20SchmidtKaler%2C%20M.%20Staszczak%2C%20K.%20Szymczyk%2C%20T.%20Tanaka%2C%20B.%20Tuchming%2C%20B.%20Vallage%2C%20A.%20Voronin%2C%20D.P.%20van%20der%20Werf%2C%20S.%20Wolf%2C%20D.%20Won%2C%20S.%20Wronka%2C%20Y.%20Yamazaki%2C%20K.H.%20Yoo%2C%20P.%20Yzombard%2C%20GBAR%20Collaboration%2C%20Corrigendum%20to%20%26%23x201C%3BPositron%20accumulation%20in%20the%20GBAR%20experiment%26%23x201D%3B%20%5BNucl.%20Inst.%20Method.%20Phys.%20Res.%20A%201040%20%282022%29%20167263%5D%2C%20Nuclear%20Instruments%20%26amp%3B%20Methods%20in%20Physics%20Research%20Section%20A-Accelerators%20Spectrometers%20Detectors%20and%20Associated%20Equipment%201070%20%282025%29%20169998.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.nima.2024.169998%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.nima.2024.169998%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Corrigendum%20to%20%5Cu201cPositron%20accumulation%20in%20the%20GBAR%20experiment%5Cu201d%20%5BNucl.%20Inst.%20Method.%20Phys.%20Res.%20A%201040%20%282022%29%20167263%5D%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Blumer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Charlton%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Chung%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Clade%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Comini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Crivelli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22O.%22%2C%22lastName%22%3A%22Dalkarov%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Debu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22L.%22%2C%22lastName%22%3A%22Dodd%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Douillet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Guellati%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paul-Antoine%22%2C%22lastName%22%3A%22Hervieux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22L.%22%2C%22lastName%22%3A%22Hilico%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Husson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Indelicato%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G.%22%2C%22lastName%22%3A%22Janka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Jonsell%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%20P.%22%2C%22lastName%22%3A%22Karr%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%20H.%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%20S.%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%20K.%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Ko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.%22%2C%22lastName%22%3A%22Kosinski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Kuroda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%20M.%22%2C%22lastName%22%3A%22Latacz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Lee%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Lee%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Lee%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%20M.%20M.%22%2C%22lastName%22%3A%22Leite%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Leveque%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Lim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22L.%22%2C%22lastName%22%3A%22Liszkay%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Lotrus%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D.%22%2C%22lastName%22%3A%22Lunney%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G.%22%2C%22lastName%22%3A%22Manfredi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Mansoulie%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Matusiak%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G.%22%2C%22lastName%22%3A%22Mornacchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22V.%22%2C%22lastName%22%3A%22Nesvizhevsky%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Nez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Niang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Nishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Ohayon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Park%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Paul%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Perez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Procureur%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Radics%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Regenfus%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%20-M.%22%2C%22lastName%22%3A%22Reymond%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Reynaud%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%20-Y.%22%2C%22lastName%22%3A%22Rousse%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22O.%22%2C%22lastName%22%3A%22Rousselle%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Rubbia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Rzadkiewicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Sacquin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22SchmidtKaler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Staszczak%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Szymczyk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.%22%2C%22lastName%22%3A%22Tanaka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Tuchming%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Vallage%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Voronin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D.%20P.%22%2C%22lastName%22%3A%22van%20der%20Werf%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Wolf%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D.%22%2C%22lastName%22%3A%22Won%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Wronka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Yamazaki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%20H.%22%2C%22lastName%22%3A%22Yoo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Yzombard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22name%22%3A%22GBAR%20Collaboration%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.nima.2024.169998%22%2C%22ISSN%22%3A%220168-9002%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.nima.2024.169998%22%2C%22collections%22%3A%5B%2288PVNMDA%22%2C%22CHW2VGSR%22%5D%2C%22dateModified%22%3A%222025-01-16T07%3A38%3A48Z%22%7D%7D%2C%7B%22key%22%3A%22M7NYREF6%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bolielyi%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EO.%20Bolielyi%2C%20V.%20Levytskyi%2C%20J.%20Wagler%2C%20K.O.%20Kvashnina%2C%20B.%20Kundys%2C%20A.%20Leithe-Jasper%2C%20R.%20Gumeniuk%2C%20Yb5Rh6Sn18%3A%20a%20valence%20fluctuating%20system%20with%20ultra-low%20thermal%20conductivity.%2C%20Dalton%20Transactions%2054%20%282025%29%20784%26%23x2013%3B796.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4dt02759k%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4dt02759k%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Yb5Rh6Sn18%3A%20a%20valence%20fluctuating%20system%20with%20ultra-low%20thermal%20conductivity.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Oleksandr%22%2C%22lastName%22%3A%22Bolielyi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Volodymyr%22%2C%22lastName%22%3A%22Levytskyi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jorg%22%2C%22lastName%22%3A%22Wagler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kristina%20O%22%2C%22lastName%22%3A%22Kvashnina%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bohdan%22%2C%22lastName%22%3A%22Kundys%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andreas%22%2C%22lastName%22%3A%22Leithe-Jasper%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Roman%22%2C%22lastName%22%3A%22Gumeniuk%22%7D%5D%2C%22abstractNote%22%3A%22Yb5Rh6Sn18%20crystallizes%20with%20a%20unique%20structural%20arrangement%20%5Bspace%20group%20P42%5C%2Fnmc%2C%20a%20%3D%209.6997%284%29%20A%2C%20c%20%3D%2013.7710%287%29%20A%5D%2C%20which%20is%20related%20with%20primitive%20cubic%20Yb3Rh4Sn13%20and%20body-centered%20tetragonal%20%28Sn1-xTbx%29Tb4Rh6Sn18%20types.%20X-ray%20absorption%20spectroscopy%20showed%20that%20Yb%20atoms%20exhibit%20temperature-dependent%20valence%20fluctuations%20%28VF%29%20%28i.e.%2C%20intermediate%20valence%20state%29.%20Its%20complex%20mechanism%20is%20corroborated%20by%20the%20fact%20that%20the%20well-pronounced%20maximum%20in%20magnetic%20susceptibility%20can%20only%20be%20fairly%20described%20by%20the%20Bickers-Cox-Wilkins%20model%20developed%20for%20a%20J%20%3D%203%5C%2F2%20multiplet%2C%20atypical%20for%20Yb%20ions.%20Both%20Hall%20and%20Seebeck%20coefficients%20revealed%20a%20switch%20of%20the%20sign%2C%20indicating%20the%20change%20of%20charge%20carrier%20type%20from%20electrons%20to%20holes%20between%20120%20and%20220%20K.%20Both%20these%20effects%20together%20with%20electrical%20resistivity%20and%20theoretical%20DFT%20calculations%20confirm%20Yb5Rh6Sn18%20to%20be%20a%20metal%2C%20which%20disobeys%20the%20free%20electron%20gas%20theory.%20%27Rattling%27%20motion%20of%20Sn1%20atoms%20within%20the%20enlarged%2016-vertices%20distorted%20Frank-Kasper%20polyhedra%2C%20concluded%20from%20the%20specific%20heat%20measurements%2C%20is%20argued%20to%20be%20the%20main%20reason%20for%20the%20appearance%20of%20a%20phonon%20resonance%20behavior%2C%20resulting%20in%20an%20ultra-low%20thermal%20conductivity%20in%20the%20studied%20stannide.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd4dt02759k%22%2C%22ISSN%22%3A%221477-9234%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd4dt02759k%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%225T5YGD4D%22%5D%2C%22dateModified%22%3A%222025-02-11T15%3A45%3A40Z%22%7D%7D%2C%7B%22key%22%3A%2289GPPKHK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bulou%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EH.%20Bulou%2C%20Numerical%20Modeling%20of%20Healthcare%20Materials%2C%20JOM%20Early%20access%20%282025%29.%20%3Ca%20class%3D%27zp-ItemURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs11837-025-07318-x%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs11837-025-07318-x%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Numerical%20Modeling%20of%20Healthcare%20Materials%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Herv%5Cu00e9%22%2C%22lastName%22%3A%22Bulou%22%7D%5D%2C%22abstractNote%22%3A%22Healthcare%20materials%2C%20whether%20natural%20or%20synthetic%2C%20consist%20of%20intricate%20structures%20formed%20from%20simpler%20components.%20Due%20to%20their%20complex%20structure%2C%20composite%20materials%20are%20optimal%20for%20prosthetics%20as%20their%20properties%20may%20be%20adjusted%20to%20align%20with%20those%20of%20bone%2C%20hence%20promoting%20biointegration.%20For%20optimal%20efficacy%2C%20implants%20must%20be%20appropriately%20tailored%20to%20the%20host%2C%20requiring%20comprehensive%20control%20of%20both%20the%20implant%20design%20and%20its%20progression%20over%20time%20during%20utilization.%20For%20composite%20implants%2C%20it%20is%20essential%20to%20maintain%20material%20control%20at%20the%20macroscopic%20level%20during%20the%20shaping%20process%20while%20simultaneously%20ensuring%20the%20quality%20of%20the%20interface%2C%20which%20is%20influenced%20by%20nanoscale%20phenomena.%20This%20study%20demonstrates%20that%20the%20issue%20can%20be%20addressed%20using%20a%20multi-scale%20strategy%2C%20wherein%20numerical%20modeling%20serves%20as%20an%20effective%20tool.%20We%20describe%20the%20implementation%20of%20the%20approach%20and%20present%20the%20main%20methods%20and%20concepts%20involved%20in%20modeling%20composite%20biomaterials.%20Subsequently%2C%20we%20present%20a%20specific%20illustration%20of%20the%20protocol%20by%20discussing%20the%20initial%20phase%20of%20the%20recently%20developed%20%5Cu201cgrafting%20from%5Cu201d%20technique%20for%20fabricating%20implants%20using%20hybrid%20biomaterials.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1007%5C%2Fs11837-025-07318-x%22%2C%22ISSN%22%3A%221543-1851%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs11837-025-07318-x%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22ISRWITRA%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T12%3A29%3A56Z%22%7D%7D%2C%7B%22key%22%3A%22M3RMQJCT%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22D%27Al%5Cu00e9o%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20D%26%23x2019%3BAl%26%23xE9%3Bo%2C%20X.%20Tang%2C%20D.-H.%20Kim%2C%20D.%20Valverde%2C%20E.%20Zaborova%2C%20G.%20Canard%2C%20A.%20Brosseau%2C%20L.%20Mager%2C%20G.%20Clavier%2C%20C.%20Adachi%2C%20Y.%20Olivier%2C%20J.-C.%20Ribierre%2C%20Curcuminoid%20Derivatives%20with%20a%20Donor-Acceptor-Donor%20Architecture%3A%20an%20Outstanding%20Platform%20for%20Highly-Efficient%20Near-Infrared%20Electroluminescence%20and%20Amplified%20Spontaneous%20Emission%2C%20Advanced%20Optical%20Materials%20Early%20access%20%282025%29%202500338.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadom.202500338%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadom.202500338%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Curcuminoid%20Derivatives%20with%20a%20Donor-Acceptor-Donor%20Architecture%3A%20an%20Outstanding%20Platform%20for%20Highly-Efficient%20Near-Infrared%20Electroluminescence%20and%20Amplified%20Spontaneous%20Emission%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anthony%22%2C%22lastName%22%3A%22D%27Al%5Cu00e9o%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xun%22%2C%22lastName%22%3A%22Tang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dae-Hyeon%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Danillo%22%2C%22lastName%22%3A%22Valverde%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Elena%22%2C%22lastName%22%3A%22Zaborova%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gabriel%22%2C%22lastName%22%3A%22Canard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Arnaud%22%2C%22lastName%22%3A%22Brosseau%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lo%5Cu00efc%22%2C%22lastName%22%3A%22Mager%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gilles%22%2C%22lastName%22%3A%22Clavier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chihaya%22%2C%22lastName%22%3A%22Adachi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoann%22%2C%22lastName%22%3A%22Olivier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Charles%22%2C%22lastName%22%3A%22Ribierre%22%7D%5D%2C%22abstractNote%22%3A%22Abstract%20The%20development%20of%20high-efficiency%20near-infrared%20%28NIR%29%20emitters%20for%20organic%20light-emitting%20diodes%20%28OLEDs%29%20and%20organic%20semiconductor%20lasers%20has%20become%20an%20important%20target%20in%20organic%20photonics.%20Herein%2C%20it%20is%20demonstrated%20that%20donor-acceptor-donor%20borondifluoride%20curcuminoid%20derivatives%20represent%20a%20versatile%20and%20simple%20platform%20for%20the%20molecular%20engineering%20of%20high-efficiency%20NIR%20emitters%20combining%20thermally-activated%20delayed%20fluorescence%20%28TADF%29%20with%20excellent%20electroluminescence%20properties%20and%20amplified%20spontaneous%20emission%20%28ASE%29%20activity.%20A%20series%20of%20donor-acceptor-donor%20curcuminoid%20compounds%20containing%20triphenylamino-substituents%20for%20the%20donor%20side%20groups%20and%20various%20acceptor%20units%20in%20the%20meso%20position%20were%20designed%20and%20synthesized.%20The%20investigation%20of%20the%20effects%20of%20the%20molecular%20structure%20on%20the%20TADF%20properties%20show%20that%20the%20nature%20of%20the%20substituents%20enables%20a%20fine%20tuning%20of%20the%20emission%20wavelengths%20while%20maintaining%20high%20photoluminescence%20quantum%20yield%20values.%20These%20NIR%20TADF%20dyes%20were%20used%20in%20OLEDs%20with%20an%20external%20quantum%20efficiency%20of%20almost%201%25%20for%20a%20maximum%20emission%20wavelength%20of%20797%20nm.%20They%20also%20show%20a%20low%20threshold%20tuneable%20amplified%20spontaneous%20emission%20between%20725%20and%20900%20nm.%20Overall%2C%20this%20study%20provides%20new%20essential%20insights%20to%20rationalize%20the%20TADF%20activity%20of%20this%20family%20of%20NIR%20emitters%20and%20offers%20important%20prospects%20for%20designing%20the%20next%20generation%20of%20NIR%20TADF-OLEDs%20and%20organic%20semiconductor%20laser%20materials.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadom.202500338%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fadvanced.onlinelibrary.wiley.com%5C%2Fdoi%5C%2Fabs%5C%2F10.1002%5C%2Fadom.202500338%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22VYTETDZF%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-24T11%3A58%3A01Z%22%7D%7D%2C%7B%22key%22%3A%22WP55MQYF%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22de%20Domingo%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EE.%20de%20Domingo%2C%20G.%20Garcia%2C%20E.%20Tritto%2C%20B.%20Donnio%2C%20A.%20Shah%2C%20D.P.%20Singh%2C%20S.%20Coco%2C%20Self-assembly%20and%20ambipolar%20charge%20transport%20in%20columnar%20phases%20of%20polynuclear%20gold%20isocyano-triphenylene%20complexes%2C%20Journal%20of%20Materials%20Chemistry%20C%20Early%20access%20%282025%29.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd5tc00575b%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd5tc00575b%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Self-assembly%20and%20ambipolar%20charge%20transport%20in%20columnar%20phases%20of%20polynuclear%20gold%20isocyano-triphenylene%20complexes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Estela%22%2C%22lastName%22%3A%22de%20Domingo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gregorio%22%2C%22lastName%22%3A%22Garcia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emiliano%22%2C%22lastName%22%3A%22Tritto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Asmita%22%2C%22lastName%22%3A%22Shah%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dharmendra%20Pratap%22%2C%22lastName%22%3A%22Singh%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Silverio%22%2C%22lastName%22%3A%22Coco%22%7D%5D%2C%22abstractNote%22%3A%22An%20uncommon%20approach%20to%20the%20synthesis%20of%20ambipolar%20semiconductors%20based%20on%20di-%20and%20tri-nuclear%20gold%20isocyano-triphenylene%20complexes%20of%20the%20formula%20%5B%28AuX%29n%28CN-C6H4-O-%28CH2%296%29n-TriPh%5D%20%28n%20%3D%202%2C%203%3B%20X%20%3D%20Cl%2C%20C%2000000000000000000%2000000000000000000%2000000000000000000%2001111111111111110%2000000000000000000%2001111111111111110%2000000000000000000%2001111111111111110%2000000000000000000%2000000000000000000%2000000000000000000%20C-Ph%29%20is%20described.%20Although%20mesomorphism%20has%20only%20been%20obtained%20with%20chloro%20derivatives%2C%20the%20trialkynyl%20complex%20has%20turned%20out%20to%20be%20a%20precursor%20of%20gold%20nanoparticles.%20The%20chloro%20complexes%20self-assemble%20in%20lamello-columnar%20phases%2C%20whose%20supramolecular%20organizations%20were%20confirmed%20by%20SAXS%5C%2FWAXS%20experiments.%20Both%20the%20tri%28chloro-gold%29%20and%20the%20di%28chloro-gold%29%20complexes%20display%20high%20ambipolar%20charge%20transport%20along%20the%20columnar%20stacking%20direction%2C%20either%20in%20the%20mesophase%20%28trichloro%20derivative%29%20or%20in%20the%20crystalline%20solid%20state%20%28dichloro%20complex%29.%20The%20analysis%20of%20ambipolar%20charge%20transport%20in%20the%20chloro-gold%20compounds%20has%20been%20performed%20using%20the%20time-of-flight%20%28ToF%29%20technique.%20The%20dichloro%20compound%20exhibits%20an%20ambipolar%20charge%20carrier%20mobility%20of%20the%20order%20of%2010-4%20cm2%20V-1%20s-1%2C%20whereas%20the%20trinuclear%20compound%20displays%20an%20ambipolar%20charge%20carrier%20mobility%20of%20the%20order%20of%2010-3%20cm2%20V-1%20s-1%2C%20which%20is%20attributed%20to%20the%20addition%20of%20a%20supplementary%20peripheral%20-NC-Au-Cl%20complex%20unit%2C%20offering%20a%20drift%20field%20to%20the%20charge%20carriers%20and%20a%20lower%20optical%20bandgap.%20Quantum%20chemical%20calculations%20show%20that%20the%20introduction%20of%20an%20additional%20-NC-Au-Cl%20fragment%20to%20the%20dinuclear%20complex%20to%20give%20the%20trinuclear%20derivative%20promotes%20a%20cofacial%20stacking%20of%20the%20molecules%2C%20which%20increases%20the%20mobility%20of%20the%20charge%20carriers%20of%20the%20system.%20Due%20to%20their%20ambipolar%20charge%20carrier%20mobility%2C%20the%20poly-nuclear%20gold%20isocyano-triphenylene%20complexes%20demonstrate%20their%20potential%20for%20use%20in%20organic%20electronics%20and%20optoelectronic%20devices.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd5tc00575b%22%2C%22ISSN%22%3A%222050-7526%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd5tc00575b%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22IEGKATUQ%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T12%3A22%3A05Z%22%7D%7D%2C%7B%22key%22%3A%22ASNXJ6VK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Diaa%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Diaa%2C%20N.%20El-Mahallawy%2C%20A.%20Carrad%26%23xF2%3B%2C%20Effect%20of%20Mg%20content%20on%20the%20microstructure%2C%20texture%2C%20and%20mechanical%20performance%20of%20hypoeutectic%20extruded%20Zn-Mg%20alloys%2C%20Journal%20of%20Alloys%20and%20Compounds%201010%20%282025%29%20177155.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jallcom.2024.177155%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jallcom.2024.177155%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Effect%20of%20Mg%20content%20on%20the%20microstructure%2C%20texture%2C%20and%20mechanical%20performance%20of%20hypoeutectic%20extruded%20Zn-Mg%20alloys%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22AA%22%2C%22lastName%22%3A%22Diaa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N%22%2C%22lastName%22%3A%22El-Mahallawy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Adele%22%2C%22lastName%22%3A%22Carrad%5Cu00f2%22%7D%5D%2C%22abstractNote%22%3A%22The%20effect%20of%20Mg%20addition%20on%20the%20microstructure%2C%20texture%2C%20and%20mechanical%20performance%20of%20two%20hypoeutectic%20ZnMg%20alloys%20with%200.68%20and%201.89%20wt%25%20Mg%20content%20was%20studied%20and%20compared%20to%20pure%20Zn%20after%20extrusion.%20The%20SEM%5C%2F%20EDX%2C%20EBSD%2C%20and%20XRD%20investigations%20were%20carried%20out%20to%20study%20the%20effect%20of%20alloying%20on%20%281%29%20phases%27%20composition%2C%20morphology%2C%20and%20size%20and%20%282%29%20crystallography%20of%20the%20grains%20and%20the%20dominating%20slip%20systems.%20Through%20the%20mentioned%20investigations%2C%20hypothesized%20strengthening%20mechanisms%20could%20be%20estimated%20to%20identify%20the%20contribution%20of%20solid%20solution%2C%20grain%20boundary%2C%20secondary%20phase%2C%20dislocation%2C%20and%20texture%20rations%20of%20strengthening%20to%20improve%20the%20overall%20calculated%20yield%20strength.%20Uniaxial%20tensile%20testing%20was%20performed%20to%20evaluate%20the%20ultimate%20tensile%20strength%20%28UTS%29%2C%20the%20yield%20tensile%20strength%20%28YTS0.2%20%25%29%2C%20and%20the%20elongation%20to%20failure%20%28Ef%29%20of%20the%20pure%20and%20alloyed%20Zn%20and%20to%20compare%20the%20yield%20tensile%20strength%20with%20the%20computed%20ones.%20The%20combined%20impacts%20of%20the%20bimodal%20grains%2C%20the%20solubility%20of%20Mg%2C%20favorable%20morphology%20and%20distribution%20of%20secondary%20phase%2C%20and%20weakened%20bimodal%20basal%20texture%20with%20simultaneous%20twin-non%20basal%20slip%20mode%20deformation%20mechanisms%20resulted%20in%20an%20extraordinary%20strength-ductility%20synergy%20of%20the%20as%20extruded%20Zn-0.68Mg%20alloy%20%28--326%20MPa%20and%20--16%20%25%29.%20The%20current%20research%20provides%20a%20new%20pathway%20for%20designing%20high-performance%20Zn-based%20alloys%20as%20an%20alternative%20loadbearing%20material%20for%20orthopedic%20implant%20applications.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jallcom.2024.177155%22%2C%22ISSN%22%3A%220925-8388%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.jallcom.2024.177155%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%5D%2C%22dateModified%22%3A%222025-02-11T15%3A56%3A18Z%22%7D%7D%2C%7B%22key%22%3A%22FRCPDHKQ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Duroux%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EG.%20Duroux%2C%20M.D.S.L.%20Mendes%2C%20I.%20Makarchuk%2C%20T.%20Lucante%2C%20C.%20Kiefer%2C%20S.%20Buffiere%2C%20F.%20Weill%2C%20W.%20Baaziz%2C%20T.%20Buffeteau%2C%20S.%20Nlate%2C%20R.%20Oda%2C%20P.%20Rosa%2C%20E.A.%20Hillard%2C%20B.P.%20Pichon%2C%20E.%20Pouget%2C%20Challenges%20in%20Chirality%20Induction%20in%20Iron%20Oxide%20Nanoparticles%3A%20In%20Situ%20vs%20Ex%20Situ%20Growth%20on%20Helical%20Nanoplatforms%2C%20Crystal%20Growth%20%26amp%3B%20Design%2025%20%282025%29%20603%26%23x2013%3B611.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.cgd.4c01346%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.cgd.4c01346%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Challenges%20in%20Chirality%20Induction%20in%20Iron%20Oxide%20Nanoparticles%3A%20In%20Situ%20vs%20Ex%20Situ%20Growth%20on%20Helical%20Nanoplatforms%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gautier%22%2C%22lastName%22%3A%22Duroux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matheus%20De%20Souza%20Lima%22%2C%22lastName%22%3A%22Mendes%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Iryna%22%2C%22lastName%22%3A%22Makarchuk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Theo%22%2C%22lastName%22%3A%22Lucante%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Celine%22%2C%22lastName%22%3A%22Kiefer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sonia%22%2C%22lastName%22%3A%22Buffiere%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Weill%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Walid%22%2C%22lastName%22%3A%22Baaziz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thierry%22%2C%22lastName%22%3A%22Buffeteau%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvain%22%2C%22lastName%22%3A%22Nlate%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Reiko%22%2C%22lastName%22%3A%22Oda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patrick%22%2C%22lastName%22%3A%22Rosa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Elizabeth%20A.%22%2C%22lastName%22%3A%22Hillard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%20P.%22%2C%22lastName%22%3A%22Pichon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emilie%22%2C%22lastName%22%3A%22Pouget%22%7D%5D%2C%22abstractNote%22%3A%22The%20integration%20of%20chiral%20and%20magnetic%20properties%20has%20gained%20increasing%20interest%20due%20to%20its%20potential%20for%20enabling%20magneto-chiral%20phenomena.%20However%2C%20the%20development%20of%20nanoscale%20chiral%20systems%20that%20exhibit%20strong%20responsiveness%20to%20both%20light%20and%20magnetic%20fields%20remains%20largely%20underexplored.%20In%20this%20context%2C%20we%20investigate%20the%20use%20of%20silica%20nanohelices%20as%20a%20chiral%20platform%20for%20inducing%20circular%20dichroism%20%28CD%29%20in%20iron%20oxide%20nanoparticles%20%28NPs%29.%20Two%20strategies%20are%20compared%3A%20an%20ex%20situ%20approach%2C%20where%20the%20NPs%20are%20synthesized%20independently%20and%20then%20grafted%20onto%20the%20helices%2C%20and%20an%20in%20situ%20approach%2C%20where%20the%20NPs%20are%20directly%20formed%20on%20the%20surface%20of%20the%20helices.%20This%20comparison%20enables%20us%20to%20evaluate%20the%20chirality%20induction%20arising%20from%20helicoidal%20assembly%20versus%20chiral%20shape%2C%20respectively.%20The%20efficiency%20of%20each%20strategy%20was%20assessed%20by%20electronic%20CD%20%28ECD%29%20and%20magnetic%20CD%20%28MCD%29%20spectroscopies.%20The%20results%20show%20that%20chirality%20induction%20on%20iron%20oxide%20nanocrystals%20is%20negligible%20with%20the%20ex%20situ%20method%2C%20whereas%20weak%20but%20unambiguous%20ECD%20signals%20are%20observed%20following%20the%20in%20situ%20approach.%20Furthermore%2C%20a%20comparative%20analysis%20of%20chirality%20induction%20in%20magnetite%20%28Fe3O4%29%20vs.%20maghemite%20%28gamma-Fe2O3%29%20with%20both%20strategies%20is%20presented%20and%20discussed.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.cgd.4c01346%22%2C%22ISSN%22%3A%221528-7483%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.cgd.4c01346%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222025-02-17T12%3A59%3A43Z%22%7D%7D%2C%7B%22key%22%3A%22TBR48GPZ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22El%20Khabchi%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EL.%20El%20Khabchi%2C%20A.P.%20Corredor%2C%20F.%20Roulland%2C%20M.%20Lenertz%2C%20C.%20Leuvrey%2C%20J.%20Robert%2C%20G.%20Versini%2C%20L.%20Schlur%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20N.%20Viart%2C%20Solid-state%20synthesis%20of%20stoichiometric%20and%20dense%20CoV2O4%20targets%2C%20Journal%20of%20the%20European%20Ceramic%20Society%2045%20%282025%29%20117286.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jeurceramsoc.2025.117286%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jeurceramsoc.2025.117286%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Solid-state%20synthesis%20of%20stoichiometric%20and%20dense%20CoV2O4%20targets%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lamiae%22%2C%22lastName%22%3A%22El%20Khabchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Antonio%20Pena%22%2C%22lastName%22%3A%22Corredor%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marc%22%2C%22lastName%22%3A%22Lenertz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cedric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jerome%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gilles%22%2C%22lastName%22%3A%22Versini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Schlur%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22The%20CoV2O4%20%28CVO%29%20spinel%20is%20a%20magnetically%20frustrated%20compound%20for%20which%20thin%20films%2C%20with%20their%20associated%20substrate-induced%20strains%2C%20can%20bring%20challenging%20new%20magnetic%20structures.%20Research%20on%20CVO%20thin%20films%20remains%20scarce%20to%20date%2C%20probably%20hindered%20by%20the%20complex%20synthesis%20of%20CVO%20stoichiometric%20targets%20necessary%20for%20their%20deposition.%20The%20difficulty%20to%20have%20V%20in%20its%20%2BIII%20valence%20is%20a%20serious%20challenge.%20We%20present%20here%20a%20solid-state%20method%20for%20the%20production%20of%20polycrystalline%20stoichiometric%20single-phased%20and%20dense%20pellets%20of%20CVO.%20The%20procedure%20involves%20controlling%20the%20heat%20treatment%20atmospheres%20to%20ensure%20single-phased%20CoV2O4%20powder%20and%20homogenising%20grains%20size%20by%20attrition%20to%20promote%20dense%20pellet%20sintering.%20The%20significant%20density%20of%20the%20prepared%20pellets%20allows%20their%20use%20as%20targets%20for%20the%20growth%20of%20thin%20films%20by%20techniques%20such%20as%20pulsed%20laser%20deposition%20%28PLD%29%20or%20sputtering%20and%20opens%20the%20way%20to%20alternative%20thin%20films%20depositions.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jeurceramsoc.2025.117286%22%2C%22ISSN%22%3A%220955-2219%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.jeurceramsoc.2025.117286%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22TBP4QFHK%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T12%3A26%3A34Z%22%7D%7D%2C%7B%22key%22%3A%22D38C2PQR%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Ferrara%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EN.%20Ferrara%2C%20G.%20Giuliani%2C%20M.%20Maimaris%2C%20S.%20Prioli%2C%20M.%20Manathunga%2C%20L.%20Blancafort%2C%20J.%20L%26%23xE9%3Bonard%2C%20A.%20Cappelli%2C%20M.%20Olivucci%2C%20M.%20Paolino%2C%20Design%2C%20Synthesis%2C%20and%20Characterization%20of%20pH-Resettable%20Photoswitches%20Mimicking%20the%20GFP%20Fluorophore%20Structure.%2C%20Journal%20of%20Physical%20Chemistry%20B%20129%20%282025%29%202845%26%23x2013%3B2855.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpcb.4c07003%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpcb.4c07003%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Design%2C%20Synthesis%2C%20and%20Characterization%20of%20pH-Resettable%20Photoswitches%20Mimicking%20the%20GFP%20Fluorophore%20Structure.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicola%22%2C%22lastName%22%3A%22Ferrara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Germano%22%2C%22lastName%22%3A%22Giuliani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marios%22%2C%22lastName%22%3A%22Maimaris%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Salvatore%22%2C%22lastName%22%3A%22Prioli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Madushanka%22%2C%22lastName%22%3A%22Manathunga%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lluis%22%2C%22lastName%22%3A%22Blancafort%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jeremie%22%2C%22lastName%22%3A%22L%5Cu00e9onard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andrea%22%2C%22lastName%22%3A%22Cappelli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Massimo%22%2C%22lastName%22%3A%22Olivucci%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marco%22%2C%22lastName%22%3A%22Paolino%22%7D%5D%2C%22abstractNote%22%3A%22Light-controlled%20molecular%20switches%20based%20on%20double%20bond%20isomerization%20can%20represent%20classical%20binary%20systems%20in%20logic%20gates.%20Here%2C%20starting%20from%20the%20biomimetic%20photoswitch%201%20and%20combining%20computational%20and%20experimental%20techniques%2C%20we%20designed%20the%20insertion%20of%20a%20third%20control%20element%20%28the%20%5C%22reset%20button%5C%22%29%2C%20proposing%20an%20appropriate%20structural%20modification%20capable%20of%20altering%20the%20electronic%20distribution%20within%20the%20molecule.%20Thus%2C%20the%20substitution%20on%20the%20pyrrolidinone%20nitrogen%20atom%20of%201%20with%20a%20methane%20sulfonic%20%28in%202a%29%20or%20toluene%20sulfonic%20%28in%202b%29%20functional%20groups%20furnished%20molecules%20capable%20of%20alternating%20between%20two%20stable%20equilibrium%20forms%20by%20light%20irradiation.%20The%20addition%20of%20KOH%20deprotonates%20the%20phenolic%20moiety%20of%20the%20molecular%20photoswitches%2C%20providing%20systems%20in%20which%20the%20Z%20isomer%20becomes%20thermally%20unstable%20and%20spontaneously%20evolves%20into%20the%20starting%20E%20isomer.%20Re-establishing%20the%20initial%20phenolic%20form%20%28e.g.%2C%20by%20addition%20of%20acetic%20acid%29%2C%20the%20two%20molecules%20re-establish%20both%20isomers%20relative%20stability%20and%20their%20photochemical%20properties.%20These%20molecules%20represent%20a%20prototype%20of%20a%20potentially%20pH-resettable%20photoswitch%20with%20possible%20applications%20in%20pH-sensitive%20organic%20materials.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.jpcb.4c07003%22%2C%22ISSN%22%3A%221520-5207%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.jpcb.4c07003%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%2295EJ8IDX%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T12%3A26%3A26Z%22%7D%7D%2C%7B%22key%22%3A%22KCLZCVZA%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Fetida%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Fetida%2C%20O.%20Bengone%2C%20C.%20Goyhenex%2C%20F.%20Scheurer%2C%20R.%20Robles%2C%20N.%20Lorente%2C%20L.%20Limot%2C%20Molecular%20spin-probe%20sensing%20of%20H-mediated%20changes%20in%20Co%20nanomagnets.%2C%20Science%20Advances%2011%20%282025%29%20eads1456.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1126%5C%2Fsciadv.ads1456%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1126%5C%2Fsciadv.ads1456%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Molecular%20spin-probe%20sensing%20of%20H-mediated%20changes%20in%20Co%20nanomagnets.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alex%22%2C%22lastName%22%3A%22Fetida%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22Bengone%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christine%22%2C%22lastName%22%3A%22Goyhenex%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fabrice%22%2C%22lastName%22%3A%22Scheurer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Roberto%22%2C%22lastName%22%3A%22Robles%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Lorente%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Limot%22%7D%5D%2C%22abstractNote%22%3A%22The%20influence%20of%20hydrogen%20on%20magnetization%20is%20of%20substantial%20interest%20to%20spintronics.%20Understanding%20and%20controlling%20this%20phenomenon%20at%20the%20atomic%20scale%2C%20in%20particular%20in%20nanoscale%20systems%2C%20is%20crucial.%20In%20this%20study%2C%20we%20used%20scanning%20tunneling%20microscopy%20%28STM%29%20combined%20with%20a%20nickelocene%20molecule%20to%20sense%20the%20spin%20of%20a%20hydrogen-loaded%20nanoscale%20Co%20island%20grown%20on%20Cu%28111%29.%20Magnetic%20exchange%20maps%20obtained%20from%20the%20molecular%20tip%20revealed%20the%20presence%20of%20a%20hydrogen%20superstructure%20and%20a%2090%5Cu00b0%20rotation%20of%20the%20magnetization%20compared%20to%20the%20pristine%20island.%20Ab%20initio%20calculations%20corroborate%20these%20observations%2C%20indicating%20that%20hydrogen%20hybridization%20with%20Co%20atoms%20on%20the%20island%20surface%20drives%20the%20spin%20reorientation%20of%20the%20island.%20This%20reorientation%20is%20further%20reinforced%20by%20hydrogen%20penetration%20into%20the%20island%20that%20locates%20at%20the%20Co%5C%2FCu%20interface.%20However%2C%20the%20subsurface%20sensitivity%20of%20the%20magnetic%20exchange%20maps%20indicates%20that%20this%20effect%20is%20limited.%20Our%20study%20provides%20valuable%20microscopic%20insights%20into%20the%20chemical%20control%20of%20magnetism%20at%20the%20nanoscale.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1126%5C%2Fsciadv.ads1456%22%2C%22ISSN%22%3A%222375-2548%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1126%5C%2Fsciadv.ads1456%22%2C%22collections%22%3A%5B%229USMFXMV%22%2C%22DEB5KWFS%22%2C%22ISRWITRA%22%5D%2C%22dateModified%22%3A%222025-02-25T14%3A02%3A23Z%22%7D%7D%2C%7B%22key%22%3A%22WWUDTTR8%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Fortier%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EL.%20Fortier%2C%20C.%20Lefebvre%2C%20N.%20Hoffmann%2C%20Red%20light%20excitation%3A%20illuminating%20photocatalysis%20in%20a%20new%20spectrum.%2C%20Beilstein%20Journal%20of%20Organic%20Chemistry%2021%20%282025%29%20296%26%23x2013%3B326.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3762%5C%2Fbjoc.21.22%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3762%5C%2Fbjoc.21.22%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Red%20light%20excitation%3A%20illuminating%20photocatalysis%20in%20a%20new%20spectrum.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lucas%22%2C%22lastName%22%3A%22Fortier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corentin%22%2C%22lastName%22%3A%22Lefebvre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Norbert%22%2C%22lastName%22%3A%22Hoffmann%22%7D%5D%2C%22abstractNote%22%3A%22Red-light-activated%20photocatalysis%20has%20become%20a%20powerful%20approach%20for%20achieving%20sustainable%20chemical%20transformations%2C%20combining%20high%20efficiency%20with%20energy-saving%2C%20mild%20conditions.%20By%20harnessing%20the%20deeper%20penetration%20and%20selectivity%20of%20red%20and%20near-infrared%20light%2C%20this%20method%20minimizes%20the%20side%20reactions%20typical%20of%20higher-energy%20sources%2C%20making%20it%20particularly%20suited%20for%20large-scale%20applications.%20Recent%20advances%20highlight%20the%20unique%20advantages%20of%20both%20metal-based%20and%20metal-free%20catalysts%20under%20red-light%20irradiation%2C%20broadening%20the%20range%20of%20possible%20reactions%2C%20from%20selective%20oxidations%20to%20complex%20polymerizations.%20In%20biological%20contexts%2C%20red-light%20photocatalysis%20enables%20innovative%20applications%20in%20phototherapy%20and%20controlled%20drug%20release%2C%20exploiting%20its%20tissue%20penetration%20and%20low%20cytotoxicity.%20Together%2C%20these%20developments%20underscore%20the%20versatility%20and%20impact%20of%20red-light%20photocatalysis%2C%20positioning%20it%20as%20a%20cornerstone%20of%20green%20organic%20chemistry%20with%20significant%20potential%20in%20synthetic%20and%20biomedical%20fields.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.3762%5C%2Fbjoc.21.22%22%2C%22ISSN%22%3A%221860-5397%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222025-02-17T13%3A01%3A05Z%22%7D%7D%2C%7B%22key%22%3A%224HFRNU9Z%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Garifo%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.%20Garifo%2C%20D.%20Stanicki%2C%20T.%20Vangijzegem%2C%20P.%20Mellet%2C%20H.A.%20Girard%2C%20J.-C.%20Arnault%2C%20S.%20B%26%23xE9%3Bgin-Colin%2C%20Y.-M.%20Frapart%2C%20R.N.%20Muller%2C%20S.%20Laurent%2C%20Tailoring%20Nanodiamonds%20for%20High-Contrast%20EPR%20Imaging%3A%20Size%2C%20Surface%20Properties%2C%20and%20Spectroscopic%20Performance%2C%20Langmuir%20early%20access%20%282025%29.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.langmuir.4c05169%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.langmuir.4c05169%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Tailoring%20Nanodiamonds%20for%20High-Contrast%20EPR%20Imaging%3A%20Size%2C%20Surface%20Properties%2C%20and%20Spectroscopic%20Performance%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sarah%22%2C%22lastName%22%3A%22Garifo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dimitri%22%2C%22lastName%22%3A%22Stanicki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Vangijzegem%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%22%2C%22lastName%22%3A%22Mellet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hugues%20A.%22%2C%22lastName%22%3A%22Girard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Charles%22%2C%22lastName%22%3A%22Arnault%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22B%5Cu00e9gin-Colin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yves-Michel%22%2C%22lastName%22%3A%22Frapart%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Robert%20N.%22%2C%22lastName%22%3A%22Muller%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sophie%22%2C%22lastName%22%3A%22Laurent%22%7D%5D%2C%22abstractNote%22%3A%22Electron%20paramagnetic%20resonance%20%28EPR%29%20spectroscopy%20is%20a%20tool%20that%20provides%20sensitive%20detection%20of%20uncoupled%20electron%20spins%20for%20a%20variety%20of%20applications.%20This%20technique%20enables%20the%20specific%20detection%20and%20quantification%20of%20radical%20species%20while%20also%20being%20able%20of%20generating%20high-contrast%2C%20background-free%20images.%20However%2C%20the%20EPR%20labeling%20and%20imaging%20techniques%20encounter%20limitations%20mainly%20due%20to%20the%20instability%20of%20organic%20radicals%20from%20organic%20probes%2C%20which%20can%20influence%20the%20reliability%20and%20scope%20of%20the%20experiment.%20In%20that%20context%2C%20the%20use%20of%20nanodiamonds%20%28NDs%29%20in%20EPR%20may%20be%20a%20promising%20route%20for%20understanding%20their%20unique%20properties%20and%20potential%20biomedical%20applications.%20The%20ability%20to%20perform%20EPR%20imaging%20in%20combination%20with%20the%20stable%20intrinsic%20properties%20of%20paramagnetic%20centers%20within%20these%20particles%20raises%20the%20possibility%20of%20extending%20nanodiamond-based%20imaging%20capabilities.%20Herein%2C%20we%20present%20a%20preliminary%20demonstration%20of%20a%20practical%20spectroscopy%20and%20imaging%20application%20using%20nanosized%20diamond%20particles%20%28%3C18%20nm%29%20for%20electron%20paramagnetic%20resonance%20imaging%20%28EPRI%29.%20The%20discretization%20of%20two%20different%20nanodiamond%20production%20sources%20among%20the%20most%20studied%20NDs%20%28HPHT%20or%20detonation%29%20allows%20further%20characterization%20of%20their%20physicochemical%20properties.%20In%20addition%2C%20we%20have%20investigated%20variations%20in%20the%20physicochemical%20properties%20of%20nanodiamonds%2C%20including%20size%20effects%20and%20surface%20treatments.%20Finally%2C%20we%20provide%20experimental%20evidence%20of%20the%20conditions%20required%20for%20optimal%20spectroscopic%20and%20imaging%20resolution%20%28R%20%3C%201%20mm%29%20as%20well%20as%20achievable%20EPR%20sensitivity.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.langmuir.4c05169%22%2C%22ISSN%22%3A%220743-7463%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.langmuir.4c05169%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222025-02-25T14%3A47%3A58Z%22%7D%7D%2C%7B%22key%22%3A%22SS3H4A86%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Giuso%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EV.%20Giuso%2C%20T.%20Thierry%2C%20C.%20Gourlaouen%2C%20P.%20Mercandelli%2C%20N.%20Vanthuyne%2C%20M.%20Mauro%2C%20S.%20Bellemin-Laponnaz%2C%20A%20chiral%20Si%28iv%29%20complex%20bearing%20a%201%2C2%2C4-triazole-2%2C2%26%23x2032%3B-diphenol%20ligand%3A%20synthesis%2C%20%28chiro-%29optical%20properties%20and%20computational%20investigation%2C%20Dalton%20Transactions%20Early%20access%20%282025%29.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd5dt00392j%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd5dt00392j%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22A%20chiral%20Si%28iv%29%20complex%20bearing%20a%201%2C2%2C4-triazole-2%2C2%5Cu2032-diphenol%20ligand%3A%20synthesis%2C%20%28chiro-%29optical%20properties%20and%20computational%20investigation%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valerio%22%2C%22lastName%22%3A%22Giuso%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thibault%22%2C%22lastName%22%3A%22Thierry%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Gourlaouen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pierluigi%22%2C%22lastName%22%3A%22Mercandelli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Vanthuyne%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matteo%22%2C%22lastName%22%3A%22Mauro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%5D%2C%22abstractNote%22%3A%22The%20reactivity%20of%20bis-3%2C5-phenol%201-phenyl-1%2C2%2C4-triazole%2C%20a%20non-symmetrical%20tridentate%20O%3C%5E%3EN%3C%5E%3EO%20proligand%20derived%20from%20Deferasirox%2C%20towards%20a%20Si%28iv%29%20precursor%20is%20herein%20studied.%20The%20reaction%20of%20the%20proligand%20%28O1NO2%29H2%20with%20SiCl4%20afforded%20a%20highly%20stable%20homoleptic%20hexacoordinate%20complex%2C%20namely%20Si%28O1NO2%292%2C%20in%20high%20yield.%20While%20the%20emission%20profile%20of%20the%20proligand%20-%20arising%20from%20an%20excited-state%20intramolecular%20proton%20transfer%20%28ESIPT%29%20mechanism%20-%20appears%20featureless%20and%20broad%2C%20the%20Si%28iv%29%20complex%20exhibits%20enhanced%20photoluminescence%20in%20the%20violet-to-deep-blue%20region%2C%20with%20a%20quantum%20yield%20of%20up%20to%2032%25%20in%20spin-coated%20thin%20films.%20A%20comprehensive%20study%2C%20combining%20photophysical%20methods%20and%20%28time-dependent%29%20density%20functional%20theory%20%28TD-DFT%29%20calculations%2C%20has%20rationalized%20the%20emissive%20behavior%20of%20this%20complex.%20Due%20to%20the%20non-symmetrical%20nature%20of%20the%20ligand%2C%20the%20homoleptic%20Si%20complex%20is%20obtained%20as%20a%20racemate%20of%20two%20Delta%5C%2FLambda%20enantiomers%20that%20were%20separated%20by%20chiral%20chromatography%20and%20characterized%20by%20electronic%20circular%20dichroism%20%28ECD%29.%20Subsequent%20TD-DFT%20calculations%20enabled%20the%20modelling%20of%20the%20ECD%20spectra%20and%20the%20assignment%20of%20the%20absolute%20configuration%20of%20the%20resolved%20enantiomers.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd5dt00392j%22%2C%22ISSN%22%3A%221477-9226%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd5dt00392j%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T12%3A27%3A21Z%22%7D%7D%2C%7B%22key%22%3A%2228JIG4Z9%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Gubbiotti%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EG.%20Gubbiotti%2C%20A.%20Barman%2C%20S.%20Ladak%2C%20C.%20Bran%2C%20D.%20Grundler%2C%20M.%20Huth%2C%20H.%20Plank%2C%20G.%20Schmidt%2C%20S.%20van%20Dijken%2C%20R.%20Streubel%2C%20O.V.%20Dobrovolskiy%2C%20V.%20Scagnoli%2C%20L.J.%20Heyderman%2C%20C.%20Donnelly%2C%20O.%20Hellwig%2C%20L.%20Fallarino%2C%20M.B.%20Jungfleisch%2C%20A.%20Farhan%2C%20N.%20Maccaferri%2C%20P.%20Vavassori%2C%20P.%20Fischer%2C%20R.%20Tomasello%2C%20G.%20Finocchio%2C%20R.%20Clerac%2C%20R.%20Sessoli%2C%20D.%20Makarov%2C%20D.%20Sheka%2C%20M.%20Krawczyk%2C%20R.A.%20Gallardo%2C%20P.%20Landeros%2C%20M.%20d%26%23x2019%3BAquino%2C%20R.%20Hertel%2C%20P.%20Pirro%2C%20F.%20Ciubotaru%2C%20M.%20Becherer%2C%20J.%20Gartside%2C%20T.%20Ono%2C%20P.%20Bortolotti%2C%20A.%20Fernandez-Pacheco%2C%202025%20Roadmap%20on%203D%20Nano-magnetism.%2C%20Journal%20of%20Physics.%20Condensed%20Matter%2037%20%282025%29%20143502.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-648X%5C%2Fad9655%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-648X%5C%2Fad9655%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%222025%20Roadmap%20on%203D%20Nano-magnetism.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gianluca%22%2C%22lastName%22%3A%22Gubbiotti%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anjan%22%2C%22lastName%22%3A%22Barman%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sam%22%2C%22lastName%22%3A%22Ladak%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cristina%22%2C%22lastName%22%3A%22Bran%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dirk%22%2C%22lastName%22%3A%22Grundler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Michael%22%2C%22lastName%22%3A%22Huth%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Harald%22%2C%22lastName%22%3A%22Plank%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Georg%22%2C%22lastName%22%3A%22Schmidt%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sebastiaan%22%2C%22lastName%22%3A%22van%20Dijken%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Robert%22%2C%22lastName%22%3A%22Streubel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Oleksandr%20V%22%2C%22lastName%22%3A%22Dobrovolskiy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valerio%22%2C%22lastName%22%3A%22Scagnoli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laura%20J%22%2C%22lastName%22%3A%22Heyderman%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Claire%22%2C%22lastName%22%3A%22Donnelly%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olav%22%2C%22lastName%22%3A%22Hellwig%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lorenzo%22%2C%22lastName%22%3A%22Fallarino%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M%20Benjamin%22%2C%22lastName%22%3A%22Jungfleisch%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alan%22%2C%22lastName%22%3A%22Farhan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolo%22%2C%22lastName%22%3A%22Maccaferri%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paolo%22%2C%22lastName%22%3A%22Vavassori%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Peter%22%2C%22lastName%22%3A%22Fischer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Riccardo%22%2C%22lastName%22%3A%22Tomasello%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Giovanni%22%2C%22lastName%22%3A%22Finocchio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Rodolphe%22%2C%22lastName%22%3A%22Clerac%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Roberta%22%2C%22lastName%22%3A%22Sessoli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Denys%22%2C%22lastName%22%3A%22Makarov%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Denis%22%2C%22lastName%22%3A%22Sheka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maciej%22%2C%22lastName%22%3A%22Krawczyk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Rodolfo%20A%22%2C%22lastName%22%3A%22Gallardo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pedro%22%2C%22lastName%22%3A%22Landeros%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Massimiliano%22%2C%22lastName%22%3A%22d%27Aquino%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Riccardo%22%2C%22lastName%22%3A%22Hertel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philipp%22%2C%22lastName%22%3A%22Pirro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Florin%22%2C%22lastName%22%3A%22Ciubotaru%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Markus%22%2C%22lastName%22%3A%22Becherer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jack%22%2C%22lastName%22%3A%22Gartside%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Teruo%22%2C%22lastName%22%3A%22Ono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paolo%22%2C%22lastName%22%3A%22Bortolotti%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Amalio%22%2C%22lastName%22%3A%22Fernandez-Pacheco%22%7D%5D%2C%22abstractNote%22%3A%22The%20transition%20from%20planar%20%282D%29%20to%20three-dimensional%20%283D%29%20magnetic%20nanostructures%20represents%20a%20significant%20advancement%20in%20both%20fundamental%20research%20and%20practical%20applications%2C%20offering%20vast%20potential%20for%20next-generation%20technologies%20like%20ultrahigh-density%20storage%2C%20memory%2C%20logic%2C%20and%20neuromorphic%20computing.%20Despite%20being%20a%20relatively%20new%20field%2C%20the%20emergence%20of%203D%20nanomagnetism%20presents%20numerous%20opportunities%20for%20innovation%2C%20prompting%20the%20creation%20of%20a%20comprehensive%20roadmap%20by%20leading%20international%20researchers.%20This%20roadmap%20aims%20to%20facilitate%20collaboration%20and%20interdisciplinary%20dialogue%20to%20address%20challenges%20in%20materials%20science%2C%20physics%2C%20engineering%2C%20and%20computing.The%20roadmap%20comprises%20eighteen%20sections%2C%20roughly%20divided%20into%20three%20parts.%20The%20first%20section%20explores%20the%20fundamentals%20of%203D%20nanomagnetism%2C%20focusing%20on%20recent%20trends%20in%20fabrication%20techniques%20and%20imaging%20methods%20crucial%20for%20understanding%20complex%20spin%20textures%2C%20curved%20surfaces%2C%20and%20small-scale%20interactions.%20Techniques%20such%20as%20two-photon%20lithography%20and%20focused%20electron%20beam-induced%20deposition%20enable%20the%20creation%20of%20intricate%203D%20architectures%2C%20while%20advanced%20imaging%20methods%20like%20electron%20holography%20and%20Lorentz%20electron%20Ptychography%20provide%20sub-nanometer%20resolution%20for%20studying%20magnetization%20dynamics%20in%20three%20dimensions.%20Various%203D%20magnetic%20systems%2C%20including%20coupled%20multilayer%20systems%2C%20artificial%20spin%20ice%2C%20magneto-plasmonic%20systems%2C%20topological%20spin%20textures%2C%20and%20molecular%20magnets%2C%20are%20discussed.The%20second%20section%20introduces%20analytical%20and%20numerical%20methods%20for%20investigating%203D%20nanomagnetic%20structures%20and%20curvilinear%20systems%2C%20highlighting%20geometrically%20curved%20architectures%2C%20interconnected%20nanowire%20systems%2C%20and%20other%20complex%20geometries.%20Finite%20element%20methods%20are%20emphasized%20for%20capturing%20complex%20geometries%2C%20along%20with%20direct%20frequency%20domain%20solutions%20for%20addressing%20magnonic%20problems.The%20final%20section%20focuses%20on%203D%20magnonic%20crystals%20and%20networks%2C%20exploring%20their%20fundamental%20properties%20and%20potential%20applications%20in%20magnonic%20circuits%2C%20memory%2C%20and%20spintronics.%20Computational%20approaches%20using%203D%20nanomagnetic%20systems%20and%20complex%20topological%20textures%20in%203D%20spintronics%20are%20highlighted%20for%20their%20potential%20to%20enable%20faster%20and%20more%20energy-efficient%20computing.%26%23xD.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1088%5C%2F1361-648X%5C%2Fad9655%22%2C%22ISSN%22%3A%221361-648X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1088%5C%2F1361-648X%5C%2Fad9655%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22GA3EX26X%22%5D%2C%22dateModified%22%3A%222025-02-21T13%3A03%3A59Z%22%7D%7D%2C%7B%22key%22%3A%22RDEU4IEG%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Guchait%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.%20Guchait%2C%20S.%20Oummouch%2C%20P.%20Durand%2C%20N.%20Kamatham%2C%20B.%20Jismy%2C%20L.%20Herrmann%2C%20S.%20M%26%23xE9%3Bry%2C%20N.%20Leclerc%2C%20M.%20Brinkmann%2C%20Impact%20of%20Side%20Chain%20Chemical%20Structure%20on%20Doping%20and%20Thermoelectric%20Properties%20of%20Oriented%20PBTTT%20Thin%20Films.%2C%20Small%2021%20%282025%29%202410073.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fsmll.202410073%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fsmll.202410073%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Impact%20of%20Side%20Chain%20Chemical%20Structure%20on%20Doping%20and%20Thermoelectric%20Properties%20of%20Oriented%20PBTTT%20Thin%20Films.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shubhradip%22%2C%22lastName%22%3A%22Guchait%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Said%22%2C%22lastName%22%3A%22Oummouch%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pablo%22%2C%22lastName%22%3A%22Durand%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Narayanaswamy%22%2C%22lastName%22%3A%22Kamatham%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Badr%22%2C%22lastName%22%3A%22Jismy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Herrmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22M%5Cu00e9ry%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Leclerc%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Martin%22%2C%22lastName%22%3A%22Brinkmann%22%7D%5D%2C%22abstractNote%22%3A%22In%20this%20contribution%2C%20doping%20of%20oriented%20thin%20films%20is%20investigated%20for%20three%20PBTTT%20polymers%20bearing%20different%20side%20chains%20including%20linear%20alkyl%20%5Cu2500%28CH2%2912%5Cu2500H%2C%20single%20ether%20%5Cu2500%28CH2%297%5Cu2500O%5Cu2500%28CH2%294%5Cu2500H%20and%20alkyl-siloxane%20%5Cu2500%28CH2%295%5Cu2500%28Si%28CH3%292O%292%5Cu2500Si%28CH3%293%20A%20combination%20of%20transmission%20electron%20microscopy%2C%20polarized%20UV-vis-NIR%20spectroscopy%20and%20transport%20measurements%20helps%20uncover%20the%20essential%20role%20of%20the%20chemical%20nature%20of%20side%20chains%20on%20the%20efficacy%20of%20the%20doping%20and%20on%20the%20resulting%20thermoelectric%20performances%20in%20oriented%20PBTTT%20films.%20Siloxane%20side%20chains%20help%20to%20reach%20record%20alignment%20level%20of%20PBTTT%20with%20dichroic%20ratio%20beyond%2050%20for%20an%20optimized%20rubbing%20temperature%20but%20they%20impede%20effective%20doping%20of%20PBTTT%20crystals%20with%20F6TCNNQ%2C%20resulting%20in%20very%20poor%20TE%20properties.%20By%20contrast%2C%20doping%20the%20amorphous%20phase%20of%20all%20three%20PBTTTs%20with%20magic%20blue%20%28MB%29%20results%20in%20excellent%20TE%20performances.%20Both%2C%20chemical%20nature%20of%20side%20chains%20and%20semi-crystalline%20structure%20of%20the%20polymer%20determine%20the%20efficacy%20of%20doping.%20The%20use%20of%20siloxane%20side%20chains%20further%20impacts%20the%20scaling%20laws%20Ssigma-1%5C%2Fs%20between%20the%20Seebeck%20coefficient%20S%20and%20the%20charge%20conductivity%20sigma.%20An%20unexpected%20s%20%3D%202%20exponent%20is%20observed%20and%20tentatively%20attributed%20to%20the%20dimensionality%20of%20charge%20transport%20in%20the%20highly%20oriented%20mesophase%20of%20PBTTT.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fsmll.202410073%22%2C%22ISSN%22%3A%221613-6829%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22VYTETDZF%22%5D%2C%22dateModified%22%3A%222025-02-25T16%3A42%3A19Z%22%7D%7D%2C%7B%22key%22%3A%22IK2VBMHD%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Gupta%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ED.%20Gupta%2C%20M.%20Pankratova%2C%20M.%20Riepp%2C%20M.%20Pereiro%2C%20B.%20Sanyal%2C%20S.%20Ershadrad%2C%20M.%20Hehn%2C%20N.%20Pontius%2C%20C.%20Schuessler-Langeheine%2C%20R.%20Abrudan%2C%20N.%20Bergeard%2C%20A.%20Bergman%2C%20O.%20Eriksson%2C%20C.%20Boeglin%2C%20Tuning%20ultrafast%20demagnetization%20with%20ultrashort%20spin%20polarized%20currents%20in%20multi-sublattice%20ferrimagnets%2C%20Nature%20Communications%2016%20%282025%29%203097.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41467-025-58411-3%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41467-025-58411-3%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Tuning%20ultrafast%20demagnetization%20with%20ultrashort%20spin%20polarized%20currents%20in%20multi-sublattice%20ferrimagnets%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Deeksha%22%2C%22lastName%22%3A%22Gupta%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maryna%22%2C%22lastName%22%3A%22Pankratova%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matthias%22%2C%22lastName%22%3A%22Riepp%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Manuel%22%2C%22lastName%22%3A%22Pereiro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Biplab%22%2C%22lastName%22%3A%22Sanyal%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soheil%22%2C%22lastName%22%3A%22Ershadrad%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Michel%22%2C%22lastName%22%3A%22Hehn%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Niko%22%2C%22lastName%22%3A%22Pontius%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christian%22%2C%22lastName%22%3A%22Schuessler-Langeheine%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Radu%22%2C%22lastName%22%3A%22Abrudan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Bergeard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anders%22%2C%22lastName%22%3A%22Bergman%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olle%22%2C%22lastName%22%3A%22Eriksson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christine%22%2C%22lastName%22%3A%22Boeglin%22%7D%5D%2C%22abstractNote%22%3A%22Femtosecond%20laser%20pulses%20can%20be%20used%20to%20induce%20ultrafast%20changes%20of%20the%20magnetization%20in%20magnetic%20materials.%20Several%20microscopic%20mechanisms%20have%20been%20proposed%20to%20explain%20these%20observations%2C%20including%20the%20transport%20of%20ultrashort%20spin-polarized%20hot-electrons%20%28SPHE%29.%20However%2C%20currently%20such%20ultrafast%20spin%20currents%20are%20only%20poorly%20characterized%20due%20to%20the%20measurement%20requirements%20for%20element%20and%20time%20resolution.%20Here%2C%20using%20time-%20and%20element-resolved%20X-ray%20magnetic%20circular%20dichroism%20alongside%20atomistic%20spin-dynamics%20simulations%2C%20we%20study%20the%20ultrafast%20transfer%20of%20the%20angular%20momentum%20from%20spin-polarized%20currents.%20We%20show%20that%20using%20a%20Co%5C%2FPt%20multilayer%20as%20a%20polarizer%20in%20a%20spin-valve%20structure%2C%20the%20SPHE%20drives%20the%20demagnetization%20of%20the%20two%20sub-lattices%20of%20the%20Fe74Gd26%20film.%20This%20behaviour%20can%20be%20explained%20with%20two%20physical%20mechanisms%3B%20spin%20transfer%20torque%20and%20thermal%20fluctuations%20induced%20by%20the%20SPHE.%20We%20provide%20a%20quantitative%20description%20of%20the%20heat%20transfer%20of%20the%20ultrashort%20SPHE%20pulse%20to%20the%20Fe74Gd26%20films%2C%20as%20well%20as%20the%20effect%20of%20spin-polarization%20of%20the%20SPHE%20current%20density%20responsible%20for%20the%20observed%20magnetization%20dynamics.%20Our%20work%20finally%20characterizes%20the%20spin-polarization%20of%20the%20SPHEs%20revealing%20unexpected%20opposite%20spin%20polarization%20to%20the%20Co%20magnetization.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1038%5C%2Fs41467-025-58411-3%22%2C%22ISSN%22%3A%222041-1723%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1038%5C%2Fs41467-025-58411-3%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22MKAFAH44%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T12%3A28%3A36Z%22%7D%7D%2C%7B%22key%22%3A%22Z5QV2LL8%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Henning%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EX.%20Henning%2C%20L.%20Schlur%2C%20L.%20Wendling%2C%20T.%20Fix%2C%20S.%20Colis%2C%20A.%20Dinia%2C%20M.%20Alexe%2C%20M.V.%20Rastei%2C%20Interfacial%20photovoltaic%20effects%20in%20ferroelectric%20%5C%5CmathrmBi_2%5C%5CmathrmFeCrO_6%20thin%20films%2C%20Physical%20Review%20Materials%209%20%282025%29%20024403.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevMaterials.9.024403%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevMaterials.9.024403%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Interfacial%20photovoltaic%20effects%20in%20ferroelectric%20%5C%5CmathrmBi_2%5C%5CmathrmFeCrO_6%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xavier%22%2C%22lastName%22%3A%22Henning%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Schlur%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22L.%22%2C%22lastName%22%3A%22Wendling%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Fix%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Silviu%22%2C%22lastName%22%3A%22Colis%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aziz%22%2C%22lastName%22%3A%22Dinia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Alexe%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mircea%20V.%22%2C%22lastName%22%3A%22Rastei%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevMaterials.9.024403%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevMaterials.9.024403%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222025-02-13T15%3A39%3A36Z%22%7D%7D%2C%7B%22key%22%3A%223KR2PB88%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Herasymenko%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EK.%20Herasymenko%2C%20D.%20Walisinghe%2C%20M.%20Konno%2C%20L.%20Barneschi%2C%20I.%20de%20Waele%2C%20M.%20Sliwa%2C%20K.%20Inoue%2C%20M.%20Olivucci%2C%20S.%20Haacke%2C%20Archaerhodopsin%203%20is%20an%20ideal%20template%20for%20the%20engineering%20of%20highly%20fluorescent%20optogenetic%20reporters%2C%20Chemical%20Science%2016%20%282025%29%20761%26%23x2013%3B774.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4sc05120c%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4sc05120c%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Archaerhodopsin%203%20is%20an%20ideal%20template%20for%20the%20engineering%20of%20highly%20fluorescent%20optogenetic%20reporters%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Krystyna%22%2C%22lastName%22%3A%22Herasymenko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Danushka%22%2C%22lastName%22%3A%22Walisinghe%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masae%22%2C%22lastName%22%3A%22Konno%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Leonardo%22%2C%22lastName%22%3A%22Barneschi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Isabelle%22%2C%22lastName%22%3A%22de%20Waele%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Michel%22%2C%22lastName%22%3A%22Sliwa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Keiichi%22%2C%22lastName%22%3A%22Inoue%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Massimo%22%2C%22lastName%22%3A%22Olivucci%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stefan%22%2C%22lastName%22%3A%22Haacke%22%7D%5D%2C%22abstractNote%22%3A%22Archaerhodopsin-3%20%28AR-3%29%20variants%20stand%20out%20among%20other%20rhodopsins%20in%20that%20they%20display%20a%20weak%2C%20but%20voltage-sensitive%2C%20near-infrared%20fluorescence%20emission.%20This%20has%20led%20to%20their%20application%20in%20optogenetics%20both%20in%20cell%20cultures%20and%20small%20animals.%20However%2C%20in%20the%20context%20of%20improving%20the%20fluorescence%20characteristics%20of%20the%20next%20generation%20of%20AR-3%20reporters%2C%20an%20understanding%20of%20their%20ultrafast%20light-response%20in%20light-adapted%20conditions%2C%20is%20mandatory.%20To%20this%20end%2C%20we%20present%20a%20combined%20experimental%20and%20computational%20investigation%20of%20the%20excited%20state%20dynamics%20and%20quantum%20yields%20of%20AR-3%20and%20its%20DETC%20and%20Arch-5%20variants.%20The%20latter%20always%20display%20a%20mixture%20of%20all-trans%5C%2F15-anti%20and%2013-cis%5C%2F15-syn%20isomers%2C%20which%20leads%20to%20a%20bi-exponential%20excited%20state%20decay.%20The%20isomerisation%20quantum%20yield%20is%20reduced%20more%20than%2020%20times%20as%20compared%20to%20WT%20AR-3%20and%20proves%20that%20the%20steady-state%20fluorescence%20is%20induced%20by%20a%20single%20absorption%20photon%20event.%20In%20wild-type%20AR-3%2C%20we%20show%20that%20a%20300%20fs%2C%20barrier-less%20and%20vibrationally%20coherent%20isomerization%20is%20driven%20by%20an%20unusual%20covalent%20electronic%20character%20of%20its%20all-trans%20retinal%20chromophore%20leading%20to%20a%20metastable%20twisted%20diradical%20%28TIDIR%29%2C%20in%20clear%20contrast%20to%20the%20standard%20charge-transfer%20scenario%20established%20for%20other%20microbial%20rhodopsins.%20We%20discuss%20how%20the%20presence%20of%20TIDIR%20makes%20AR-3%20an%20ideal%20candidate%20for%20the%20design%20of%20variants%20with%20a%20one-photon%20induced%20fluorescence%20possibly%20reaching%20the%20emission%20quantum%20yield%20of%20the%20top%20natural%20emitter%20neorhodopsin%20%28NeoR%29.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd4sc05120c%22%2C%22ISSN%22%3A%222041-6520%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd4sc05120c%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%2295EJ8IDX%22%5D%2C%22dateModified%22%3A%222025-01-09T13%3A17%3A41Z%22%7D%7D%2C%7B%22key%22%3A%2248VIJ6FK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Jouaiti%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Jouaiti%2C%20L.%20Ballerini%2C%20W.-M.%20Zhang%2C%20F.%20Polo%2C%20C.%20Gourlaouen%2C%20H.-C.%20Su%2C%20M.%20Mauro%2C%20Tuning%20the%20Electroluminescence%20of%20Binuclear%20Copper%28I%29%20Emitters%20Into%20the%20NIR-I%20Region%2C%20Advanced%20Optical%20Materials%2013%20%282025%29%202402666.%20https%3A%5C%2F%5C%2Fdoi.org%5C%2F%3Ca%20class%3D%27zp-ItemURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadom.202402666%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadom.202402666%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Tuning%20the%20Electroluminescence%20of%20Binuclear%20Copper%28I%29%20Emitters%20Into%20the%20NIR-I%20Region%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Abdelaziz%22%2C%22lastName%22%3A%22Jouaiti%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lavinia%22%2C%22lastName%22%3A%22Ballerini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Wei-Min%22%2C%22lastName%22%3A%22Zhang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Federico%22%2C%22lastName%22%3A%22Polo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Gourlaouen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hai-Ching%22%2C%22lastName%22%3A%22Su%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matteo%22%2C%22lastName%22%3A%22Mauro%22%7D%5D%2C%22abstractNote%22%3A%22Abstract%20Optoelectronic%20devices%20that%20emit%20into%20the%20near%20infrared%20%28NIR%29%20region%20are%20appealing%20technologies%20with%20applications%20in%20optical%20communication%20and%20as%20disposable%2C%20lightweight%20and%20cheaper%20photodynamic%20biomedical%20devices.%20The%20development%20of%20efficient%20devices%20is%20currently%20hampered%20by%20the%20lack%20of%20suitable%20NIR-emissive%20materials.%20Achieving%20this%20goal%20is%20even%20more%20challenging%20when%20the%20use%20of%20non-toxic%2C%20earth-abundant%20metal%20complexes%20as%20electroactive%20materials%20is%20targeted.%20Herein%2C%20an%20enlarge%20family%20of%20binuclear%20Cu%28I%29%20emitters%20%28D1%5Cu2013D4%29%20bearing%20the%20bridging%20thiazolo%5B5%2C4-d%5Dthiazole%20scaffold%20is%20described%20along%20with%20their%20mononuclear%20counterparts%20%28M3%5Cu2013M4%29%2C%20which%20are%20synthetized%20and%20characterized%20comprehensively%20by%20a%20combination%20of%20chemical%2C%20spectroscopical%2C%20electrochemical%20and%20computational%20techniques.%20By%20means%20of%20an%20efficient%20dinuclearisation%20strategy%20in%20combination%20with%20the%20selective%20tuning%20of%20the%20%5Cu03c0-accepting%20feature%20of%20the%20lateral%20N-heterocyclic%20rings%20enabled%20modulation%20of%20photo-%20and%20electro-luminescence%20spectra%20into%20the%20NIR-I%20region.%20Light-emitting%20electrochemical%20cells%20%28LECs%29%20fabricated%20by%20employing%20the%20binuclear%20copper%20complexes%20displayed%20electroluminescence%20into%20the%20deep-red%20to%20NIR-I%20region.%20Remarkably%2C%20derivative%20D2%20shows%20the%20combination%20of%20%5Cu03bbEL%2Cmax%20up%20to%20782%20with%20a%20spectral%20profile%20squarely%20falling%20into%20the%20NIR%20region%2C%20excellent%20carrier%20balance%20and%20good%20EL%20performances%20among%20all%20types%20of%20emissive%20materials%20used%20for%20NIR%20LECs.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadom.202402666%22%2C%22ISSN%22%3A%222195-1071%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadom.202402666%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222025-04-15T07%3A52%3A02Z%22%7D%7D%2C%7B%22key%22%3A%22ULY6ZV6M%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Knapman%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ER.%20Knapman%2C%20M.%20Azhar%2C%20A.%20Pignedoli%2C%20L.%20Gallard%2C%20R.%20Hertel%2C%20J.%20Leliaert%2C%20K.%20Everschor-Sitte%2C%20Numerical%20calculation%20of%20the%20Hopf%20index%20for%20three-dimensional%20magnetic%20textures%2C%20Physical%20Review%20B%20111%20%282025%29%20134408.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.111.134408%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.111.134408%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Numerical%20calculation%20of%20the%20Hopf%20index%20for%20three-dimensional%20magnetic%20textures%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Knapman%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Azhar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Pignedoli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Louis%22%2C%22lastName%22%3A%22Gallard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Riccardo%22%2C%22lastName%22%3A%22Hertel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Leliaert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Everschor-Sitte%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.111.134408%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.111.134408%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22GA3EX26X%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T12%3A29%3A46Z%22%7D%7D%2C%7B%22key%22%3A%22ER6PGZZM%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Krieger%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EG.%20Krieger%2C%20C.-P.%20Su%2C%20H.%20Sahib%2C%20R.%20Fan%2C%20P.%20Steadman%2C%20A.%20Gloter%2C%20N.%20Viart%2C%20D.%20Preziosi%2C%20Tailoring%20the%20breathing-mode%20distortions%20in%20nickelate%5C%2Fferroelectric%20heterostructures%2C%20Journal%20of%20Applied%20Physics%20137%20%282025%29%20125301.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0255194%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0255194%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Tailoring%20the%20breathing-mode%20distortions%20in%20nickelate%5C%2Fferroelectric%20heterostructures%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Krieger%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chia-Ping%22%2C%22lastName%22%3A%22Su%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hoshang%22%2C%22lastName%22%3A%22Sahib%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Raymond%22%2C%22lastName%22%3A%22Fan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paul%22%2C%22lastName%22%3A%22Steadman%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alexandre%22%2C%22lastName%22%3A%22Gloter%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniele%22%2C%22lastName%22%3A%22Preziosi%22%7D%5D%2C%22abstractNote%22%3A%22In%20transition%20metal%20oxides%2C%20electron-electron%20interaction%20and%20lattice%20degree%20of%20freedom%20are%20basic%20ingredients%20of%20emergent%20phenomena%2C%20such%20as%20metal-to-insulator%20transition%20%28MIT%29%20and%20superconductivity.%20Perovskite%20rare-earth%20nickelates%20are%20largely%20studied%20for%20their%20temperature-driven%20MIT%2C%20which%20is%20accompanied%20by%20a%20breathing-mode%20distortion%20and%20associated%20with%20a%20bond-disproportionation%20of%20the%20expanded%20%283d%288%29L%280%29%29%20and%20compressed%20%283d%288%29L%282%29%29%20NiO6%20octahedra.%20Steric%20effects%20control%20the%20onset%20temperature%20of%20the%20MIT%2C%20the%20latter%20being%20concomitant%20or%20not%20with%20a%20complex%20antiferromagnetic%20spin%20arrangement%20depending%20upon%20the%20choice%20of%20the%20rare-earth%20ion%20%28T-MIT%20%3E%3D%20T-Neel%29.%20Interface%20engineering%20of%20oxygen%20octahedra%20tilting%2C%20as%20imposed%20by%20the%20symmetry%20and%20orientation%20of%20the%20substrate%2C%20has%20resulted%20in%20an%20efficient%20pathway%20to%20modify%20both%20T-MIT%20and%20T-Neel%2C%20hence%20suggesting%20a%20key%20role%20of%20the%20electron-phonon%20coupling%20for%20both%20transport%20and%20magnetic%20properties%20in%20nickelate%20thin%20films.%20Here%2C%20via%20a%20combination%20of%20resonant%20elastic%20x-ray%20scattering%20and%20transport%20experiments%2C%20we%20show%20control%20over%20both%20T-MIT%20and%20T-Neel%20in%20heteroepitaxial%20PbZr0.2Ti0.8O3%28d%29%5C%2FNdNiO3%287%20nm%29%5C%2F%5C%2FSrTiO3%20heterostructures%2C%20which%20are%20characterized%20by%20different%20strains%20and%20polarization%20states%20of%20the%20PbZr0.2Ti0.8O3%20layer%20grown%20at%20different%20thicknesses%20d.%20We%20found%20the%20expected%20NdNiO3%20bulk%20behavior%20%28T-MIT%20%3D%20T-Neel%29%2C%20for%20a%20fully%20relaxed%20PbZr0.2Ti0.8O3%20layer%20showing%20a%20monodomain%20polarization%20state.%20On%20the%20other%20side%2C%20an%20almost%2030%20K%20difference%20%28T-MIT%20%3E%20T-Neel%29%2C%20is%20found%20for%20a%20fully%20strained%20PbZr0.2Ti0.8O3%20characterized%20by%20a%20multidomain%20texture%20of%20the%20polarization%20state.%20We%20discuss%20our%20results%20in%20terms%20of%20an%20altered%20breathing%20distortion%20pattern%20of%20the%20underlying%20nickelate%20layer%20as%20supported%20by%20x-ray%20absorption%20spectroscopy%20measurements.%20We%20infer%20that%20locally%20different%20polar%20distortions%20controlled%20by%20a%20combination%20of%20polarization%20direction%20and%20strength%20of%20the%20strain%20state%20play%20the%20main%20role%20in%20the%20observed%20T-MIT%20and%20T-Neel%20variations.%20%28c%29%202025%20Author%28s%29.%20All%20article%20content%2C%20except%20where%20otherwise%20noted%2C%20is%20licensed%20under%20a%20Creative%20Commons%20Attribution%20%28CC%20BY%29%20license%28https%3A%5C%2F%5C%2Fcreativecommons.org%5C%2Flicenses%5C%2Fby%5C%2F4.0%5C%2F%29.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1063%5C%2F5.0255194%22%2C%22ISSN%22%3A%220021-8979%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1063%5C%2F5.0255194%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T12%3A31%3A01Z%22%7D%7D%2C%7B%22key%22%3A%22TJUJWS6W%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Le%20Roux%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.%20Le%20Roux%2C%20atomes%3A%20Analysis%2C%20visualization%2C%20edition%20and%20post-processing%20of%203D%20atomic%20scale%20models%2C%20Computational%20Materials%20Science%20253%20%282025%29%20113805.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.commatsci.2025.113805%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.commatsci.2025.113805%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22atomes%3A%20Analysis%2C%20visualization%2C%20edition%20and%20post-processing%20of%203D%20atomic%20scale%20models%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sebastien%22%2C%22lastName%22%3A%22Le%20Roux%22%7D%5D%2C%22abstractNote%22%3A%22atomes%20is%20a%20cross-platform%20open%20source%20program%20developed%20to%20analyze%2C%20to%20visualize%20and%20to%20edit%5C%2Fcreate%20large%20three-dimensional%20atomic%20scale%20models.%20By%20regrouping%20advanced%20analysis%20techniques%2C%203D%20visualization%20and%203D%20edition%2C%20atomes%20introduces%20innovative%203D%20rendering%20possibilities%20and%20intuitive%20applications%20of%20the%20calculation%20results.%20atomes%20also%20provides%20an%20advanced%20input%20preparation%20system%20for%20further%20calculations%20using%20well%20known%20classical%2C%20ab-initio%20and%20QM-MM%20molecular%20dynamics%20codes.%20To%20prepare%20the%20input%20files%20for%20these%20calculations%20is%20likely%20to%20be%20the%20key%2C%20and%20most%20complicated%20step%20towards%20MD%20simulations.%20atomes%20offers%20a%20user-friendly%20assistant%20to%20help%20and%20guide%20the%20user%20step%20by%20step%20to%20achieve%20this%20crucial%20step.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.commatsci.2025.113805%22%2C%22ISSN%22%3A%220927-0256%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.commatsci.2025.113805%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T12%3A32%3A34Z%22%7D%7D%2C%7B%22key%22%3A%229FVN36DL%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Liparo%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20Liparo%2C%20J.-P.%20Jay%2C%20B.%20Kundys%2C%20G.%20Simon%2C%20A.%20Fessant%2C%20Y.%20Le%20Grand%2C%20C.J.%20Sheppard%2C%20A.R.E.%20Prinsloo%2C%20D.%20Spenato%2C%20D.T.%20Dekadjevi%2C%20Rare%20earth%20trace%20element%20doping%20of%20extrinsic%20multiferroics%20for%20an%20energy%20efficient%20remote%20control%20of%20magnetic%20properties%2C%20Scientific%20Reports%2015%20%282025%29%205788.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41598-025-90205-x%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41598-025-90205-x%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Rare%20earth%20trace%20element%20doping%20of%20extrinsic%20multiferroics%20for%20an%20energy%20efficient%20remote%20control%20of%20magnetic%20properties%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matthieu%22%2C%22lastName%22%3A%22Liparo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Philippe%22%2C%22lastName%22%3A%22Jay%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bohdan%22%2C%22lastName%22%3A%22Kundys%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gaelle%22%2C%22lastName%22%3A%22Simon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alain%22%2C%22lastName%22%3A%22Fessant%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yann%22%2C%22lastName%22%3A%22Le%20Grand%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Charles%20J.%22%2C%22lastName%22%3A%22Sheppard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aletta%20R.%20E.%22%2C%22lastName%22%3A%22Prinsloo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22Spenato%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%20T.%22%2C%22lastName%22%3A%22Dekadjevi%22%7D%5D%2C%22abstractNote%22%3A%22Developing%20functional%20materials%20for%20optical%20remote%20control%20of%20magnetism%20can%20lead%20to%20faster%2C%20more%20efficient%20wireless%20data%20storage%20and%20sensing%20devices.%20In%20terms%20of%20desired%20material%20properties%2C%20this%20development%20requires%20the%20combined%20optimization%20of%20elastic%20interactions%2C%20low%20magnetic%20coercivity%2C%20and%20a%20narrow%20linewidth%20of%20ferromagnetic%20resonance%20to%20establish%20low-loss%20dynamic%20functionalities.%20A%20general%20pathway%20to%20achieve%20these%20requirements%20is%20still%20lacking.%20Here%2C%20we%20demonstrate%20that%20rare-earth%20trace%20element%20doping%20of%20an%20extrinsic%20multiferroic%20promotes%20strain%20mediated%20energy%20efficient%20remote%20control%20of%20static%20and%20dynamic%20magnetic%20properties%20induced%20by%20non-pulsed%20visible%20light.%20The%20strain%20under%20illumination%20arises%20from%20the%20photostrictive%20property%20of%20the%20ferroelectric%20substrate%20whereas%20the%20magnetism%20control%20originates%20from%20the%20enhanced%20magnetostrictive%20property%20of%20a%20rare-earth%20trace%20element%20doped%20ferromagnetic%20thin%20film.%20Combining%20the%20light-strain-magnetic%20interaction%20in%20the%20rare-earth%20doped%20extrinsic%20multiferroic%20provides%20a%20general%20approach%20for%20enhanced%20photo-magnetic%20elastic%20control%20extendable%20to%20optically%20tunable%20magnetic%20devices.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1038%5C%2Fs41598-025-90205-x%22%2C%22ISSN%22%3A%222045-2322%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1038%5C%2Fs41598-025-90205-x%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%225T5YGD4D%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T12%3A53%3A05Z%22%7D%7D%2C%7B%22key%22%3A%22JK6VXUAG%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Liu%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EX.%20Liu%2C%20V.%20Placide%2C%20L.%20Chu%2C%20K.M.%20Haidaraly%2C%20L.S.%20Vargas%2C%20C.%20Adachi%2C%20J.W.%20Wu%2C%20B.%20Heinrich%2C%20E.%20Lacaze%2C%20W.%20Yan%2C%20A.%20D%26%23x2019%3BAleo%2C%20F.%20Mathevet%2C%20Investigation%20and%20modulation%20of%20charge%20transport%20properties%20with%20thin%20films%20of%20an%20isoindigo-based%20donor-acceptor%20molecular%20semiconductor%2C%20Applied%20Surface%20Science%20686%20%282025%29%20162057.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.apsusc.2024.162057%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.apsusc.2024.162057%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Investigation%20and%20modulation%20of%20charge%20transport%20properties%20with%20thin%20films%20of%20an%20isoindigo-based%20donor-acceptor%20molecular%20semiconductor%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xiao%22%2C%22lastName%22%3A%22Liu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Virginie%22%2C%22lastName%22%3A%22Placide%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Liang%22%2C%22lastName%22%3A%22Chu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kevin%20Mall%22%2C%22lastName%22%3A%22Haidaraly%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lydia%20Sosa%22%2C%22lastName%22%3A%22Vargas%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chihaya%22%2C%22lastName%22%3A%22Adachi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jeong%20Weon%22%2C%22lastName%22%3A%22Wu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emmanuelle%22%2C%22lastName%22%3A%22Lacaze%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Wensheng%22%2C%22lastName%22%3A%22Yan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anthony%22%2C%22lastName%22%3A%22D%27Aleo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fabrice%22%2C%22lastName%22%3A%22Mathevet%22%7D%5D%2C%22abstractNote%22%3A%22Charge%20mobility%20plays%20a%20crucial%20role%20in%20determining%20the%20performance%20of%20organic%20semiconducting%20devices.%20Organic%20semiconductors%20%28OSCs%29%20based%20on%20donor-acceptor%20%28D-A%29%20small%20molecules%20generally%20have%20planar%20backbones%20that%20facilitate%20charge%20transport.%20However%2C%20their%20hole%20transport%20property%20in%20thin%20film%20transistors%20%28TFTs%29%20still%20required%20to%20be%20further%20improved%2C%20and%20simultaneously%20achieving%20electron%20transport%20alongside%20hole%20transport%20remains%20a%20great%20challenge%20due%20to%20the%20presence%20of%20electron%20traps%20on%20the%20substrate%20surface.%20In%20this%20study%2C%20an%20isoindigo-based%20oligothiophene%20that%20is%20a%20D-A%20small%20molecule%2C%20was%20synthesized%20and%20employed%20as%20an%20active%20layer%20in%20TFTs.%20The%20impact%20of%20thermal%20annealing%20on%20the%20structure%2C%20morphology%20and%20charge%20transport%20properties%20of%20its%20thin%20films%20was%20investigated.%20By%20implementing%20a%20facile%20surface%20engineering%2C%20electron%20traps%20on%20the%20SiO2%20dielectric%20surface%20were%20effectively%20eliminated.%20As%20a%20result%2C%20the%20charge%20transport%20behavior%20in%20the%20TFTs%20was%20successfully%20transformed%20from%20solely%20p-type%20to%20ambipolar%20characteristics.%20This%20accomplishment%20holds%20great%20significance%20for%20the%20advancement%20of%20optoelectronic%20devices%20in%20which%20both%20p-type%20and%20n-type%20conduction%20are%20harnessed.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.apsusc.2024.162057%22%2C%22ISSN%22%3A%220169-4332%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.apsusc.2024.162057%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22VYTETDZF%22%5D%2C%22dateModified%22%3A%222025-02-12T08%3A46%3A20Z%22%7D%7D%2C%7B%22key%22%3A%22RR9Y4IZI%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Makarchuk%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EI.%20Makarchuk%2C%20B.%20Rotonnelli%2C%20L.%20Royer%2C%20S.%20Hettler%2C%20J.-J.%20Gallet%2C%20F.%20Bournel%2C%20J.%20Guehl%2C%20A.%20Brige%2C%20A.%20Zitolo%2C%20G.%20Kerangueven%2C%20A.%20Bonnefont%2C%20R.%20Arenal%2C%20E.%20Savinova%2C%20T.%20Asset%2C%20B.P.%20Pichon%2C%20Effect%20of%20Shell%20Thickness%20on%20the%20Oxygen%20Evolution%20Activity%20of%20Core%40shell%20Fe3O4%40CoFe2O4%20Nanoparticles%2C%20Chemistry%20of%20Materials%2037%20%282025%29%20833%26%23x2013%3B844.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.chemmater.4c01784%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.chemmater.4c01784%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Effect%20of%20Shell%20Thickness%20on%20the%20Oxygen%20Evolution%20Activity%20of%20Core%40shell%20Fe3O4%40CoFe2O4%20Nanoparticles%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Iryna%22%2C%22lastName%22%3A%22Makarchuk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benjamin%22%2C%22lastName%22%3A%22Rotonnelli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lisa%22%2C%22lastName%22%3A%22Royer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Simon%22%2C%22lastName%22%3A%22Hettler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Jacques%22%2C%22lastName%22%3A%22Gallet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fabrice%22%2C%22lastName%22%3A%22Bournel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Julie%22%2C%22lastName%22%3A%22Guehl%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Amandine%22%2C%22lastName%22%3A%22Brige%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andrea%22%2C%22lastName%22%3A%22Zitolo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gwenaelle%22%2C%22lastName%22%3A%22Kerangueven%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Antoine%22%2C%22lastName%22%3A%22Bonnefont%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Raul%22%2C%22lastName%22%3A%22Arenal%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Elena%22%2C%22lastName%22%3A%22Savinova%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tristan%22%2C%22lastName%22%3A%22Asset%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%20P.%22%2C%22lastName%22%3A%22Pichon%22%7D%5D%2C%22abstractNote%22%3A%22Hydrogen%20production%20via%20water%20splitting%20requires%20efficient%20electrocatalysts%20to%20reduce%20the%20overpotential%20of%20the%20anodic%20oxygen%20evolution%20reaction%20%28OER%29%20and%20cathodic%20hydrogen%20evolution%20reaction%20%28HER%29.%20In%20this%20study%2C%20we%20investigated%20the%20influence%20of%20apparent%20shell%20thickness%20on%20the%20electrocatalytic%20activity%20of%20Fe3O4%40CoFe2O4%20core%40shell%20nanoparticles%2C%20an%20efficient%20noble%20metal-free%20OER%20catalyst%20in%20alkaline%20media.%20Three%20different%20types%20of%20core%40shell%20nanoparticles%20were%20synthesized%20by%20the%20seed-mediated%20crystal%20growth%20of%20cobalt%20ferrite%20on%20pristine%20magnetite%20nanoparticles.%20The%20synthesis%20conditions%20were%20adapted%20to%20modulate%20the%20shell%20structure.%20Importantly%2C%20all%20proposed%20core%40shell%20structures%20showed%20excellent%20stability%20during%20electrochemical%20testing%2C%20which%20is%20important%20for%20eventual%20industrial%20applications.%20We%20showed%20that%20the%20electrocatalytic%20performance%20of%20Fe3O4%40CoFe2O4%20core%40shell%20nanoparticles%20was%20significantly%20influenced%20by%20the%20shell%20structure.%20The%20cooperative%20redox%20mechanism%20proposed%20to%20be%20the%20origin%20of%20the%20activity%20enhancement%20in%20core%40shell%20nanoparticles%20was%20investigated%20by%20using%20in%20situ%20soft%20X-ray%20absorption%20spectroscopy%20%28XAS%29.%20XAS%20revealed%20that%20cooperative%20redox%20interactions%20occurred%20between%20Co%28II%29%20and%20Fe%28II%29%20residing%20in%20close%20proximity%20at%20the%20core%5C%2Fshell%20interface%2C%20hence%20requiring%20a%20thin%20and%20continuous%20CoFe2O4%20shell.%20Overall%2C%20this%20study%20provides%20insights%20into%20the%20design%20of%20efficient%20core%40shell%20nanocatalysts%20for%20the%20OER%2C%20offering%20a%20path%20toward%20improving%20the%20performance%20of%20earth-abundant%20transition%20metal-oxide%20%28TMO%29%20catalysts%20for%20sustainable%20H2%20production.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.chemmater.4c01784%22%2C%22ISSN%22%3A%220897-4756%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.chemmater.4c01784%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222025-02-12T08%3A48%3A55Z%22%7D%7D%2C%7B%22key%22%3A%222ML7HVTC%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Mastrippolito%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ED.%20Mastrippolito%2C%20M.%20Cavallo%2C%20D.%20Borowski%2C%20E.%20Bossavit%2C%20C.%20Gureghian%2C%20A.%20Colle%2C%20T.%20Gemo%2C%20A.%20Khalili%2C%20H.%20Zhang%2C%20A.%20Ram%2C%20E.%20Dandeu%2C%20S.%20Ithurria%2C%20J.%20Biscaras%2C%20P.%20Dudin%2C%20J.-F.%20Dayen%2C%20J.%20Avila%2C%20E.%20Lhuillier%2C%20D.%20Pierucci%2C%20Operando%20Photoemission%20Imaging%20of%20the%20Energy%20Landscape%20from%20a%202D%20Material-Based%20Field-Effect%20Transistor.%2C%20ACS%20Nano%2019%20%282025%29%209241%26%23x2013%3B9249.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsnano.5c00256%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsnano.5c00256%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Operando%20Photoemission%20Imaging%20of%20the%20Energy%20Landscape%20from%20a%202D%20Material-Based%20Field-Effect%20Transistor.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dario%22%2C%22lastName%22%3A%22Mastrippolito%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mariarosa%22%2C%22lastName%22%3A%22Cavallo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Davy%22%2C%22lastName%22%3A%22Borowski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Erwan%22%2C%22lastName%22%3A%22Bossavit%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Clement%22%2C%22lastName%22%3A%22Gureghian%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Albin%22%2C%22lastName%22%3A%22Colle%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tommaso%22%2C%22lastName%22%3A%22Gemo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Adrien%22%2C%22lastName%22%3A%22Khalili%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Huichen%22%2C%22lastName%22%3A%22Zhang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ankita%22%2C%22lastName%22%3A%22Ram%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Erwan%22%2C%22lastName%22%3A%22Dandeu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sandrine%22%2C%22lastName%22%3A%22Ithurria%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Johan%22%2C%22lastName%22%3A%22Biscaras%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pavel%22%2C%22lastName%22%3A%22Dudin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Francois%22%2C%22lastName%22%3A%22Dayen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jose%22%2C%22lastName%22%3A%22Avila%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emmanuel%22%2C%22lastName%22%3A%22Lhuillier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Debora%22%2C%22lastName%22%3A%22Pierucci%22%7D%5D%2C%22abstractNote%22%3A%22As%20the%20integration%20of%20transition%20metal%20dichalcogenides%20%28TMDC%29%20becomes%20more%20advanced%20for%20optoelectronics%2C%20it%20is%20increasingly%20relevant%20to%20develop%20tools%20that%20can%20correlate%20the%20structural%20properties%20of%20the%20materials%20with%20their%20electrical%20output.%20To%20do%20so%2C%20the%20determination%20of%20the%20electronic%20structure%20must%20go%20beyond%20the%20hypothesis%20that%20the%20properties%20of%20the%20pristine%20material%20remain%20unaffected%20after%20the%20device%20integration%2C%20which%20generates%20changes%20in%20the%20dielectric%20environment%2C%20including%20electric%20fields%20that%20are%20likely%20to%20renormalize%20the%20electronic%20spectrum.%20Here%2C%20we%20demonstrate%20that%20nanobeam%20photoemission%20spectroscopy%20is%20a%20well-suited%20tool%20to%20unveil%20the%20device%20energy%20landscape%20under%20operando%20conditions.%20Both%20the%20gate%20vertical%20field%20and%20the%20drain%20in-plane%20vectorial%20electric%20field%20can%20be%20determined%20with%20a%20sub-mum%20resolution.%20We%20provide%20a%20correlative%20description%20of%20a%20field-effect%20transistor%20to%20connect%20its%20bias-modified%20energy%20landscape%20with%20the%20transistor%20electrical%20output.%20The%20method%20appears%20highly%20suited%20to%20unveil%20how%20the%20actual%20geometry%20of%20the%20flake%20%28thickness%2C%20edge%20effect%2C%20presence%20of%20structural%20defects%2C%20etc.%29%20is%20driving%20the%20current%20flow%20within%20the%20device.%20Lastly%2C%20the%20method%20appears%20fully%20compatible%20with%20traditional%20device%20fabrication%2C%20therefore%20making%20it%20relevant%20for%20systematic%20rational%20optimization%20of%20TMDC-based%20electronic%20devices.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facsnano.5c00256%22%2C%22ISSN%22%3A%221936-086X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facsnano.5c00256%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%225T5YGD4D%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T12%3A53%3A35Z%22%7D%7D%2C%7B%22key%22%3A%22SXUVAH2S%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Metin%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ER.%20Metin%2C%20E.%20Keles%2C%20E.%20Aktan%2C%20A.%20Barsella%2C%20Z.%20Seferoglu%2C%20Synthesis%20of%20fluorescent%20dicyanomethylenevinyl-1%2C3-dicoumarin%20compounds%20with%20donor-acceptor-pi-donor%20%28D-A-pi-D%29%20system%20and%20investigation%20of%20their%20photophysical%2C%20NLO%2C%20and%20chemosensor%20properties%3A%20Part%201.%2C%20Spectrochimica%20Acta.%20Part%20A%2C%20Molecular%20and%20Biomolecular%20Spectroscopy%20330%20%282025%29%20125619%26%23x2013%3B125619.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.saa.2024.125619%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.saa.2024.125619%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Synthesis%20of%20fluorescent%20dicyanomethylenevinyl-1%2C3-dicoumarin%20compounds%20with%20donor-acceptor-pi-donor%20%28D-A-pi-D%29%20system%20and%20investigation%20of%20their%20photophysical%2C%20NLO%2C%20and%20chemosensor%20properties%3A%20Part%201.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Rumeysa%22%2C%22lastName%22%3A%22Metin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ergin%22%2C%22lastName%22%3A%22Keles%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ebru%22%2C%22lastName%22%3A%22Aktan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alberto%22%2C%22lastName%22%3A%22Barsella%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Zeynel%22%2C%22lastName%22%3A%22Seferoglu%22%7D%5D%2C%22abstractNote%22%3A%22Coumarin%20compounds%20have%20heterocyclic%20core%20with%20different%20properties%20such%20as%20high%20quantum%20yields%2C%20broad%20Stokes%20shifts%2C%20and%20superior%20photophysical%20and%20biological%20activity.%20It%20is%20known%20that%20fluorescence%20properties%20increase%20with%20increased%20intramolecular%20charge%20transfer%20in%20systems%20where%20electron-withdrawing%20or%20donor%20groups%20are%20attached%20to%20different%20positions%20of%20the%20coumarin%20compound.%20When%20these%20compounds%20interact%20with%20analytes%20in%20the%20environment%2C%20the%20analytes%20in%20the%20environment%20can%20be%20detected%20by%20quenching%20or%20increasing%20fluorescence.%20For%20this%20purpose%2C%20dicyanomethylenevinyl-1%2C3-dicoumarin%20compounds%20were%20obtained%20and%201H%20NMR%2C%2013C%20NMR%2C%20FT-IR%2C%20HR-MS%20elucidated%20their%20structures.%20To%20determine%20the%20photophysical%20properties%20of%20the%20synthesized%20compounds%2C%20absorption%2C%20and%20emission%20spectra%20were%20examined%20in%20solvents%20with%20different%20polarities%2C%20and%20also%20quantum%20yields%20and%20Stokes%20shifts%20were%20calculated.%20Additionally%2C%20the%20sensitivity%5C%2Fselectivity%20properties%20of%20the%20compounds%20towards%20various%20anions%20were%20investigated%20by%20spectrophotometric%2C%20spectrofluorometric%2C%20and%201H%20NMR%20titration%20methods.%20The%20limit%20of%20detection%20%28LOD%29%20of%20the%20sensors%20to%20sense%20cyanide%20anion%20was%20considered%20based%20on%20absorption%20titration.%20The%20pKa%20value%20of%20compound%20that%20could%20be%20pH%20sensor%20candidate%20was%20determined.%20Thermogravimetric%20analysis%20was%20performed%20as%20an%20important%20parameter%20for%20compounds%20in%20electro-optical%20%28EO%29%20systems.%20Additionally%2C%20nonlinear%20optical%20%28NLO%29%20properties%20of%20the%20compounds%20were%20calculated%20experimentally%20and%20theoretically.%20The%20some%20experimental%20results%20were%20explained%20by%20Density%20Functional%20Theory%20%28DFT%29%20and%20time-dependent%20DFT%20%28TDDFT%29%20calculations.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.saa.2024.125619%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.saa.2024.125619%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%22WWGPR7DV%22%5D%2C%22dateModified%22%3A%222025-02-11T15%3A54%3A00Z%22%7D%7D%2C%7B%22key%22%3A%22AGFVG4PV%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Mgbukwu%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20Mgbukwu%2C%20X.%20Fu%2C%20R.Yu.%20Peshkov%2C%20D.%20Doellerer%2C%20C.G.%20Buitrago%2C%20B.L.%20Feringa%2C%20S.%20Haacke%2C%20S.%20Crespi%2C%20J.%20L%26%23xE9%3Bonard%2C%20Tuning%20the%20Photoisomerization%20Mechanism%20of%20Oxindole%20Switches%20with%20Electron-Donating%20Substituents%2C%20Journal%20of%20Physical%20Chemistry%20B%20129%20%282025%29%203839%26%23x2013%3B3850.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpcb.4c06856%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpcb.4c06856%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Tuning%20the%20Photoisomerization%20Mechanism%20of%20Oxindole%20Switches%20with%20Electron-Donating%20Substituents%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matthew%22%2C%22lastName%22%3A%22Mgbukwu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xingjie%22%2C%22lastName%22%3A%22Fu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Roman%20Yu.%22%2C%22lastName%22%3A%22Peshkov%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniel%22%2C%22lastName%22%3A%22Doellerer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Camilo%20Granados%22%2C%22lastName%22%3A%22Buitrago%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ben%20L.%22%2C%22lastName%22%3A%22Feringa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stefan%22%2C%22lastName%22%3A%22Haacke%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stefano%22%2C%22lastName%22%3A%22Crespi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jeremie%22%2C%22lastName%22%3A%22L%5Cu00e9onard%22%7D%5D%2C%22abstractNote%22%3A%22This%20study%20investigates%20the%20photoreaction%20mechanism%20of%20a%20hydroxy-substituted%20oxindole%20photoswitch%20using%20femtosecond%20transient%20absorption%2C%20fluorescence%20up-conversion%2C%20and%20computational%20chemistry.%20Deprotonation%20of%20the%20hydroxyl%20group%20enhances%20the%20push-pull%20character%20in%20the%20molecule%2C%20allowing%20tuning%20of%20the%20photoisomerization%20mechanism%20from%20a%20precessional%20to%20an%20axial%20motion.%20The%20neutral%20form%20of%20the%20switch%20exhibits%20longer%20excited-state%20lifetimes%2C%20while%20the%20anionic%20form%20decays%20rapidly%20within%20200%20fs.%20Computational%20models%20show%20that%20deprotonation%20increases%20the%20charge%20transfer%20and%20accessibility%20to%20conical%20intersections.%20This%20work%20highlights%20how%20varying%20the%20electron-donating%20strength%20of%20a%20substituent%20in%20a%20push-pull%20photoswitch%20tunes%20the%20photoreaction%20mechanism%20in%20designing%20photoswitches.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.jpcb.4c06856%22%2C%22ISSN%22%3A%221520-6106%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.jpcb.4c06856%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%2295EJ8IDX%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-24T12%3A28%3A58Z%22%7D%7D%2C%7B%22key%22%3A%224LLG7MVK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Pakalniskis%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Pakalniskis%2C%20G.%20Niaura%2C%20R.%20Ramanauskas%2C%20A.N.%20Morozovska%2C%20E.A.%20Eliseev%2C%20G.%20Rogez%2C%20M.%20Lenertz%2C%20J.%20Robert%2C%20P.%20Rabu%2C%20L.%20Puppulin%2C%20S.-W.%20Chen%2C%20T.C.-K.%20Yang%2C%20R.%20Skaudzius%2C%20A.%20Kareiva%2C%20The%20effect%20of%20manganese%20doping%20and%20calcination%20temperature%20on%20polarization%2C%20structural%20and%20magnetic%20properties%20of%20multiferroic%20LuFe%3Csub%3E%281-x%29%3C%5C%2Fsub%3EMn%3Csub%3Ex%3C%5C%2Fsub%3EO%3Csub%3E3%3C%5C%2Fsub%3E%20system%2C%20Journal%20of%20Alloys%20and%20Compounds%201010%20%282025%29%20178335.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jallcom.2024.178335%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jallcom.2024.178335%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22The%20effect%20of%20manganese%20doping%20and%20calcination%20temperature%20on%20polarization%2C%20structural%20and%20magnetic%20properties%20of%20multiferroic%20LuFe%3Csub%3E%281-x%29%3C%5C%2Fsub%3EMn%3Csub%3Ex%3C%5C%2Fsub%3EO%3Csub%3E3%3C%5C%2Fsub%3E%20system%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andrius%22%2C%22lastName%22%3A%22Pakalniskis%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gediminas%22%2C%22lastName%22%3A%22Niaura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Rimantas%22%2C%22lastName%22%3A%22Ramanauskas%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%20N.%22%2C%22lastName%22%3A%22Morozovska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Eugene%20A.%22%2C%22lastName%22%3A%22Eliseev%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Rogez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marc%22%2C%22lastName%22%3A%22Lenertz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jerome%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pierre%22%2C%22lastName%22%3A%22Rabu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Leonardo%22%2C%22lastName%22%3A%22Puppulin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shih-Wen%22%2C%22lastName%22%3A%22Chen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%20Chung-Kuang%22%2C%22lastName%22%3A%22Yang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ramunas%22%2C%22lastName%22%3A%22Skaudzius%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aivaras%22%2C%22lastName%22%3A%22Kareiva%22%7D%5D%2C%22abstractNote%22%3A%22A%20systematic%20investigation%20of%20multiferroic%20LuFe%281-x%29MnxO3%2C%20prepared%20by%20ethylene%20glycol%20based%20sol-gel%20route%2C%20is%20presented.%20The%20effect%20of%20Mn%20content%20and%20calcination%20temperature%20is%20investigated%20employing%20XRD%2C%20Raman%20spectroscopy%2C%20XPS%2C%20SEM%2C%20and%20magnetometry%20measurements.%20Theoretical%20estimation%20of%20the%20polarization%20of%20the%20hexagonal%20unit%20cell%20is%20also%20explored.%20The%20obtained%20data%20reveals%20two%20crystallographic%20phases%2C%20orthorhombic%20Pnma%2C%20and%20hexagonal%20P63cm.%20A%20mixture%20of%20the%20aforementioned%20phases%20is%20obtained%20when%200.3%20%3E%3D%20x%2C%20at%20higher%20content%20a%20single%20phase%20hexagonal%20compound%20is%20formed.%20Rietveld%20refinement%20reveals%20distortion%20of%20the%20lattice%20as%20the%20a-%20unit%20cell%20parameter%20increases%20together%20with%20Mn%20content%20while%20the%20c-%20parameter%20decreases.%20The%20increase%20of%20calcination%20temperature%20from%201100%20to%201300%20degrees%20C%2C%20causes%20particle%20size%20to%20increase%20by%20a%20factor%20of%20around%205.%20XPS%20data%20shows%20that%201100%20degrees%20C%20temperature%20is%20favorable%20for%20the%20iron%20in%20the%202%2B%20state%2C%20while%20the%20formation%20of%20Mn4%2B%20is%20favored%20at%201300%20degrees%20C.%20An%20increase%20in%20Mn%20content%20leads%20to%20a%20decrease%20of%20the%20Neel%20ordering%20temperature%20T-N%20from%20similar%20to%20130%20K%20at%20x%20%3D%200.2%20to%20around%20similar%20to%20115%20K%20when%20x%20%3D%200.4.%20Lastly%2C%20theoretical%20calculations%20reveal%20that%20the%20introduction%20of%20Mn%20into%20the%20unit%20cell%20almost%20linearly%20increases%20the%20polarization%20value.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jallcom.2024.178335%22%2C%22ISSN%22%3A%220925-8388%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.jallcom.2024.178335%22%2C%22collections%22%3A%5B%22M244N6AF%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%5D%2C%22dateModified%22%3A%222025-02-17T13%3A10%3A52Z%22%7D%7D%2C%7B%22key%22%3A%22PWXXBHYZ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Pandey%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.%20Pandey%2C%20T.%20Pin%2C%20S.%20Hettler%2C%20R.%20Arenal%2C%20C.%20Bouillet%2C%20T.%20Maroutian%2C%20J.%20Robert%2C%20B.%20Gobaut%2C%20B.%20Kundys%2C%20J.-F.%20Dayen%2C%20D.%20Halley%2C%20Proximity-Mediated%20Multi-Ferroelectric%20Coupling%20in%20Highly%20Strained%20EuO-Graphene%20Heterostructures%2C%20Advanced%20Materials%20%282025%29%202417669.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadma.202417669%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadma.202417669%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Proximity-Mediated%20Multi-Ferroelectric%20Coupling%20in%20Highly%20Strained%20EuO-Graphene%20Heterostructures%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satakshi%22%2C%22lastName%22%3A%22Pandey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Pin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Simon%22%2C%22lastName%22%3A%22Hettler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Raul%22%2C%22lastName%22%3A%22Arenal%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Bouillet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Maroutian%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jerome%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Gobaut%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bohdan%22%2C%22lastName%22%3A%22Kundys%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Francois%22%2C%22lastName%22%3A%22Dayen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22Halley%22%7D%5D%2C%22abstractNote%22%3A%222D%20van%20der%20Waals%20materials%20and%20their%20heterostructures%20are%20a%20fantastic%20playground%20to%20explore%20emergent%20phenomena%20arising%20from%20electronic%20quantum%20hybridization%20effects.%20In%20the%20last%20decade%2C%20the%20spin-dependant%20hybridization%20effect%20pushed%20this%20frontier%20further%20introducing%20the%20magnetic%20proximity%20effect%20as%20a%20promising%20tool%20for%20spintronic%20applications.%20Here%20the%20uncharted%20proximity-controlled%20magnetoelectric%20effect%20in%20EuO%5C%2Fgraphene%20heterostructure%20is%20unveiled.%20This%20is%20obtained%20while%20creating%20a%20new%20multiferroic%20hybrid%20heterostructure%20with%20multifunctional%20properties.%20Using%20a%20topotactic%20method%20magnetic%20insulating%20EuO%20thin%20films%20on%20graphene%20is%20grown%20under%20high%20compressive%20strain%2C%20which%20induces%20the%20appearance%20of%20an%20additional%20ferroelectric%20order%2C%20with%20an%20electric%20polarization%20that%20reaches%20up%20to%2018%20mu%20C%20cm-2%20at%20room%20temperature.%20This%20observation%20therefore%20quantitatively%20confirms%20the%20theoretical%20predictions%20made%2015%20years%20ago%20of%20a%20strain-induced%20ferroelectric%20state%20in%20EuO.%20Moreover%2C%20the%20EuO%20induces%20a%20magnetic%20proximity%20state%20into%20the%20graphene%20layer%20by%20interfacial%20hybridization.%20This%20new%20ferroelectric%20state%20in%20the%20EuO%5C%2Fgraphene%20heterostructure%20is%20stable%20up%20to%20room%20temperature%20where%20it%20coexists%20with%20the%20EuO%5C%2Fgraphene%20magnetic%20state.%20Furthermore%2C%20intertwined%20magneto-electric%20effects%20are%20shown%20in%20these%20strained%20heterostructures%20which%20can%20facilitate%20the%20manipulation%20of%20magnetization%20and%20electric%20polarization%20in%20future%20memory%20and%20neuromorphic%20devices.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fadma.202417669%22%2C%22ISSN%22%3A%220935-9648%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fadma.202417669%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%225T5YGD4D%22%2C%22IUWT6S8X%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T12%3A58%3A52Z%22%7D%7D%2C%7B%22key%22%3A%22TFYZDVJV%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Pesqueira%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EN.M.%20Pesqueira%2C%20F.%20Morlet-Savary%2C%20M.%20Schmitt%2C%20A.%20Jouaiti%2C%20B.E.%20Goi%2C%20M.%20Mauro%2C%20J.%20Lalevee%2C%20Heteroleptic%20Copper%28I%29%20Complexes%20with%20Pyridine-Benzothiazole%20Ligands%20as%20Photocatalysts%20for%20Free%20Radical%20Photopolymerization%20and%203D%20Printing%2C%20ACS%20Applied%20Polymer%20Materials%20Early%20access%20%282025%29.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsapm.4c04066%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsapm.4c04066%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Heteroleptic%20Copper%28I%29%20Complexes%20with%20Pyridine-Benzothiazole%20Ligands%20as%20Photocatalysts%20for%20Free%20Radical%20Photopolymerization%20and%203D%20Printing%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Naralyne%20M.%22%2C%22lastName%22%3A%22Pesqueira%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fabrice%22%2C%22lastName%22%3A%22Morlet-Savary%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Michael%22%2C%22lastName%22%3A%22Schmitt%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Abdelaziz%22%2C%22lastName%22%3A%22Jouaiti%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Beatriz%20E.%22%2C%22lastName%22%3A%22Goi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matteo%22%2C%22lastName%22%3A%22Mauro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jacques%22%2C%22lastName%22%3A%22Lalevee%22%7D%5D%2C%22abstractNote%22%3A%22Copper%28I%29%20complexes%20have%20attracted%20considerable%20attention%20as%20efficient%20redox%20photocatalysts%20%28PCs%29%20in%20photopolymerization.%20In%20this%20study%2C%20two%20copper%28I%29%20complexes%20bearing%20a%20pyridine-benzothiazole%20ligand%20were%20thoroughly%20investigated%20as%20photocatalysts%20for%20the%20free%20radical%20photopolymerization%20of%20ethoxylated%20trimethylolpropane%20triacrylate%20under%20violet%20and%20green%20light%20irradiation.%20A%20three-component%20system%20comprising%20a%20copper%20complex%2C%20di-tert-butyl-diphenyl%20iodonium%20hexafluorophosphate%2C%20and%20ethyl%20dimethylaminobenzoate%20as%20additives%20was%20investigated%20under%20various%20conditions.%20The%20copper%20complexes%20exhibited%20remarkable%20photoinitiation%20capabilities%2C%20achieving%20high%20monomer%20conversion%20rates%20and%20highlighting%20significant%20structure-reactivity%20relationships.%20Based%20on%20free%20energy%20calculations%20and%20spectroscopic%20analyses%2C%20a%20mechanistic%20pathway%20was%20proposed.%20The%20optimal%20conditions%20were%20successfully%20applied%20in%203D%20printing%2C%20producing%20smooth%20and%20uniform%203D%20structures.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facsapm.4c04066%22%2C%22ISSN%22%3A%222637-6105%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facsapm.4c04066%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222025-02-25T14%3A39%3A31Z%22%7D%7D%2C%7B%22key%22%3A%22LZNPV8AM%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Raimbault%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EJ.%20Raimbault%2C%20C.%20Chevallard%2C%20D.%20Ihiawakrim%2C%20V.%20Ramnarain%2C%20O.%20Ersen%2C%20F.%20Gobeaux%2C%20D.%20Carriere%2C%20Dense%20Liquid%20Precursor%20in%20Mineral%20Crystallization%3A%20Spinodal%20Morphology%20and%20High%20Viscosity%20Evidenced%20by%20Electron%20Imaging.%2C%20Nano%20Letters%2025%20%282025%29%202275%26%23x2212%3B2282.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.nanolett.4c05556%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.nanolett.4c05556%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Dense%20Liquid%20Precursor%20in%20Mineral%20Crystallization%3A%20Spinodal%20Morphology%20and%20High%20Viscosity%20Evidenced%20by%20Electron%20Imaging.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jade%22%2C%22lastName%22%3A%22Raimbault%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Chevallard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Driss%22%2C%22lastName%22%3A%22Ihiawakrim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vinavadini%22%2C%22lastName%22%3A%22Ramnarain%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Frederic%22%2C%22lastName%22%3A%22Gobeaux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22Carriere%22%7D%5D%2C%22abstractNote%22%3A%22Recent%20consensus%20suggests%20that%20the%20classical%20single-step%20nucleation%20theory%2C%20a%20key%20reference%20for%20nanomaterial%20synthesis%2C%20inadequately%20explains%20nanocrystal%20formation%20in%20solutions%2C%20as%20it%20ignores%20noncrystalline%20intermediate%20structures.%20Among%20these%2C%20reactant-rich%20liquid%20nanostructures%20have%20gained%20attention%20for%20their%20potential%20to%20differentiate%20between%20crystallization%20theories.%20However%2C%20capturing%20their%20physical%20properties%20at%20the%20nanometer%20scale%20before%20crystallization%20remains%20challenging.%20We%20demonstrate%20that%20liquid%20nanostructures%20in%20cerium%20oxalate%20crystallization%20exhibit%20spinodal%20decomposition-like%20morphologies%2C%20have%20a%20viscosity%20at%20least%205%20orders%20of%20magnitude%20higher%20than%20the%20surrounding%20water-rich%20phase%2C%20and%20act%20as%20the%20main%20nucleation%20reservoir%20for%20the%20amorphous%20phase.%20These%20findings%20suggest%20that%20models%20for%20multistep%20crystallization%20must%20incorporate%20spinodal%20morphologies%2C%20significant%20viscosity%20contrasts%20between%20separating%20phases%2C%20and%20a%20nucleation%20process.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.nanolett.4c05556%22%2C%22ISSN%22%3A%221530-6992%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.nanolett.4c05556%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22WJDNKBGA%22%2C%226739WBV7%22%5D%2C%22dateModified%22%3A%222025-02-24T10%3A39%3A13Z%22%7D%7D%2C%7B%22key%22%3A%223XIT4CR6%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Ramirez%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20de%20L.A.%20Ramirez%2C%20J.%20Bou-Gharios%2C%20B.%20Freis%2C%20J.%20Draussin%2C%20C.%20Cheignon%2C%20L.J.%20Charbonniere%2C%20S.%20Laurent%2C%20T.%20Gevart%2C%20A.%20Gasser%2C%20S.%20Jung%2C%20F.%20Rossetti%2C%20O.%20Tillement%2C%20G.%20Noel%2C%20X.%20Pivot%2C%20A.%20Detappe%2C%20S.%20B%26%23xE9%3Bgin-Colin%2C%20S.%20Harlepp%2C%20Spacer%20engineering%20in%20nanoparticle-peptide%20conjugates%20boosts%20targeting%20specificity%20for%20tumor-associated%20antigens.%2C%20Nanoscale%20Early%20access%20%282025%29.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4nr02931c%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4nr02931c%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Spacer%20engineering%20in%20nanoparticle-peptide%20conjugates%20boosts%20targeting%20specificity%20for%20tumor-associated%20antigens.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maria%20de%20Los%20Angeles%22%2C%22lastName%22%3A%22Ramirez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jolie%22%2C%22lastName%22%3A%22Bou-Gharios%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Barbara%22%2C%22lastName%22%3A%22Freis%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Julien%22%2C%22lastName%22%3A%22Draussin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Clemence%22%2C%22lastName%22%3A%22Cheignon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Loic%20J%22%2C%22lastName%22%3A%22Charbonniere%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sophie%22%2C%22lastName%22%3A%22Laurent%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Gevart%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Adeline%22%2C%22lastName%22%3A%22Gasser%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sebastian%22%2C%22lastName%22%3A%22Jung%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fabien%22%2C%22lastName%22%3A%22Rossetti%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22Tillement%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Georges%22%2C%22lastName%22%3A%22Noel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xavier%22%2C%22lastName%22%3A%22Pivot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alexandre%22%2C%22lastName%22%3A%22Detappe%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22B%5Cu00e9gin-Colin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sebastien%22%2C%22lastName%22%3A%22Harlepp%22%7D%5D%2C%22abstractNote%22%3A%22Developing%20and%20synthesizing%20nano-objects%20capable%20of%20enabling%20early%20targeted%20diagnosis%20and%20ensuring%20effective%20tumor%20treatment%20represents%20a%20significant%20challenge%20in%20the%20theranostic%20field.%20Among%20various%20nanoparticles%20%28NPs%29%2C%20iron%20oxide%20nanoparticles%20%28IONPs%29%20have%20made%20significant%20contributions%20to%20advancing%20this%20field.%20However%2C%20a%20key%20challenge%20lies%20in%20achieving%20selective%20recognition%20of%20specific%20cell%20types.%20In%20oncology%2C%20the%20primary%20goal%20is%20to%20develop%20innovative%20strategies%20to%20enhance%20NP%20uptake%20by%20tumors%2C%20primarily%20through%20active%20targeting.%20This%20involves%20adding%20targeting%20ligands%20%28TL%29%20to%20the%20NP%20surface%20to%20facilitate%20tumor%20accumulation%20and%20increase%20retention%20within%20the%20tumor%20microenvironment.%20Despite%20biofunctionalization%20strategies%2C%20overall%20tumor%20uptake%20remains%20modest%20at%20only%205-7%25%20of%20the%20injected%20dose%20per%20gram.%20In%20this%20work%2C%20we%20demonstrate%20the%20effect%20of%20spacing%20between%20the%20NPs%20and%20the%20TL%20to%20improve%20their%20availability%20and%20thus%20the%20tumor%20uptake%20of%20the%20complex.%20This%20proof-of-concept%20study%20targets%20the%20epidermal%20growth%20factor%20receptor%20%28EGFR%29%20using%20a%20peptide%20as%20a%20targeting%20ligand.%20Specifically%2C%20we%20characterized%20the%20PEG-peptide%20coupled%20to%20dendronized%20IONPs%2C%20including%20the%20density%20of%20grafted%20TL.%20These%20nano-objects%20underwent%20in%20vitro%20evaluation%20to%20assess%20their%20ability%20to%20specifically%20target%20and%20be%20internalized%20by%20tumor%20cells.%20Therapeutically%2C%20compared%20to%20non-functionalized%20NPs%2C%20the%20presence%20of%20the%20TL%20with%20a%20PEG%20linker%20enhanced%20targeting%20efficacy%20and%20increased%20internalization%2C%20leading%20to%20improved%20photothermal%20efficacy.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd4nr02931c%22%2C%22ISSN%22%3A%222040-3372%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd4nr02931c%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222025-02-12T08%3A52%3A12Z%22%7D%7D%2C%7B%22key%22%3A%2288TLJD5T%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Reato%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20Reato%2C%20B.%20Polido%2C%20A.%20Bonfiglio%2C%20G.%20Moro%2C%20V.%20Cesar%2C%20S.%20Bellemin-Laponnaz%2C%20A.%20Alla%2C%20N.%20Sojic%2C%20M.%20Mauro%2C%20F.%20Polo%2C%20Bright%20and%20Stable%20Electrochemiluminescence%20by%20Heterobimetallic%20IrIII-MI%20%28MI%20%3D%20CuI%2C%20AuI%29%20Complexes%2C%20Advanced%20Optical%20Materials%20%282025%29%202403430.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadom.202403430%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadom.202403430%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Bright%20and%20Stable%20Electrochemiluminescence%20by%20Heterobimetallic%20IrIII-MI%20%28MI%20%3D%20CuI%2C%20AuI%29%20Complexes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mattia%22%2C%22lastName%22%3A%22Reato%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Beatrice%22%2C%22lastName%22%3A%22Polido%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%22%2C%22lastName%22%3A%22Bonfiglio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Giulia%22%2C%22lastName%22%3A%22Moro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vincent%22%2C%22lastName%22%3A%22Cesar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alessandro%22%2C%22lastName%22%3A%22Alla%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Neso%22%2C%22lastName%22%3A%22Sojic%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matteo%22%2C%22lastName%22%3A%22Mauro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Federico%22%2C%22lastName%22%3A%22Polo%22%7D%5D%2C%22abstractNote%22%3A%22Ionic%20transition%20metal%20complexes%20%28iTMCs%29%20often%20suffer%20from%20low%20photoluminescence%20quantum%20yield%2C%20especially%20in%20the%20red%20to%20near-infrared%20spectral%20region.%20Rational%20molecular%20design%20strategies%20unlock%20recovering%20the%20emission%20features%20efficiently.%20A%20potential%20solution%20is%20offered%20by%20bimetallic%20complexes%2C%20which%20are%20rapidly%20emerging%20as%20a%20valid%20and%20attractive%20class%20of%20emitters.%20In%20this%20work%2C%20the%20yet%20unexplored%20electrochemiluminescence%20%28ECL%29%20properties%20of%20a%20series%20of%20heterobimetallic%20complexes%20of%20general%20structure%20Ir-III-M-I%20are%20investigated%2C%20where%20the%20formally%20neutral%20cyclometalated%20iridium%20complex%20provides%20efficient%20photo-%20and%20electro-active%20properties%20to%20the%20molecular%20emitters.%20Whereas%20bulky%20M-I%20%28gold%20or%20copper%29%20metalloligand%20increases%20structural%20rigidity%20and%20chemical%20stability%20of%20the%20architecture%20while%20enabling%20larger%20values%20for%20the%20radiative%20rate%20constant.%20The%20Ir-III-M-I%20shows%20highly%20efficient%20red%20ECL%20at%20lambda%28em%2Cmax%29%20%3D%20600%20nm%2C%20which%20is%20stable%20in%20a%20wider%20range%20of%20applied%20potential.%20The%20activation%20is%20triggered%20at%200.45-0.65%20V%2C%20ca.%200.3-0.5%20V%20lower%20than%20that%20of%20tris-%282%2C2%20%27-bipyridyl%29%20ruthenium%28II%29%20complex%2C%20%5BRu%28bpy%29%283%29%5D%282%2B%29.%20Remarkably%2C%20the%20ECL%20quantum%20yield%20relative%20to%20%5BRu%28bpy%29%283%29%5D%282%2B%29%20is%20up%20to%20six-fold%20higher%2C%20thus%20positioning%20this%20new%20series%20of%20iTMCs%20amongst%20the%20brightest%20ECL-active%20emitters%20to%20date%20and%20possibly%20offering%20a%20platform%20to%20develop%20novel%20and%20even%20more%20efficient%20ECL%20probes%20for%20biosensing%20and%20bioimaging%20applications.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fadom.202403430%22%2C%22ISSN%22%3A%222195-1071%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fadom.202403430%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T13%3A11%3A18Z%22%7D%7D%2C%7B%22key%22%3A%22X7NSP2CQ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Sahib%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EH.%20Sahib%2C%20L.%20Schlur%2C%20B.%20Mundet%2C%20K.%20Cordero%2C%20N.%20Viart%2C%20D.%20Pesquera%2C%20D.%20Preziosi%2C%20Freestanding%20perovskite%20and%20infinite-layer%20nickelate%20membranes%2C%20Physical%20Review%20Materials%209%20%282025%29%20014801.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevMaterials.9.014801%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevMaterials.9.014801%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Freestanding%20perovskite%20and%20infinite-layer%20nickelate%20membranes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hoshang%22%2C%22lastName%22%3A%22Sahib%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Schlur%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bernat%22%2C%22lastName%22%3A%22Mundet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kumara%22%2C%22lastName%22%3A%22Cordero%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22Pesquera%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniele%22%2C%22lastName%22%3A%22Preziosi%22%7D%5D%2C%22abstractNote%22%3A%22Following%20the%20discovery%20of%20superconductivity%20in%20hole-doped%20NdNiO2%20infinite-layer%20thin%20films%2C%20extensive%20research%20has%20been%20conducted%20particularly%20to%20compare%20these%20materials%20with%20cuprates.%20Superconductivity%20has%20also%20been%20observed%20in%20nickelate%20thin%20films%20with%20other%20rare-earth%20elements%20such%20as%20Pr%20and%20La%2C%20but%20not%20in%20their%20bulk%20forms%2C%20suggesting%20a%20critical%20role%20for%20substrate-induced%20strain%5C%2Finterface%20or%20dimensionality%20effects.%20In%20this%20study%2C%20we%20used%20water-soluble%20%28Ca%2CSr%293Al2O6%20sacrificial%20layers%20to%20fabricate%20freestanding%20perovskite%20nickelate%20membranes%20and%20explore%20the%20phase%20transformation%20to%20infinite%20layers%20of%20the%20membranes%20via%20topotactic%20reduction%20in%20the%20absence%20of%20any%20template%20effect%20from%20the%20substrate.%20Highly%20metallic%20NdNiO3%20membranes%20with%20bulk-like%20hysteretic%20metalto-insulator%20transitions%20could%20be%20obtained%20when%20transferred%20from%20a%20LaAlO3%20substrate.%20The%20topotactic%20reduction%20of%20these%20membranes%20with%20CaH2%20was%20shown%20to%20be%20successful%20as%20characterized%20by%20the%20expected%20decrease%20of%20the%20out-of-plane%20cell%20parameter%20and%20absence%20of%20apical%20oxygens.%20The%20reduced%20membranes%2C%20however%2C%20displayed%20insulating%20characteristics%20similar%20to%20those%20of%20bulk%20infinite-layer%20nickelates.%20Our%20findings%20strongly%20indicate%20that%20a%20template%20is%20necessary%20to%20stabilize%20a%20coherent%20and%20robust%20infinite-layer%20phase%20with%20optimal%20transport%20properties.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevMaterials.9.014801%22%2C%22ISSN%22%3A%222475-9953%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2FPhysRevMaterials.9.014801%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222025-02-17T13%3A03%3A17Z%22%7D%7D%2C%7B%22key%22%3A%22BJF5XF4Z%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Sahib%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EH.%20Sahib%2C%20A.%20Raji%2C%20F.%20Rosa%2C%20G.%20Merzoni%2C%20G.%20Ghiringhelli%2C%20M.%20Salluzzo%2C%20A.%20Gloter%2C%20N.%20Viart%2C%20D.%20Preziosi%2C%20Superconductivity%20in%20PrNiO2%20Infinite-Layer%20Nickelates.%2C%20Advanced%20Materials%20%28Deerfield%20Beach%2C%20Fla.%29%20%282025%29%20e2416187.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadma.202416187%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadma.202416187%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Superconductivity%20in%20PrNiO2%20Infinite-Layer%20Nickelates.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hoshang%22%2C%22lastName%22%3A%22Sahib%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aravind%22%2C%22lastName%22%3A%22Raji%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francesco%22%2C%22lastName%22%3A%22Rosa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Giacomo%22%2C%22lastName%22%3A%22Merzoni%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Giacomo%22%2C%22lastName%22%3A%22Ghiringhelli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marco%22%2C%22lastName%22%3A%22Salluzzo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alexandre%22%2C%22lastName%22%3A%22Gloter%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniele%22%2C%22lastName%22%3A%22Preziosi%22%7D%5D%2C%22abstractNote%22%3A%22Several%20reports%20about%20infinite-layer%20nickelate%20thin%20films%20suggest%20that%20the%20superconducting%20critical%20temperature%20versus%20chemical%20doping%20phase%20diagram%20has%20a%20dome-like%20shape%2C%20similar%20to%20cuprates.%20Here%2C%20a%20highly%20reproducible%20superconducting%20state%20in%20undoped%20PrNiO2%20thin%20films%20grown%20on%20SrTiO3%20are%20demonstrated.%20Scanning%20transmission%20electron%20microscopy%20measurements%20show%20coherent%20infinite-layer%20phase%20with%20no%20visible%20stacking-fault%20defects%2C%20an%20overall%20high%20structural%20quality%20where%20possible%20unintentional%20chemical%20doping%20or%20interstitial%20oxygen%2C%20if%20present%2C%20sum%20well%20below%20the%20measurable%20threshold%20of%20the%20technique.%20X-ray%20absorption%20measurements%20show%20very%20sharp%20features%20at%20the%20Ni%20L3%2C2-edges%20with%20a%20large%20linear%20dichroism%2C%20indicating%20the%20preferential%20hole%20occupation%20of%20Ni1%2B-3%20%20d%20x%202%20-%20y%202%20%20%20%24%7B%5C%5Crm%20d%7D_%7Bx%5E2-y%5E2%7D%24%20%20orbitals%20in%20a%20square%20planar%20geometry.%20Resonant%20inelastic%20X-ray%20scattering%20measurements%20reveal%20sharp%20magnon%20excitations%20of%20200meV%20energy%20at%20the%20magnetic%20Brillouin%20zone%20boundary%2C%20highly%20resonant%20at%20the%20Ni1%20%2B%20absorption%20peak.%20The%20results%20indicate%20that%2C%20when%20properly%20stabilized%2C%20infinite-layer%20nickelate%20thin%20films%20are%20superconducting%20without%20chemicaldoping.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fadma.202416187%22%2C%22ISSN%22%3A%221521-4095%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fadma.202416187%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T13%3A13%3A45Z%22%7D%7D%2C%7B%22key%22%3A%22CFTHZW5Q%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Savas%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EI.%20Savas%2C%20M.E.%20Celik%2C%20A.%20Barsella%2C%20C.%20Dengiz%2C%20Carbamate-Functionalized%20NLOphores%20via%20a%20Formal%20%5B2%2B2%5D%20Cycloaddition-Retroelectrocyclization%20Strategy.%2C%20Chemistry-a%20European%20Journal%20%282025%29%20e202404778%26%23x2013%3Be202404778.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fchem.202404778%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fchem.202404778%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Carbamate-Functionalized%20NLOphores%20via%20a%20Formal%20%5B2%2B2%5D%20Cycloaddition-Retroelectrocyclization%20Strategy.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ipek%22%2C%22lastName%22%3A%22Savas%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mehmet%20Efe%22%2C%22lastName%22%3A%22Celik%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alberto%22%2C%22lastName%22%3A%22Barsella%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cagatay%22%2C%22lastName%22%3A%22Dengiz%22%7D%5D%2C%22abstractNote%22%3A%22This%20study%20introduces%20a%20new%20donor%20group%20capable%20of%20activating%20click-type%20%5B2%2B2%5D%20cycloaddition-retroelectrocyclizations%2C%20generally%20known%20for%20their%20limited%20scope.%20Target%20chromophores%20were%20synthesized%20using%20isocyanate-free%20urethane%20synthesis.%20The%20developed%20synthetic%20method%20allows%20for%20the%20tuning%20of%20the%20optical%20properties%20of%20the%20chromophores%20by%20modifying%20the%20donor%20groups%2C%20the%20acceptor%20units%2C%20and%20the%20side%20chains.%20The%20charge%20transfer%20%28CT%29%20bands%20of%20the%20chromophores%20exhibit%20lambdamax%20values%20ranging%20from%20363%20to%20692%5Cu2005nm.%20The%20CT%20bands%20observed%20have%20been%20supported%20by%20solvatochromism%20and%20protonation%20experiments.%20The%20synthesized%20compounds%20exhibit%20positive%20solvatochromism.%20Due%20to%20their%20potential%20as%20NLOphore%20candidates%2C%20the%20stability%20of%20the%20synthesized%20compounds%20have%20been%20investigated%20both%20experimentally%20through%20TGA%20and%20theoretically%20by%20calculating%20parameters%20such%20as%20frontier%20orbital%20energy%20differences%2C%20electronegativity%2C%20and%20global%20hardness%5C%2Fsoftness.%20TD-DFT%20calculations%20were%20used%20to%20elucidate%20the%20nature%20of%20the%20electronic%20transitions%2C%20revealing%20that%20the%20bands%20correspond%20to%20CT%20arising%20from%20HOMO-to-LUMO%20excitations.%20The%20NLO%20properties%20of%20the%20chromophores%20were%20investigated%20theoretically%20by%20DFT%20methods%20and%20experimentally%20by%20the%20EFISHG%20technique.%20Both%20results%20are%20shown%20to%20be%20in%20agreement%20with%20HOMO-LUMO%20energy%20differences.%20The%20experimental%20mubeta%20values%20of%20the%20selected%20molecules%20range%20from%20470%2A10-48%20to%205400%2A10-48%20esu.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fchem.202404778%22%2C%22ISSN%22%3A%221521-3765%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fchem.202404778%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%22WWGPR7DV%22%5D%2C%22dateModified%22%3A%222025-02-12T09%3A46%3A09Z%22%7D%7D%2C%7B%22key%22%3A%22BIC5PVCV%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Schuler%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ET.%20Schuler%2C%20P.%20Camilos%2C%20G.%20Magnifouet%2C%20F.%20Soisson%2C%20E.%20Meslin%2C%20M.%20Vallet%2C%20V.%20Pierron-Bohnes%2C%20M.%20Nastar%2C%20Measuring%20interdiffusion%20coefficient%20from%20XRD%20spectra%20of%20thermally%20annealed%20superlattices%3A%20A%20combined%20modeling%20and%20experimental%20study%20in%20Fe%26%23x2013%3BCr%20nanometric%20multilayers%2C%20Acta%20Materialia%20287%20%282025%29%20120765.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.actamat.2025.120765%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.actamat.2025.120765%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Measuring%20interdiffusion%20coefficient%20from%20XRD%20spectra%20of%20thermally%20annealed%20superlattices%3A%20A%20combined%20modeling%20and%20experimental%20study%20in%20Fe%5Cu2013Cr%20nanometric%20multilayers%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Schuler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pamela%22%2C%22lastName%22%3A%22Camilos%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gladice%22%2C%22lastName%22%3A%22Magnifouet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fr%5Cu00e9d%5Cu00e9ric%22%2C%22lastName%22%3A%22Soisson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Estelle%22%2C%22lastName%22%3A%22Meslin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maxime%22%2C%22lastName%22%3A%22Vallet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22V%5Cu00e9ronique%22%2C%22lastName%22%3A%22Pierron-Bohnes%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maylise%22%2C%22lastName%22%3A%22Nastar%22%7D%5D%2C%22abstractNote%22%3A%22In%20this%20paper%2C%20we%20employ%20atomic%20kinetic%20Monte%20Carlo%20%28AKMC%29%20simulations%20to%20get%20insight%20into%20the%20kinetics%20of%20Fe%5Cu2013Cr%20interdiffusion%20in%20nanometric%20multilayer%20materials%2C%20and%20the%20relevant%20information%20that%20can%20be%20extracted%20from%20the%20evolution%20of%20the%20experimental%20X-ray%20diffraction%20%28XRD%29%20spectrum.%20For%20this%20purpose%2C%20we%20develop%20an%20elastic%20model%20to%20obtain%20the%20interplanar%20spacing%20for%20a%20given%20composition%20profile%20derived%20from%20AKMC%20simulation%2C%20and%20then%20we%20simulate%20the%20corresponding%20XRD%20spectrum%20and%20compare%20it%20with%20the%20experimental%20one.%20We%20find%20a%20very%20good%20agreement%20between%20the%20two%2C%20which%20validates%20our%20modeling%20procedure.%20Then%20we%20put%20some%20effort%20into%20trying%20to%20relate%20specific%20features%20of%20the%20XRD%20spectra%20with%20phenomena%20occurring%20at%20the%20atomic%20scale%2C%20mostly%20the%20decay%20of%20satellite%20peak%20intensities%20over%20time.%20The%20interdiffusion%20coefficients%20extracted%20from%20the%20XRD%20spectra%20are%20underestimated%20in%20the%20Fe-rich%20phase%20and%20overestimated%20in%20the%20Cr-rich%20phase%2C%20but%20more%20or%20less%20within%20one%20order%20of%20magnitude%20of%20the%20values%20obtained%20from%20standard%20measurements.%20Extracting%20more%20quantitative%20kinetic%20information%20directly%20from%20the%20experimental%20XRD%20spectra%20is%20rather%20difficult%20without%20resorting%20to%20a%20modeling%20study.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.actamat.2025.120765%22%2C%22ISSN%22%3A%221359-6454%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS1359645425000588%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22GA3EX26X%22%5D%2C%22dateModified%22%3A%222025-02-12T08%3A53%3A07Z%22%7D%7D%2C%7B%22key%22%3A%22GYNJLGE3%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Shuaib%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EF.%20Shuaib%2C%20G.%20Ori%2C%20P.%20Thomas%2C%20O.%20Masson%2C%20A.%20Bouzid%2C%20Multikernel%20similarity-based%20clustering%20of%20amorphous%20systems%20and%20machine-learned%20interatomic%20potentials%20by%20active%20learning%2C%20Journal%20of%20the%20American%20Ceramic%20Society%20108%20%282025%29%20e20128.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1111%5C%2Fjace.20128%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1111%5C%2Fjace.20128%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Multikernel%20similarity-based%20clustering%20of%20amorphous%20systems%20and%20machine-learned%20interatomic%20potentials%20by%20active%20learning%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Firas%22%2C%22lastName%22%3A%22Shuaib%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guido%22%2C%22lastName%22%3A%22Ori%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%22%2C%22lastName%22%3A%22Thomas%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22Masson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Assil%22%2C%22lastName%22%3A%22Bouzid%22%7D%5D%2C%22abstractNote%22%3A%22We%20present%20a%20hybrid%20similarity%20kernel%20that%20exemplifies%20the%20integration%20of%20short-%20and%20long-range%20descriptors%20via%20the%20use%20of%20an%20average%20kernel%20approach.%20This%20technique%20allows%20for%20a%20direct%20measure%20of%20the%20similarity%20between%20amorphous%20configurations%2C%20and%20when%20combined%20with%20an%20active%20learning%20%28AL%29%20spectral%20clustering%20approach%2C%20it%20leads%20to%20a%20classification%20of%20the%20amorphous%20configurations%20into%20uncorrelated%20clusters.%20Subsequently%2C%20a%20minimum%20size%20database%20is%20built%20by%20considering%20a%20small%20fraction%20of%20configurations%20belonging%20to%20each%20cluster%20and%20a%20machine%20learning%20interatomic%20potential%20%28MLIP%29%2C%20within%20the%20Gaussian%20approximation%20scheme%2C%20is%20fitted%20by%20relying%20on%20a%20Bayesian%20optimization%20of%20the%20potential%20hyperparameters.%20This%20step%20is%20embedded%20within%20an%20AL%20loop%20that%20allows%20to%20sequentially%20increase%20the%20size%20of%20the%20learning%20database%20whenever%20the%20MLIP%20fails%20to%20meet%20a%20predefined%20energy%20convergence%20threshold.%20As%20such%2C%20MLIP%20are%20fitted%20in%20an%20almost%20fully%20automatized%20fashion.%20This%20approach%20is%20tested%20on%20two%20diverse%20amorphous%20systems%20that%20were%20previously%20generated%20using%20first-principles%20molecular%20dynamics.%20Accurate%20potentials%20with%20less%20than%202%20meV%5C%2Fatom%20root%20mean%20square%20energy%20error%20compared%20to%20the%20reference%20data%20are%20obtained.%20This%20accuracy%20is%20achieved%20with%20only%20175%20configurations%20sampling%20the%20studied%20systems%20at%20various%20temperatures.%20The%20robustness%20of%20these%20potentials%20is%20then%20confirmed%20by%20producing%20models%20with%20several%20thousands%20of%20atoms%20featuring%20a%20good%20agreement%20with%20reference%20ab%20initio%20and%20experimental%20data.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1111%5C%2Fjace.20128%22%2C%22ISSN%22%3A%220002-7820%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1111%5C%2Fjace.20128%22%2C%22collections%22%3A%5B%22NZSFH59F%22%2C%22CF4ZI7HM%22%5D%2C%22dateModified%22%3A%222024-11-08T10%3A44%3A16Z%22%7D%7D%2C%7B%22key%22%3A%22VVYJFL5C%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Skachko%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ED.%20Skachko%2C%20B.%20Kundys%2C%20V.%20Levytskyi%2C%20E.%20Zuniga-Puelles%2C%20A.%20Leithe-Jasper%2C%20R.%20Gumeniuk%2C%20Magnetism%20and%20electrical%20and%20thermal%20transport%20in%20the%20natural%20Fe1-xMnxWO4%20%28x%20%3D%200.2%29%20mineral%20from%20Potosi%2C%20Bolivia.%2C%20Dalton%20Transactions%20Early%20access%20%282025%29.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd5dt00332f%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd5dt00332f%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Magnetism%20and%20electrical%20and%20thermal%20transport%20in%20the%20natural%20Fe1-xMnxWO4%20%28x%20%3D%200.2%29%20mineral%20from%20Potosi%2C%20Bolivia.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dmytro%22%2C%22lastName%22%3A%22Skachko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bohdan%22%2C%22lastName%22%3A%22Kundys%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Volodymyr%22%2C%22lastName%22%3A%22Levytskyi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Esteban%22%2C%22lastName%22%3A%22Zuniga-Puelles%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andreas%22%2C%22lastName%22%3A%22Leithe-Jasper%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Roman%22%2C%22lastName%22%3A%22Gumeniuk%22%7D%5D%2C%22abstractNote%22%3A%22The%20composition%20of%20a%20natural%20single%20crystalline%20specimen%20from%20the%20province%20of%20Potosi%20in%20Bolivia%20is%20found%20to%20be%20Fe0.8Mn0.2WO4.%20It%20crystallizes%20with%20the%20primitive%20monoclinic%20NiWO4%20structure%20type%20%5Bspace%20group%20P2%5C%2Fc%2C%20a%20%3D%204.74751%286%29%20A%2C%20b%20%3D%205.71335%287%29%20A%2C%20c%20%3D%204.96847%285%29%20A%2C%20beta%20%3D%2090.15%281%29%5Cu00b0%5D.%20Magnetic%20susceptibility%20and%20specific%20heat%20capacity%20measurements%20indicated%20that%20the%20mineral%20undergoes%20multiple%20magnetic%20transitions%3A%20TN1%20%20T%5C%5C%2CcpN1%20%3D%2067%281%29%20K%2C%20TN2%20%3D%2028%283%29%20K%2C%20and%20T%5C%5C%2CcpN2%20%3D%208%281%29%20K.%20The%20reduced%20magnetic%20entropy%20of%20Rln3%20upon%20the%20high-temperature%20antiferromagnetic%20ordering%20suggests%20the%20failure%20of%20the%20simplified%20LS-coupling%20scheme%20in%20the%20description%20of%20the%20magnetism.%20Fe0.8Mn0.2WO4%20is%20characterized%20by%20enlarged%20electrical%20resistivity%20showing%20an%20exponential%20decrease%20with%20temperature%20for%20T%20%3E%20300%20K%2C%20from%20which%20an%20energy%20gap%20of%20310%20meV%20is%20deduced.%20The%20well-pronounced%20maximum%20occurring%20in%20the%20phononic%20thermal%20conductivity%20just%20below%20the%20TN1%20is%20described%20by%20the%20Debye-Callaway%20model%2C%20indicating%20the%20dominance%20of%20phonon%20scattering%20on%20defects%20as%20well%20as%20umklapp%20processes.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd5dt00332f%22%2C%22ISSN%22%3A%221477-9234%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd5dt00332f%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%225T5YGD4D%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T13%3A14%3A51Z%22%7D%7D%2C%7B%22key%22%3A%2269FZVBWV%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Smolsky%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EJ.%20Smolsky%2C%20K.G.%20Leach%2C%20R.%20Abells%2C%20P.%20Amaro%2C%20A.%20Andoche%2C%20K.%20Borbridge%2C%20C.%20Bray%2C%20R.%20Cantor%2C%20D.%20Diercks%2C%20S.%20Fretwell%2C%20S.%20Friedrich%2C%20A.%20Gillespie%2C%20M.%20Guerra%2C%20A.%20Hall%2C%20C.N.%20Harris%2C%20J.T.%20Harris%2C%20L.M.%20Hayen%2C%20P.-A.%20Hervieux%2C%20C.%20Hinkle%2C%20G.-B.%20Kim%2C%20I.%20Kim%2C%20A.%20Lamm%2C%20A.%20Lennarz%2C%20V.%20Lordi%2C%20J.%20Machado%2C%20A.%20Marino%2C%20D.%20Mckeen%2C%20X.%20Mougeot%2C%20F.%20Ponce%2C%20C.%20Ruiz%2C%20A.%20Samanta%2C%20J.P.%20Santos%2C%20C.%20Stone-Whitehead%2C%20J.%20Taylor%2C%20J.%20Templet%2C%20S.%20Upadhyayula%2C%20L.%20Wagner%2C%20W.K.%20Warburton%2C%20Direct%20experimental%20constraints%20on%20the%20spatial%20extent%20of%20a%20neutrino%20wavepacket%2C%20Nature%20638%20%282025%29.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41586-024-08479-6%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41586-024-08479-6%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Direct%20experimental%20constraints%20on%20the%20spatial%20extent%20of%20a%20neutrino%20wavepacket%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joseph%22%2C%22lastName%22%3A%22Smolsky%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kyle%20G.%22%2C%22lastName%22%3A%22Leach%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ryan%22%2C%22lastName%22%3A%22Abells%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pedro%22%2C%22lastName%22%3A%22Amaro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Adrien%22%2C%22lastName%22%3A%22Andoche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Keith%22%2C%22lastName%22%3A%22Borbridge%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Connor%22%2C%22lastName%22%3A%22Bray%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Robin%22%2C%22lastName%22%3A%22Cantor%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22Diercks%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Spencer%22%2C%22lastName%22%3A%22Fretwell%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephan%22%2C%22lastName%22%3A%22Friedrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Abigail%22%2C%22lastName%22%3A%22Gillespie%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mauro%22%2C%22lastName%22%3A%22Guerra%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ad%22%2C%22lastName%22%3A%22Hall%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cameron%20N.%22%2C%22lastName%22%3A%22Harris%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jackson%20T.%22%2C%22lastName%22%3A%22Harris%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Leendert%20M.%22%2C%22lastName%22%3A%22Hayen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paul-Antoine%22%2C%22lastName%22%3A%22Hervieux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Calvin%22%2C%22lastName%22%3A%22Hinkle%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Geon-Bo%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Inwook%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Amii%22%2C%22lastName%22%3A%22Lamm%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Annika%22%2C%22lastName%22%3A%22Lennarz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vincenzo%22%2C%22lastName%22%3A%22Lordi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jorge%22%2C%22lastName%22%3A%22Machado%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andrew%22%2C%22lastName%22%3A%22Marino%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22Mckeen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xavier%22%2C%22lastName%22%3A%22Mougeot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francisco%22%2C%22lastName%22%3A%22Ponce%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chris%22%2C%22lastName%22%3A%22Ruiz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Amit%22%2C%22lastName%22%3A%22Samanta%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jose%20Paulo%22%2C%22lastName%22%3A%22Santos%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Caitlyn%22%2C%22lastName%22%3A%22Stone-Whitehead%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22John%22%2C%22lastName%22%3A%22Taylor%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joseph%22%2C%22lastName%22%3A%22Templet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sriteja%22%2C%22lastName%22%3A%22Upadhyayula%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Louis%22%2C%22lastName%22%3A%22Wagner%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22William%20K.%22%2C%22lastName%22%3A%22Warburton%22%7D%5D%2C%22abstractNote%22%3A%22Despite%20their%20high%20relative%20abundance%20in%20our%20Universe%2C%20neutrinos%20are%20the%20least%20understood%20fundamental%20particles%20of%20nature.%20In%20fact%2C%20the%20quantum%20properties%20of%20neutrinos%20emitted%20in%20experimentally%20relevant%20sources%20are%20theoretically%20contested1%2C%202%2C%203-4%20and%20the%20spatial%20extent%20of%20the%20neutrino%20wavepacket%20is%20only%20loosely%20constrained%20by%20reactor%20neutrino%20oscillation%20data%20with%20a%20spread%20of%2013%20orders%20of%20magnitude5%2C6.%20Here%20we%20present%20a%20method%20to%20directly%20access%20this%20quantity%20by%20precisely%20measuring%20the%20energy%20width%20of%20the%20recoil%20daughter%20nucleus%20emitted%20in%20the%20radioactive%20decay%20of%20beryllium-7.%20The%20final%20state%20in%20the%20decay%20process%20contains%20a%20recoiling%20lithium-7%20nucleus%2C%20which%20is%20entangled%20with%20an%20electron%20neutrino%20at%20creation.%20The%20lithium-7%20energy%20spectrum%20is%20measured%20to%20high%20precision%20by%20directly%20embedding%20beryllium-7%20radioisotopes%20into%20a%20high-resolution%20superconducting%20tunnel%20junction%20that%20is%20operated%20as%20a%20cryogenic%20sensor.%20Under%20this%20approach%2C%20we%20set%20a%20lower%20limit%20on%20the%20Heisenberg%20spatial%20uncertainty%20of%20the%20recoil%20daughter%20of%206.2%20pm%2C%20which%20implies%20that%20the%20final-state%20system%20is%20localized%20at%20a%20scale%20more%20than%20a%20thousand%20times%20larger%20than%20the%20nucleus%20itself.%20From%20this%20measurement%2C%20the%20first%2C%20to%20our%20knowledge%2C%20direct%20lower%20limit%20on%20the%20spatial%20extent%20of%20a%20neutrino%20wavepacket%20is%20extracted.%20These%20results%20may%20have%20implications%20in%20several%20areas%20including%20the%20theoretical%20understanding%20of%20neutrino%20properties%2C%20the%20nature%20of%20localization%20in%20weak%20nuclear%20decays%20and%20the%20interpretation%20of%20neutrino%20physics%20data.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1038%5C%2Fs41586-024-08479-6%22%2C%22ISSN%22%3A%220028-0836%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1038%5C%2Fs41586-024-08479-6%22%2C%22collections%22%3A%5B%2288PVNMDA%22%2C%22CHW2VGSR%22%5D%2C%22dateModified%22%3A%222025-02-25T14%3A19%3A08Z%22%7D%7D%2C%7B%22key%22%3A%22WHR5FT64%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Thomas%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Thomas%2C%20E.%20Devaux%2C%20K.%20Nagarajan%2C%20T.%20Chervy%2C%20M.%20Seidel%2C%20G.%20Rogez%2C%20J.%20Robert%2C%20M.%20Drillon%2C%20T.%20Ruan%2C%20S.%20Schlittenhardt%2C%20M.%20Ruben%2C%20D.%20Hagenm%26%23xFC%3Bller%2C%20S.%20Sch%26%23xFC%3Btz%2C%20J.%20Schachenmayer%2C%20C.%20Genet%2C%20G.%20Pupillo%2C%20T.%20Ebbesen%2C%20Exploring%20superconductivity%20under%20strong%20coupling%20with%20the%20vacuum%20electromagnetic%20field%2C%20JOURNAL%20OF%20CHEMICAL%20PHYSICS%20162%20%282025%29%20134701.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0231202%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0231202%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Exploring%20superconductivity%20under%20strong%20coupling%20with%20the%20vacuum%20electromagnetic%20field%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A%22%2C%22lastName%22%3A%22Thomas%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E%22%2C%22lastName%22%3A%22Devaux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K%22%2C%22lastName%22%3A%22Nagarajan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T%22%2C%22lastName%22%3A%22Chervy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M%22%2C%22lastName%22%3A%22Seidel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaumme%22%2C%22lastName%22%3A%22Rogez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J%5Cu00e9r%5Cu00f4me%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marc%22%2C%22lastName%22%3A%22Drillon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22TT%22%2C%22lastName%22%3A%22Ruan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S%22%2C%22lastName%22%3A%22Schlittenhardt%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M%22%2C%22lastName%22%3A%22Ruben%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22Hagenm%5Cu00fcller%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S%22%2C%22lastName%22%3A%22Sch%5Cu00fctz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J%22%2C%22lastName%22%3A%22Schachenmayer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C%22%2C%22lastName%22%3A%22Genet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G%22%2C%22lastName%22%3A%22Pupillo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22TW%22%2C%22lastName%22%3A%22Ebbesen%22%7D%5D%2C%22abstractNote%22%3A%22Strong%20light-matter%20interactions%20have%20generated%20considerable%20interest%20as%20a%20means%20to%20manipulate%20material%20properties.%20Here%2C%20we%20explore%20this%20possibility%20with%20the%20molecular%20superconductor%20Rb3C60%20under%20vibrational%20strong%20coupling%20%28VSC%29%20to%20surface%20plasmon%20polaritons.%20By%20placing%20the%20superconductor-surface%20plasmon%20system%20in%20a%20SQUID%20magnetometer%2C%20we%20find%20that%20the%20superconducting%20transition%20temperature%20%28T-c%29%20increases%20from%2030%20to%2045%20K%20at%20normal%20pressures%20under%20VSC%2C%20displaying%20a%20well-defined%20Meissner%20effect.%20A%20simple%20theoretical%20framework%20is%20provided%20to%20understand%20these%20results%20based%20on%20an%20enhancement%20of%20the%20electron-phonon%20coupling.%20This%20proof-of-principle%20study%20opens%20a%20new%20tool%20box%20to%20not%20only%20modify%20superconducting%20materials%20but%20also%20to%20understand%20the%20mechanistic%20details%20of%20different%20superconductors.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1063%5C%2F5.0231202%22%2C%22ISSN%22%3A%220021-9606%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1063%5C%2F5.0231202%22%2C%22collections%22%3A%5B%22M244N6AF%22%2C%22CF4ZI7HM%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-17T06%3A48%3A31Z%22%7D%7D%2C%7B%22key%22%3A%22856DRPM4%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Vaz-Ramos%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EJ.%20Vaz-Ramos%2C%20S.%20Le%20Calve%2C%20S.%20B%26%23xE9%3Bgin%2C%20Polycyclic%20aromatic%20hydrocarbons%20in%20water%20environments%3A%20Impact%2C%20legislation%2C%20depollution%20processes%20and%20challenges%2C%20and%20magnetic%20iron%20oxide%5C%2Fgraphene-based%20nanocomposites%20as%20promising%20adsorbent%20solutions.%2C%20Journal%20of%20Hazardous%20Materials%20490%20%282025%29%20137726.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jhazmat.2025.137726%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jhazmat.2025.137726%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Polycyclic%20aromatic%20hydrocarbons%20in%20water%20environments%3A%20Impact%2C%20legislation%2C%20depollution%20processes%20and%20challenges%2C%20and%20magnetic%20iron%20oxide%5C%2Fgraphene-based%20nanocomposites%20as%20promising%20adsorbent%20solutions.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joana%22%2C%22lastName%22%3A%22Vaz-Ramos%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Le%20Calve%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22B%5Cu00e9gin%22%7D%5D%2C%22abstractNote%22%3A%22Environmental%20pollution%20is%20a%20big%20challenge%20of%20today%27s%20world%2C%20as%20population%20continues%20to%20grow%2C%20and%20industrialisation%20and%20urbanisation%20increase.%20Out%20of%20the%20different%20micropollutants%20in%20the%20atmosphere%20and%20aquatic%20environments%2C%20polycyclic%20aromatic%20hydrocarbons%20are%20of%20particular%20importance%20because%20they%20have%20known%20severe%20associated%20health%20risks%20to%20human%20life%20and%20they%20have%20high%20stability%2C%20leading%20to%20their%20persistence%20in%20the%20environment.%20They%20are%20generally%20present%20in%20the%20environment%20in%20low%20concentrations%2C%20but%2C%20even%20at%20these%20levels%2C%20they%20pose%20threats.%20This%20review%20thus%20focuses%20on%20this%20family%20of%20pollutants%2C%20on%20their%20occurrence%20and%20consequences%2C%20as%20well%20as%20the%20current%20methodologies%20employed%20to%20remove%20them%20from%20water%20environments%20and%20the%20challenges%20that%20remain.%20This%20work%20then%20focuses%20on%20the%20potential%20of%20magnetic%20iron%20oxide%5C%2Fgraphene%20nanocomposites%20for%20the%20adsorption%20of%20PAHs%2C%20extensively%20discussing%20past%20and%20undergoing%20works%2C%20as%20well%20as%20the%20interactions%20between%20these%20adsorbents%20and%20PAHs.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jhazmat.2025.137726%22%2C%22ISSN%22%3A%221873-3336%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.jhazmat.2025.137726%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22UBUT97QT%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T13%3A15%3A59Z%22%7D%7D%2C%7B%22key%22%3A%22LNS6HH34%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Vistoso%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EV.%20Vistoso%2C%20T.%20Fert%26%23xE9%3B%2C%20F.%20Buccino%2C%20L.%20Vergani%2C%20O.%20Ersen%2C%20A.%20Carrad%26%23xF2%3B%2C%20Exploring%20the%20Potential%20of%20ATUM-SEM%20for%20Enhanced%20Characterization%20of%20Human%20Trabecular%20Bone%20in%20Biomaterials%20Research%2C%20JOM%20%282025%29.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs11837-025-07212-6%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs11837-025-07212-6%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Exploring%20the%20Potential%20of%20ATUM-SEM%20for%20Enhanced%20Characterization%20of%20Human%20Trabecular%20Bone%20in%20Biomaterials%20Research%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valeria%22%2C%22lastName%22%3A%22Vistoso%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tom%22%2C%22lastName%22%3A%22Fert%5Cu00e9%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Federica%22%2C%22lastName%22%3A%22Buccino%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laura%22%2C%22lastName%22%3A%22Vergani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Adele%22%2C%22lastName%22%3A%22Carrad%5Cu00f2%22%7D%5D%2C%22abstractNote%22%3A%22This%20study%20focuses%20on%20the%20essential%20role%20of%20lacunae%20and%20canaliculi%20in%20bone%20health%2C%20highlighting%20the%20potential%20of%20automated%20tape%20collecting%20ultramicrotome-scanning%20electron%20microscopy%20%28ATUM-SEM%29%20for%20biomimetic%20materials%20development.%20Using%20ATUM-SEM%2C%20we%20acquired%20high-resolution%2C%20three-dimensional%20datasets%20for%20a%20comprehensive%20analysis%20of%20trabecular%20bone%20microstructure.%20This%20research%20investigates%20the%20application%20of%20ATUM%20in%20characterizing%20the%20microarchitecture%20of%20healthy%20human%20trabecular%20bone.%20Unlike%20traditional%20imaging%2C%20which%20lacks%20the%20resolution%20to%20visualize%20features%20like%20the%20lacuna-canalicular%20network%20critical%20for%20mechanotransduction%20and%20nutrient%20transport%2C%20ATUM-SEM%20captures%20these%20structures%20with%20precision.%20Methods%20are%20valid%20at%20the%20macroscopic%20scale%3B%20they%20often%20lack%20the%20resolution%20needed%20to%20visualize%20intricate%20details%20such%20as%20the%20lacuna-canalicular%20network%2C%20which%20is%20critical%20for%20mechanotransduction%20and%20nutrient%20exchange.%20The%20findings%20establish%20a%20baseline%20for%20healthy%20bone%20microarchitecture%2C%20which%20could%20facilitate%20future%20research%20on%20pathological%20bones%2C%20such%20as%20those%20affected%20by%20osteoporosis%2C%20and%20open%20new%20avenues%20for%20the%20creation%20of%20synthetic%20materials%20that%20replicate%20bone%27s%20natural%20adaptability.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1007%5C%2Fs11837-025-07212-6%22%2C%22ISSN%22%3A%221047-4838%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1007%5C%2Fs11837-025-07212-6%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22MKAFAH44%22%2C%226739WBV7%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T13%3A24%3A30Z%22%7D%7D%2C%7B%22key%22%3A%22FPJK89HZ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Wansi%20Wendji%20et%20al.%22%2C%22parsedDate%22%3A%222025%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.D.%20Wansi%20Wendji%2C%20R.%20Piotrowski%2C%20C.%20Massobrio%2C%20M.%20Boero%2C%20C.%20Tug%26%23xE8%3Bne%2C%20F.%20Shuaib%2C%20D.%20Hamani%2C%20P.%20-m.%20Geffroy%2C%20P.%20Thomas%2C%20A.%20Bouzid%2C%20O.%20Masson%2C%20G.%20Delaizir%2C%20G.%20Ori%2C%20Enhanced%20structural%20description%20of%20sodium%20vanadium%20phosphate%20glasses%3A%20A%20combined%20experimental%20and%20molecular%20dynamics%20study%2C%20Journal%20of%20Non-Crystalline%20Solids%20655%20%282025%29%20123420.%20%3Ca%20class%3D%27zp-DOIURL%27%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jnoncrysol.2025.123420%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jnoncrysol.2025.123420%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Enhanced%20structural%20description%20of%20sodium%20vanadium%20phosphate%20glasses%3A%20A%20combined%20experimental%20and%20molecular%20dynamics%20study%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%20D.%22%2C%22lastName%22%3A%22Wansi%20Wendji%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Piotrowski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Carlo%22%2C%22lastName%22%3A%22Massobrio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mauro%22%2C%22lastName%22%3A%22Boero%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christine%22%2C%22lastName%22%3A%22Tug%5Cu00e8ne%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Shuaib%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D.%22%2C%22lastName%22%3A%22Hamani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%20-m.%22%2C%22lastName%22%3A%22Geffroy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Thomas%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Bouzid%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22O.%22%2C%22lastName%22%3A%22Masson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G.%22%2C%22lastName%22%3A%22Delaizir%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guido%22%2C%22lastName%22%3A%22Ori%22%7D%5D%2C%22abstractNote%22%3A%22Structural%20and%20bonding%20insights%20into%20sodium%20vanadium%20phosphate%20%28NVP%29%20glasses%20are%20crucial%20for%20optimizing%20their%20performance%20as%20cathode%20materials%20in%20sodium-ion%20batteries.%20This%20study%20quantitatively%20assesses%20the%20structural%20features%20and%20bonding%20characteristics%20of%20two%20NVP%20glass%20compositions%3A%20%28Na2O%29alpha-%28VxOy%29%281-2%20alpha%29-%28P2O5%29alpha%20with%20alpha%20%3D%200.375%2C%200.285.%20We%20combine%20experimental%20characterization%20%28differential%20scanning%20calorimetry%2C%20X-ray%20diffraction%20and%20X-ray%20photoelectron%20spectroscopy%2C%29%20and%20atomistic%20modeling%20%28classical%20molecular%20dynamics%20%28CMD%29%2C%20and%20Born-Oppenheimer%20molecular%20dynamics%20%28BOMD%29%29.%20This%20work%20provides%20a%20quantitative%20analysis%20of%20the%20different%20VO%20units%20in%20the%20two%20NVP%20glass%20models%2C%20superseding%20previous%20knowledge%20based%20largely%20on%20CMD%20simulations.%20Our%20results%20show%20that%20the%20account%20of%20the%20electronic%20structure%2C%20inherent%20in%20BOMD%20simulations%20is%20essential%20for%20capturing%20the%20V-O%20bonding%20environment.%20This%20includes%20the%20splitting%20of%20the%20V-O%20peak%20in%20the%20pair%20distribution%20function%20due%20to%20both%20short%20V%3DO%20and%20longer%20V-O%20bonds%2C%20a%20higher%20degree%20of%20polymerization%20in%20the%20phosphate%20network%20and%20amore%20significant%20role%20for%20V5%2B%20as%20a%20network%20former.%22%2C%22date%22%3A%222025%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jnoncrysol.2025.123420%22%2C%22ISSN%22%3A%220022-3093%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.jnoncrysol.2025.123420%22%2C%22collections%22%3A%5B%22NZSFH59F%22%2C%22CF4ZI7HM%22%2C%22UCSZHBXJ%22%5D%2C%22dateModified%22%3A%222025-04-16T13%3A26%3A22Z%22%7D%7D%5D%7D
[1]
E. Aloui, J. Beurton, C. Medemblik, L. Hugoni, I. Clarot, A. Boudier, Y. Arntz, M. De Giorgi, J. Combet, G. Fleith, E. Mathieu, N. Kharouf, L. Kocgozlu, B. Heinrich, D. Favier, M. Brender, F. Boulmedais, P. Schaaf, B. Frisch, P. Lavalle, Salt-Compact Albumin as a New Pure Protein-based Biomaterials: From Design to In Vivo Studies, Advanced Healthcare Materials (2025) 2403385. https://doi.org/10.1002/adhm.202403385.
[1]
B. Bacq-Labreuil, C. Fawaz, Y. Okazaki, Y. Obata, H. Cercellier, P. Le Fevre, F. Bertran, D. Santos-Cottin, H. Yamamoto, I. Yamada, M. Azuma, K. Horiba, H. Kumigashira, M. d’Astuto, S. Biermann, B. Lenz, Universal Waterfall Feature in Cuprate Superconductors: Evidence of a Momentum-Driven Crossover, Physical Review Letters 134 (2025) 016502. https://doi.org/10.1103/PhysRevLett.134.016502.
[1]
B. Bakri, N. Crouseilles, P.-A. Hervieux, X. Hong, G. Manfredi, Ultrafast dynamics of a spin-polarized electron plasma with magnetic ions, Journal of Plasma Physics 91 (2025) E9. https://doi.org/10.1017/S0022377824001594.
[1]
M. Bes, S. Lamont, A. Dufour-Lamartinie, J.-C. Mancer, L. Olanier, J. Robert, F. Vernerey, A. Kovalenko, “Magnetic marshmallows” for soft robotics: magneto-mechanical characterization and application in switchable adhesion structures, Soft Matter Early access (2025). https://doi.org/10.1039/d4sm01503g.
[1]
A.K. Bharwal, J.P. Briggs, C. Tamin, M. Hanauer, R. Vollondat, J. Bartringer, S. Roques, C. Chevalier, A. Dinia, R.T. Collins, A. Slaoui, T. Fix, Enhancing Morphological and Optoelectronic Properties of Silicon Clathrate Films through Thermal Press Annealing and SF6 Treatment, ACS Applied Energy Materials 8 (2025) 1752–1758. https://doi.org/10.1021/acsaem.4c02915.
[1]
P. Blumer, M. Charlton, M. Chung, P. Clade, P. Comini, P. Crivelli, O. Dalkarov, P. Debu, L. Dodd, A. Douillet, S. Guellati, P.-A. Hervieux, L. Hilico, A. Husson, P. Indelicato, G. Janka, S. Jonsell, J.P. Karr, B.H. Kim, E.S. Kim, S.K. Kim, Y. Ko, T. Kosinski, N. Kuroda, B.M. Latacz, B. Lee, H. Lee, J. Lee, A.M.M. Leite, K. Leveque, E. Lim, L. Liszkay, P. Lotrus, D. Lunney, G. Manfredi, B. Mansoulie, M. Matusiak, G. Mornacchi, V. Nesvizhevsky, F. Nez, S. Niang, R. Nishi, B. Ohayon, K. Park, N. Paul, P. Perez, S. Procureur, B. Radics, C. Regenfus, J.-M. Reymond, S. Reynaud, J.-Y. Rousse, O. Rousselle, A. Rubbia, J. Rzadkiewicz, Y. Sacquin, F. SchmidtKaler, M. Staszczak, K. Szymczyk, T. Tanaka, B. Tuchming, B. Vallage, A. Voronin, D.P. van der Werf, S. Wolf, D. Won, S. Wronka, Y. Yamazaki, K.H. Yoo, P. Yzombard, GBAR Collaboration, Corrigendum to “Positron accumulation in the GBAR experiment” [Nucl. Inst. Method. Phys. Res. A 1040 (2022) 167263], Nuclear Instruments & Methods in Physics Research Section A-Accelerators Spectrometers Detectors and Associated Equipment 1070 (2025) 169998. https://doi.org/10.1016/j.nima.2024.169998.
[1]
O. Bolielyi, V. Levytskyi, J. Wagler, K.O. Kvashnina, B. Kundys, A. Leithe-Jasper, R. Gumeniuk, Yb5Rh6Sn18: a valence fluctuating system with ultra-low thermal conductivity., Dalton Transactions 54 (2025) 784–796. https://doi.org/10.1039/d4dt02759k.
[1]
H. Bulou, Numerical Modeling of Healthcare Materials, JOM Early access (2025). https://doi.org/10.1007/s11837-025-07318-x.
[1]
A. D’Aléo, X. Tang, D.-H. Kim, D. Valverde, E. Zaborova, G. Canard, A. Brosseau, L. Mager, G. Clavier, C. Adachi, Y. Olivier, J.-C. Ribierre, Curcuminoid Derivatives with a Donor-Acceptor-Donor Architecture: an Outstanding Platform for Highly-Efficient Near-Infrared Electroluminescence and Amplified Spontaneous Emission, Advanced Optical Materials Early access (2025) 2500338. https://doi.org/https://doi.org/10.1002/adom.202500338.
[1]
E. de Domingo, G. Garcia, E. Tritto, B. Donnio, A. Shah, D.P. Singh, S. Coco, Self-assembly and ambipolar charge transport in columnar phases of polynuclear gold isocyano-triphenylene complexes, Journal of Materials Chemistry C Early access (2025). https://doi.org/10.1039/d5tc00575b.
[1]
A. Diaa, N. El-Mahallawy, A. Carradò, Effect of Mg content on the microstructure, texture, and mechanical performance of hypoeutectic extruded Zn-Mg alloys, Journal of Alloys and Compounds 1010 (2025) 177155. https://doi.org/10.1016/j.jallcom.2024.177155.
[1]
G. Duroux, M.D.S.L. Mendes, I. Makarchuk, T. Lucante, C. Kiefer, S. Buffiere, F. Weill, W. Baaziz, T. Buffeteau, S. Nlate, R. Oda, P. Rosa, E.A. Hillard, B.P. Pichon, E. Pouget, Challenges in Chirality Induction in Iron Oxide Nanoparticles: In Situ vs Ex Situ Growth on Helical Nanoplatforms, Crystal Growth & Design 25 (2025) 603–611. https://doi.org/10.1021/acs.cgd.4c01346.
[1]
L. El Khabchi, A.P. Corredor, F. Roulland, M. Lenertz, C. Leuvrey, J. Robert, G. Versini, L. Schlur, C. Lefèvre, N. Viart, Solid-state synthesis of stoichiometric and dense CoV2O4 targets, Journal of the European Ceramic Society 45 (2025) 117286. https://doi.org/10.1016/j.jeurceramsoc.2025.117286.
[1]
N. Ferrara, G. Giuliani, M. Maimaris, S. Prioli, M. Manathunga, L. Blancafort, J. Léonard, A. Cappelli, M. Olivucci, M. Paolino, Design, Synthesis, and Characterization of pH-Resettable Photoswitches Mimicking the GFP Fluorophore Structure., Journal of Physical Chemistry B 129 (2025) 2845–2855. https://doi.org/10.1021/acs.jpcb.4c07003.
[1]
A. Fetida, O. Bengone, C. Goyhenex, F. Scheurer, R. Robles, N. Lorente, L. Limot, Molecular spin-probe sensing of H-mediated changes in Co nanomagnets., Science Advances 11 (2025) eads1456. https://doi.org/10.1126/sciadv.ads1456.
[1]
L. Fortier, C. Lefebvre, N. Hoffmann, Red light excitation: illuminating photocatalysis in a new spectrum., Beilstein Journal of Organic Chemistry 21 (2025) 296–326. https://doi.org/10.3762/bjoc.21.22.
[1]
S. Garifo, D. Stanicki, T. Vangijzegem, P. Mellet, H.A. Girard, J.-C. Arnault, S. Bégin-Colin, Y.-M. Frapart, R.N. Muller, S. Laurent, Tailoring Nanodiamonds for High-Contrast EPR Imaging: Size, Surface Properties, and Spectroscopic Performance, Langmuir early access (2025). https://doi.org/10.1021/acs.langmuir.4c05169.
[1]
V. Giuso, T. Thierry, C. Gourlaouen, P. Mercandelli, N. Vanthuyne, M. Mauro, S. Bellemin-Laponnaz, A chiral Si(iv) complex bearing a 1,2,4-triazole-2,2′-diphenol ligand: synthesis, (chiro-)optical properties and computational investigation, Dalton Transactions Early access (2025). https://doi.org/10.1039/d5dt00392j.
[1]
G. Gubbiotti, A. Barman, S. Ladak, C. Bran, D. Grundler, M. Huth, H. Plank, G. Schmidt, S. van Dijken, R. Streubel, O.V. Dobrovolskiy, V. Scagnoli, L.J. Heyderman, C. Donnelly, O. Hellwig, L. Fallarino, M.B. Jungfleisch, A. Farhan, N. Maccaferri, P. Vavassori, P. Fischer, R. Tomasello, G. Finocchio, R. Clerac, R. Sessoli, D. Makarov, D. Sheka, M. Krawczyk, R.A. Gallardo, P. Landeros, M. d’Aquino, R. Hertel, P. Pirro, F. Ciubotaru, M. Becherer, J. Gartside, T. Ono, P. Bortolotti, A. Fernandez-Pacheco, 2025 Roadmap on 3D Nano-magnetism., Journal of Physics. Condensed Matter 37 (2025) 143502. https://doi.org/10.1088/1361-648X/ad9655.
[1]
S. Guchait, S. Oummouch, P. Durand, N. Kamatham, B. Jismy, L. Herrmann, S. Méry, N. Leclerc, M. Brinkmann, Impact of Side Chain Chemical Structure on Doping and Thermoelectric Properties of Oriented PBTTT Thin Films., Small 21 (2025) 2410073. https://doi.org/10.1002/smll.202410073.
[1]
D. Gupta, M. Pankratova, M. Riepp, M. Pereiro, B. Sanyal, S. Ershadrad, M. Hehn, N. Pontius, C. Schuessler-Langeheine, R. Abrudan, N. Bergeard, A. Bergman, O. Eriksson, C. Boeglin, Tuning ultrafast demagnetization with ultrashort spin polarized currents in multi-sublattice ferrimagnets, Nature Communications 16 (2025) 3097. https://doi.org/10.1038/s41467-025-58411-3.
[1]
X. Henning, L. Schlur, L. Wendling, T. Fix, S. Colis, A. Dinia, M. Alexe, M.V. Rastei, Interfacial photovoltaic effects in ferroelectric \mathrmBi_2\mathrmFeCrO_6 thin films, Physical Review Materials 9 (2025) 024403. https://doi.org/10.1103/PhysRevMaterials.9.024403.
[1]
K. Herasymenko, D. Walisinghe, M. Konno, L. Barneschi, I. de Waele, M. Sliwa, K. Inoue, M. Olivucci, S. Haacke, Archaerhodopsin 3 is an ideal template for the engineering of highly fluorescent optogenetic reporters, Chemical Science 16 (2025) 761–774. https://doi.org/10.1039/d4sc05120c.
[1]
A. Jouaiti, L. Ballerini, W.-M. Zhang, F. Polo, C. Gourlaouen, H.-C. Su, M. Mauro, Tuning the Electroluminescence of Binuclear Copper(I) Emitters Into the NIR-I Region, Advanced Optical Materials 13 (2025) 2402666. https://doi.org/https://doi.org/10.1002/adom.202402666.
[1]
R. Knapman, M. Azhar, A. Pignedoli, L. Gallard, R. Hertel, J. Leliaert, K. Everschor-Sitte, Numerical calculation of the Hopf index for three-dimensional magnetic textures, Physical Review B 111 (2025) 134408. https://doi.org/10.1103/PhysRevB.111.134408.
[1]
G. Krieger, C.-P. Su, H. Sahib, R. Fan, P. Steadman, A. Gloter, N. Viart, D. Preziosi, Tailoring the breathing-mode distortions in nickelate/ferroelectric heterostructures, Journal of Applied Physics 137 (2025) 125301. https://doi.org/10.1063/5.0255194.
[1]
S. Le Roux, atomes: Analysis, visualization, edition and post-processing of 3D atomic scale models, Computational Materials Science 253 (2025) 113805. https://doi.org/10.1016/j.commatsci.2025.113805.
[1]
M. Liparo, J.-P. Jay, B. Kundys, G. Simon, A. Fessant, Y. Le Grand, C.J. Sheppard, A.R.E. Prinsloo, D. Spenato, D.T. Dekadjevi, Rare earth trace element doping of extrinsic multiferroics for an energy efficient remote control of magnetic properties, Scientific Reports 15 (2025) 5788. https://doi.org/10.1038/s41598-025-90205-x.
[1]
X. Liu, V. Placide, L. Chu, K.M. Haidaraly, L.S. Vargas, C. Adachi, J.W. Wu, B. Heinrich, E. Lacaze, W. Yan, A. D’Aleo, F. Mathevet, Investigation and modulation of charge transport properties with thin films of an isoindigo-based donor-acceptor molecular semiconductor, Applied Surface Science 686 (2025) 162057. https://doi.org/10.1016/j.apsusc.2024.162057.
[1]
I. Makarchuk, B. Rotonnelli, L. Royer, S. Hettler, J.-J. Gallet, F. Bournel, J. Guehl, A. Brige, A. Zitolo, G. Kerangueven, A. Bonnefont, R. Arenal, E. Savinova, T. Asset, B.P. Pichon, Effect of Shell Thickness on the Oxygen Evolution Activity of Core@shell Fe3O4@CoFe2O4 Nanoparticles, Chemistry of Materials 37 (2025) 833–844. https://doi.org/10.1021/acs.chemmater.4c01784.
[1]
D. Mastrippolito, M. Cavallo, D. Borowski, E. Bossavit, C. Gureghian, A. Colle, T. Gemo, A. Khalili, H. Zhang, A. Ram, E. Dandeu, S. Ithurria, J. Biscaras, P. Dudin, J.-F. Dayen, J. Avila, E. Lhuillier, D. Pierucci, Operando Photoemission Imaging of the Energy Landscape from a 2D Material-Based Field-Effect Transistor., ACS Nano 19 (2025) 9241–9249. https://doi.org/10.1021/acsnano.5c00256.
[1]
R. Metin, E. Keles, E. Aktan, A. Barsella, Z. Seferoglu, Synthesis of fluorescent dicyanomethylenevinyl-1,3-dicoumarin compounds with donor-acceptor-pi-donor (D-A-pi-D) system and investigation of their photophysical, NLO, and chemosensor properties: Part 1., Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy 330 (2025) 125619–125619. https://doi.org/10.1016/j.saa.2024.125619.
[1]
M. Mgbukwu, X. Fu, R.Yu. Peshkov, D. Doellerer, C.G. Buitrago, B.L. Feringa, S. Haacke, S. Crespi, J. Léonard, Tuning the Photoisomerization Mechanism of Oxindole Switches with Electron-Donating Substituents, Journal of Physical Chemistry B 129 (2025) 3839–3850. https://doi.org/10.1021/acs.jpcb.4c06856.
[1]
A. Pakalniskis, G. Niaura, R. Ramanauskas, A.N. Morozovska, E.A. Eliseev, G. Rogez, M. Lenertz, J. Robert, P. Rabu, L. Puppulin, S.-W. Chen, T.C.-K. Yang, R. Skaudzius, A. Kareiva, The effect of manganese doping and calcination temperature on polarization, structural and magnetic properties of multiferroic LuFe(1-x)MnxO3 system, Journal of Alloys and Compounds 1010 (2025) 178335. https://doi.org/10.1016/j.jallcom.2024.178335.
[1]
S. Pandey, T. Pin, S. Hettler, R. Arenal, C. Bouillet, T. Maroutian, J. Robert, B. Gobaut, B. Kundys, J.-F. Dayen, D. Halley, Proximity-Mediated Multi-Ferroelectric Coupling in Highly Strained EuO-Graphene Heterostructures, Advanced Materials (2025) 2417669. https://doi.org/10.1002/adma.202417669.
[1]
N.M. Pesqueira, F. Morlet-Savary, M. Schmitt, A. Jouaiti, B.E. Goi, M. Mauro, J. Lalevee, Heteroleptic Copper(I) Complexes with Pyridine-Benzothiazole Ligands as Photocatalysts for Free Radical Photopolymerization and 3D Printing, ACS Applied Polymer Materials Early access (2025). https://doi.org/10.1021/acsapm.4c04066.
[1]
J. Raimbault, C. Chevallard, D. Ihiawakrim, V. Ramnarain, O. Ersen, F. Gobeaux, D. Carriere, Dense Liquid Precursor in Mineral Crystallization: Spinodal Morphology and High Viscosity Evidenced by Electron Imaging., Nano Letters 25 (2025) 2275−2282. https://doi.org/10.1021/acs.nanolett.4c05556.
[1]
M. de L.A. Ramirez, J. Bou-Gharios, B. Freis, J. Draussin, C. Cheignon, L.J. Charbonniere, S. Laurent, T. Gevart, A. Gasser, S. Jung, F. Rossetti, O. Tillement, G. Noel, X. Pivot, A. Detappe, S. Bégin-Colin, S. Harlepp, Spacer engineering in nanoparticle-peptide conjugates boosts targeting specificity for tumor-associated antigens., Nanoscale Early access (2025). https://doi.org/10.1039/d4nr02931c.
[1]
M. Reato, B. Polido, A. Bonfiglio, G. Moro, V. Cesar, S. Bellemin-Laponnaz, A. Alla, N. Sojic, M. Mauro, F. Polo, Bright and Stable Electrochemiluminescence by Heterobimetallic IrIII-MI (MI = CuI, AuI) Complexes, Advanced Optical Materials (2025) 2403430. https://doi.org/10.1002/adom.202403430.
[1]
H. Sahib, L. Schlur, B. Mundet, K. Cordero, N. Viart, D. Pesquera, D. Preziosi, Freestanding perovskite and infinite-layer nickelate membranes, Physical Review Materials 9 (2025) 014801. https://doi.org/10.1103/PhysRevMaterials.9.014801.
[1]
H. Sahib, A. Raji, F. Rosa, G. Merzoni, G. Ghiringhelli, M. Salluzzo, A. Gloter, N. Viart, D. Preziosi, Superconductivity in PrNiO2 Infinite-Layer Nickelates., Advanced Materials (Deerfield Beach, Fla.) (2025) e2416187. https://doi.org/10.1002/adma.202416187.
[1]
I. Savas, M.E. Celik, A. Barsella, C. Dengiz, Carbamate-Functionalized NLOphores via a Formal [2+2] Cycloaddition-Retroelectrocyclization Strategy., Chemistry-a European Journal (2025) e202404778–e202404778. https://doi.org/10.1002/chem.202404778.
[1]
T. Schuler, P. Camilos, G. Magnifouet, F. Soisson, E. Meslin, M. Vallet, V. Pierron-Bohnes, M. Nastar, Measuring interdiffusion coefficient from XRD spectra of thermally annealed superlattices: A combined modeling and experimental study in Fe–Cr nanometric multilayers, Acta Materialia 287 (2025) 120765. https://doi.org/https://doi.org/10.1016/j.actamat.2025.120765.
[1]
F. Shuaib, G. Ori, P. Thomas, O. Masson, A. Bouzid, Multikernel similarity-based clustering of amorphous systems and machine-learned interatomic potentials by active learning, Journal of the American Ceramic Society 108 (2025) e20128. https://doi.org/10.1111/jace.20128.
[1]
D. Skachko, B. Kundys, V. Levytskyi, E. Zuniga-Puelles, A. Leithe-Jasper, R. Gumeniuk, Magnetism and electrical and thermal transport in the natural Fe1-xMnxWO4 (x = 0.2) mineral from Potosi, Bolivia., Dalton Transactions Early access (2025). https://doi.org/10.1039/d5dt00332f.
[1]
J. Smolsky, K.G. Leach, R. Abells, P. Amaro, A. Andoche, K. Borbridge, C. Bray, R. Cantor, D. Diercks, S. Fretwell, S. Friedrich, A. Gillespie, M. Guerra, A. Hall, C.N. Harris, J.T. Harris, L.M. Hayen, P.-A. Hervieux, C. Hinkle, G.-B. Kim, I. Kim, A. Lamm, A. Lennarz, V. Lordi, J. Machado, A. Marino, D. Mckeen, X. Mougeot, F. Ponce, C. Ruiz, A. Samanta, J.P. Santos, C. Stone-Whitehead, J. Taylor, J. Templet, S. Upadhyayula, L. Wagner, W.K. Warburton, Direct experimental constraints on the spatial extent of a neutrino wavepacket, Nature 638 (2025). https://doi.org/10.1038/s41586-024-08479-6.
[1]
A. Thomas, E. Devaux, K. Nagarajan, T. Chervy, M. Seidel, G. Rogez, J. Robert, M. Drillon, T. Ruan, S. Schlittenhardt, M. Ruben, D. Hagenmüller, S. Schütz, J. Schachenmayer, C. Genet, G. Pupillo, T. Ebbesen, Exploring superconductivity under strong coupling with the vacuum electromagnetic field, JOURNAL OF CHEMICAL PHYSICS 162 (2025) 134701. https://doi.org/10.1063/5.0231202.
[1]
J. Vaz-Ramos, S. Le Calve, S. Bégin, Polycyclic aromatic hydrocarbons in water environments: Impact, legislation, depollution processes and challenges, and magnetic iron oxide/graphene-based nanocomposites as promising adsorbent solutions., Journal of Hazardous Materials 490 (2025) 137726. https://doi.org/10.1016/j.jhazmat.2025.137726.
[1]
V. Vistoso, T. Ferté, F. Buccino, L. Vergani, O. Ersen, A. Carradò, Exploring the Potential of ATUM-SEM for Enhanced Characterization of Human Trabecular Bone in Biomaterials Research, JOM (2025). https://doi.org/10.1007/s11837-025-07212-6.
[1]
S.D. Wansi Wendji, R. Piotrowski, C. Massobrio, M. Boero, C. Tugène, F. Shuaib, D. Hamani, P. -m. Geffroy, P. Thomas, A. Bouzid, O. Masson, G. Delaizir, G. Ori, Enhanced structural description of sodium vanadium phosphate glasses: A combined experimental and molecular dynamics study, Journal of Non-Crystalline Solids 655 (2025) 123420. https://doi.org/10.1016/j.jnoncrysol.2025.123420.